Physicochemical structural characterization of ambers from deposits in Poland

The physical and chemical properties of 8 samples of amber from different localities in Poland (Baltic Coast, Bełchatów Tertiary brown coal, and Jaroszów clay mine) were investigated by N₂ sorption at 77 K, positron annihilation spectroscopy for chemical analysis (PASCA) and by organic geochemical methods (FT-IR,¹H and¹³C NMR, GC, and GC-MS). The porosity of the ambers as determined by PASCA consists of narrow micropores with diameters ranging from 0.8 to 0.9 nm and a volume 0.025 cm³ g⁻¹. In the external eroded part of the amber samples (rind) the concentration of pores where positronium atoms can form is lower and consists of approximately12 the concentration as in their interior. Values of pore parameters determined from sorption of N₂ are comparable with those found by the PASCA method. The average diameter of pores ranges from 2 to 12 nm, while their volume varies from 0.018 to 0.048 cm³ g⁻¹.. The chemical character of the ambers is similar based on FT-IR spectroscopy. However, noticeable differences in concentrations of ester and hydroxyl groups are observed in both exterior and interior regions, where the abundances of the ester groups are lower in the exterior rind. The proportion of organic material extractable with chloroform-methanol (1:1, v/v) ranges from 15 to 50% and correlates inversely to the average reflectances (R_r) of polished amber surfaces which range from 1.7 to 0.1 %. These variations are attributed to differing concentrations of oxygenated groups in the respective amber samples. The FT-IR spectra of the non-polar fractions (NP) from the extracts resemble the spectra of the source ambers. However, the intensities of the absorbance for the hdroxyl group are much lower, while absorbances for exomethylene groups are not present. The¹H and¹³C NMR data of NP fractions showed a complex diversity of components in mixtures with different relative concentrations but predominantly aliphatic in character for the respective samples.GC and GC-MS analyses of these fractions revealed that they are comprised of a mixture of compounds typical for Baltic amber but with variable relative concentrations. Two groups of compounds are found to be common to all NP fractions. The first is a minor concentration of homologousn-alkanes with a characteristic Gaussian distribution in the range from C₂₂ to C₃₂ and maximizing at C₂₆–C₂₇. In addition C₂₂ is characteristically slightly higher in concentration compared to C₂₃. The second group of compounds is comprised of succinates with methyl, fenchyl, bomyl and isobornyl alcohols. The composition of these diesters revealed the same equilibrium ratio between compounds with fenchyl, bornyl and isobornyl alcohols in all NP fractions. We suggest an early enzymatically controlled (bacterial) process in the formation of succinates during resin diagenesis from the biotic precursors, yielding the same characteristic ratio of the respective succinates in these ambers. These results show that all the ambers analyzed here fall into a common class of fossil resin, succinite (class Ia) independent of the sample location in Poland.     

Dynamic stratigraphy of composite peripheral unconformity in a foredeep basin

This study employs facies analysis and basic principles of sequence stratigraphy to correlate isolated outcrop sections and reveal the depositional history of the Chmielnik Formation – a prominent mid‐Serravalian clastic wedge formed on the basinward forebulge flank of the Polish Carpathian Foredeep. The coarse‐grained clastic wedge, up to 30 m thick and spanning ca 1·1 Ma within biozone NN6, consists of fluvio‐deltaic, foreshore and shoreface deposits with a range of large littoral sand bars, all enveloped in muddy offshore‐transition deposits. Its dynamic stratigraphy indicates rapid shoreline shifts and environmental changes due to the interplay of forebulge tectonism, sediment supply and third‐order eustatic cycles. A similar interplay of tectonism and eustasy is recognizable in the whole middle Miocene sedimentary succession deposited on the forebulge flank, demonstrating an extreme case of an accommodation‐controlled shelf and indicating tectonic cycles of the forebulge uplift and subsidence spanning ca 800 to 900 ka. The episodes of forebulge uplift correlate with the main pulses of orogen thrusting. The resulting composite peripheral unconformity differs markedly from the idealized model of a ‘steady‐state’ stepwise onlap driven by forebulge continuous retreat. It is concluded that the foredeep peripheral unconformities, instead of being simplified in accordance with this idealized model, should rather be studied in detail because they bear a valuable high‐resolution record of regional events and give unique insights into the local role of tectonics, eustasy and sediment supply.     

