Environmental responses to Lateglacial climatic fluctuations recorded in the sediments of pre‐Alpine Lake Mondsee (northeastern Alps)

Investigation of the sedimentary record of pre‐Alpine Lake Mondsee (Upper Austria) focused on the environmental reaction to rapid Lateglacial climatic changes. Results of this study reveal complex proxy responses that are variable in time and influenced by the long‐term evolution of the lake and its catchment. A new field sampling approach facilitated continuous and precisely controlled parallel sampling at decadal to sub‐annual resolution for µ‐XRF element scanning, carbon geochemistry, stable isotope measurements on ostracods, pollen analyses and large‐scale thin sections for microfacies analysis. The Holocene chronology is established through microscopic varve counting and supported by accelerator mass spectrometry ¹⁴C dating of terrestrial plant macrofossils, whereas the Lateglacial age model is based on δ¹⁸O wiggle matching with the Greenland NGRIP record, using the GICC05 chronology. Microfacies analysis enables the detection of subtle sedimentological changes, proving that depositional processes even in rather large lake systems are highly sensitive to climate forcing. Comparing periods of major warming at the onset of the Lateglacial and Holocene and of major cooling at the onset of the Younger Dryas reveals differences in proxy responses, reflecting threshold effects and ecosystem inertia. Temperature increase, vegetation recovery, decrease of detrital flux and intensification of biochemical calcite precipitation at the onset of the Holocene took place with only decadal leads and lags over a ca. 100 a period, whereas the spread of woodlands and the reduction of detrital flux lagged the warming at the onset of the Lateglacial Interstadial by ca. 500–750 a. Cooling at the onset of the Younger Dryas is reflected by the simultaneous reaction of δ¹⁸O and vegetation, but sedimentological changes (reduction of endogenic calcite content, increase in detrital flux) were delayed by about 150–300 a. Three short‐term Lateglacial cold intervals, corresponding to Greenland isotope substages GI‐1d, GI‐1c2 and GI‐1b, also show complex proxy responses that vary in time. Copyright © 2011 John Wiley & Sons, Ltd.     

Heat release from rooftops during rainstorms in the Minneapolis/St. Paul Metropolitan Area,USA

In the modeling of urban storm water runoff temperatures, the contribution of rooftops to the heating of rainfall runoff is usually neglected or not mentioned in the literature. In this paper we examine the accuracy of this assumption (a) by analyzing temperature data that we recorded on a residential rooftop, a commercial rooftop, and a concrete driveway, and (b) by simulating temperature profiles within rooftops and pavements, and estimating heat transfer amounts from these surfaces to rainfall runoff (‘heat export’). Analysis of both wet‐ and dry‐weather temperature data recorded in the Minneapolis/St. Paul metropolitan area (north‐central USA) over periods of several months leads to the conclusion that (a) a concrete driveway has a far greater capacity for heat storage and release than a shingled residential rooftop, and (b) an insulated commercial rooftop is able to store and release more heat than the residential rooftop. Unexpectedly, the rainfall events with the highest dew point (rainfall) and surface temperatures often occurred during late night or early morning hours, and not during daylight hours. The analysis of three rainfall events showed that the heat export from the commercial rooftop was roughly three times that of the residential rooftop, but only 30%–90% of the heat export from a concrete driveway. Maximum (potential) heat export was significantly higher for the driveway than for either rooftop. In conclusion, the results of the data analysis and heat export simulations support the assumption that residential rooftops contribute very little heating to runoff from rainfall, while commercial rooftops may have a thermal impact on rainfall runoff because of their greater thermal storage capacity. Commercial rooftops, in addition to asphalt and concrete pavements, should be considered when estimating water temperature of rainfall runoff from urbanized areas and the associated impact on the thermal regime of streams and fish habitat. Copyright © 2011 John Wiley & Sons, Ltd.     

A Lateglacial–early Holocene tephrochronology for SW Sweden

Four cores from southwestern Sweden are presented together with their tephra geochemistry. Two cryptotephra horizons were confirmed geochemically in the cores, the Vedde Ash and the Hässeldalen Tephra. The Lateglacial Hässeldalen Tephra (11 360–11 300 cal. a BP) offers great potential as a regional isochrone to add a new degree of certainty to the deglaciation chronology of southern Sweden, including the extent of glacial Lake Bolmen. In addition, the geographical distribution of the Hässeldalen Tephra has recently been extended outside of Sweden, making it an important time‐marker horizon in northern Europe. There are potential difficulties, however. Proper identification of the actual isochrone is complicated by the vertical pattern of shard distribution, which could be the result of several eruptive events, as well as by the fact that shards from the 10‐ka Askja horizon (10 500–10 350 cal. a BP) were found in close stratigraphical proximity. The geochemical data presented are the result of improved EPMA methodology, which significantly reduces sodium mobilization. The results therefore have slightly altered values, which has consequences for classifying new finds when they are compared with previous data for geochemically similar tephras. Finally, potential indications of the Borrobol/Penifiler horizon are presented, although the existence of the horizon could not be confirmed geochemically. This highlights the need to retrieve cores from different locations within a basin based on an analysis of basin morphology if horizons are to be located.     

Earthquakes in Switzerland and surrounding regions during 2011

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2011. During this period, 522 earthquakes and 92 quarry blasts were detected and located in the region under consideration. With a total of only 10 events with M _L????2.5, the seismic activity in the year 2011 was far below the average over the previous 36?years. Most noteworthy were the earthquake sequence of Sierre (VS) in January, with two events of M _L 3.3 and 3.2, the M _L 3.3 earthquake at a depth of 31?km below Bregenz, and the M _L 3.1 event near Delémont. The two strongest events near Sierre produced shaking of intensity IV.     

Chemical changes in fluid composition due to CO2 injection in the Altmark gas field: preliminary results from batch experiments

Dissolution?Cprecipitation phenomena induced by CO₂ injection to Altmark Permian sandstone were observed through laboratory experiments carried out under simulated reservoir conditions (125?°C and 50 bars of pressure). The rock sample was collected from the Altmark gas reservoir, which is being considered for enhanced gas recovery. Two sets of experiments were performed with pulverized rock samples in a closed batch reactor with either pure water (run 1) or 3?M aqueous NaCl solution (run 2) and reacted with injected CO₂ for 3, 5, and 9?days. The liquid samples were analyzed by inductively coupled plasma optical emission spectroscopy and total reflection X-ray fluorescence, where the latter proved to be a feasible alternative to conventional analytical techniques, especially since only small sample volumes (about 10???l) are needed. Chemical analysis for both fluids (water and NaCl brine) indicated a significant dissolution of calcite and anhydrite in the solution, which might be a crucial process during CO₂ injection. The brine solution enhanced the dissolution of calcite and anhydrite compared to pure water at the beginning of the reaction. Moreover, the progressive higher Si⁴⁺/Al³⁺ molar ratios (in average by a factor of 3) in the brine experiments indicated quartz dissolution. Thermodynamic calculations of mineral saturation indices highlighted the dissolution of the Ca-bearing minerals, which was in agreement with experimental results. Modeling enabled an evaluation of the dissolution processes of minerals in a low-salinity region, yet hindrances to model more saline conditions emphasize the need for further laboratory studies in order to parameterize models for deep aquifer conditions.