Concentrations of ten DDTs (2,2-bis-(chlorophenyl)-1,1,1-trichloroethane) of which p,p'-DDA (2,2-bis(chlorophenyl)acetic acid), p,p'-DDM (bis(chlorophenyl)methane) and p,p'-DBP (dichlorobenzophenone) are often neglected, were measured in 25 water and 25 sedimentary samples from Bohai Bay and its adjacent Haihe Basin. The ratio of o,p'-DDX/p,p'-DDX in the upper reaches of Yongdingxin River ranged from 0.71 to 2.44, suggesting that the potential source of pollution would be the manufacturing or use of dicofol near this river. While DDA accounted for 52-93% of the SigmaDDT concentration in water, DDA was only detected in three sedimentary samples. And DDM was found to be an important degradation product of DDT in water following DDA. It should be noted that DBP (0.60-3.30 ng/g) is a major metabolite comparable with DDE (2,2-bis(chlorophenyl)-1,1-dichloroethylene, nondetectable-1.80 ng/g) and DDD (2,2-bis-(chlorophenyl)-1,1-dichloroethane, nondetectable-2.86 ng/g) in sediment in Bohai Bay. Finally, the SigmaDDT concentration in sedimentary sample from Bohai Bay was found to be dependent on the TOC (total organic carbon) value. 相似文献
Based on paleomagnetic measurements and morphostratigraphy of red bed/clay sequences from pediments of the Liupan Shan and the Longdong Basin, the following results are revealed. The red bed/clay sediments became to accumulate at around 8.1 MaBP, which implied that the plantation surface developed since Late Cretaceous was broken by active fault, and its development was terminated. The Liupan Shan began to slightly uplift. The Liupan Shan experienced a small-scale uplift around 5.2 MaBP, inferred from the appearance of fine gravel sediments at that time. Consequently, a pediment was developed. The Liupan Shan accelerated uplift since about 3.8 MaBP at a large scale, which caused the deep incision of the rivers and the termination of fluvial and lacustrine deposition. Meanwhile, typical eolian red clay appeared since then. This uplift process is well correlated and in response to that of the Tibetan Plateau and the mountains around it.