Hindcasting global temperature by evolutionary computation

Interpretation of changes of global temperature is important for our understanding of the climate system and for our confidence in projections for the future. Massive efforts have been devoted to improve the accuracy of reproducing the global temperature by the available climate models, but the hindcasts are still inaccurate. Notwithstanding the need to further advance climate models, one may consider data-driven approaches, providing practically useful results in a simpler and faster way. Without assuming any prior knowledge about physics and without imposing a model structure that encapsulates the existing knowledge about the underlying processes, we hindcast global temperature by automatically identified evolutionary computation models. We use 60 years of records of global temperature and climate drivers, with training and testing periods being 1950–1999 and 2000–2009, respectively. This paper demonstrates that the global temperature observed in the past is mimicked with reasonably good accuracy. Evolutionary computation holds promise for modeling the global climate system, which looks hopelessly complex in classical perspective.     

Blueschist facies metamorphism in Nordenskiöld Land of west‐central Svalbard

Recent fieldwork in Nordenskiöld Land, Svalbard's Southwestern Basement Province, has established the presence of high‐pressure (HP) lithologies. They are strongly retrogressed blueschists consisting mainly of garnet and Ca‐amphibole with remnants of ferroglaucophane and phengite. The pressure–temperature (P–T) conditions were estimated using phase equilibrium modelling in the NCKFMMnASHTO system. P–T estimates based on the garnet, phengite and ferroglaucophane compositional isopleths and modelled paragenetic assemblage indicate peak metamorphism at 470–490 °C and 14–18 kbar. These data fall close to the 7–8 °C km^?1 geotherm, which is similar to that from Motalafjella, the only previously known occurrence of blueschists in Svalbard's Caledonides. The newly discovered blueschists could have formed during the early stage of the Caledonian Orogeny and may represent a vestige of missing marginal basins of the western Iapetus developed at the onset of subduction. The likely counterpart to Svalbard's blueschists is the ophiolitic sequence in the Pearya Terrane of northern Ellesmere Island.     

Bias,variance and computational properties of Kijko’s estimators of the upper limit of magnitude distribution,M<Subscript>max</Subscript>

It is often assumed in probabilistic seismic hazard analysis that the magnitude distribution has an upper limit M _max, which indicates a limitation on event size in specific seismogeneic conditions. Accurate estimation of M _max from an earthquake catalog is a matter of utmost importance. We compare bias, dispersion and computational properties of four popular M _max estimators, introduced by Kijko and others (e.g., Kijko and Sellevoll 1989, Kijko and Graham 1998, Kijko 2004) and we recommend the ones which can be the most fruitful in practical applications. We provide nomograms for evaluation of bias and standard deviation of the recommended estimators for combinations of sample sizes and distribution parameters. We suggest to use the bias nomograms to correct the M _max estimates. The nomograms of standard deviation can be used to determine minimum sample size for a required accuracy of M _max.     

On a new hypothesis concerning the red shift

An attempt is presented to explain the red shift in terms of a theory based on two postulates: (1) perfect cosmological principle, and (2) postulate of the uniqueness of electromagnetic wavelength measurements. It is assumed that the space of events is a static space, and the red shift is a consequence of the geometry of that space. In terms of the accepted postulates a theorem has been proved, according to which the luminosity distanceD is related to the red shift Δλ/λ₀ by $$D = cT\frac{{\Delta \lambda /\lambda _0 }}{{1 + \Delta \lambda /\lambda _0 }},$$ wherec is the light velocity, andT, the Hubble constant. It is shown that this relation is in agreement with astronomical data concerning the red shift and the distribution of galaxies. The hypothesis does not lead to the necessity of accepting any assumptions concerning the creation of matter at the origin of time or a continuous creation of matter, which have been postulated by certain other theories.     

Studies of short and long memory in mining-induced seismic processes

Memory of a stochastic process implies its predictability, understood as a possibility to gain information on the future above the random guess level. Here we search for memory in the mining-induced seismic process (MIS), that is, a process induced or triggered by mining operations. Long memory is investigated by means of the Hurst rescaled range analysis, and the autocorrelation function estimate is used to test for short memory. Both methods are complemented with result uncertainty analyses based on different resampling techniques. The analyzed data comprise event series from Rudna copper mine in Poland. The studies show that the interevent time and interevent distance processes have both long and short memory. MIS occurrences and locations are internally interrelated. Internal relations among the sizes of MIS events are apparently weaker than those of other two studied parameterizations and are limited to long term interactions.