Three-dimensional hydrodynamic-eutrophication model (HEM-3D): application to Kwang-Yang Bay, Korea

The purpose of this paper is twofold: to describe the water quality model of Three-Dimensional Hydrodynamic-Eutrophication Model (HEM-3D) and to present an application of HEM-3D to a coastal system in Korea. HEM-3D, listed as a tool for the development of Total Maximum Daily Load by US Environmental Protection Agency, is a general-purpose modeling package for simulation of the flow field, transport, and eutrophication processes throughout the water column and of diagenetic processes in the benthic sediment. This paper describes the water quality model of HEM-3D with emphasis on its unique features. Excessive loadings of organic wastes have significantly deteriorated water quality conditions of Korean coastal waters. This paper presents an application of HEM-3D to Kwang-Yang Bay, a coastal system in Korea, which is one of the first water quality modeling efforts for Korean coastal waters accompanied by a relatively comprehensive field program. The current status of data availability for water quality modeling in Korea is discussed.     

Statistical assignment of upscaled flow functions for an ensemble of geological models

Upscaled flow functions are often needed to account for the effects of fine-scale permeability heterogeneity in coarse-scale simulation models. We present procedures in which the required coarse-scale flow functions are statistically assigned to an ensemble of upscaled geological models. This can be viewed as an extension and further development of a recently developed ensemble level upscaling (EnLU) approach. The method aims to efficiently generate coarse-scale flow models capable of reproducing the ensemble statistics (e.g., cumulative distribution function) of fine-scale flow predictions for multiple reservoir models. The most expensive part of standard coarsening procedures is typically the generation of upscaled two-phase flow functions (e.g., relative permeabilities). EnLU provides a means for efficiently generating these upscaled functions using stochastic simulation. This involves the use of coarse-block attributes that are both fast to compute and correlate closely with the upscaled two-phase functions. In this paper, improved attributes for use in EnLU, namely the coefficient of variation of the fine-scale single-phase velocity field (computed during computation of upscaled absolute permeability) and the integral range of the fine-scale permeability variogram, are identified. Geostatistical simulation methods, which account for spatial correlations of the statistically generated upscaled functions, are also applied. The overall methodology thus enables the efficient generation of coarse-scale flow models. The procedure is tested on 3D well-driven flow problems with different permeability distributions and variable fluid mobility ratios. EnLU is shown to capture the ensemble statistics of fine-scale flow results (water and oil flow rates as a function of time) with similar accuracy to full flow-based upscaling methods but with computational speedups of more than an order of magnitude.     

Phenol and ammonium removal by using Fe-ZSM-5 synthesized by ammonium citrate iron source

Fe-ZSM-5 zeolites are important for many applications, especially for catalysis and volatile organic carbon removal. However, the inclusion of a high content of iron in the ZSM-5 structure is hindered due to the high pH required for hydrothermal synthesis. To overcome this problem, the synthesis of Fe-ZSM-5 zeolites with a novel iron chelate complex as the iron source (ammonium iron citrate) and a common iron source (iron chloride) was investigated. The synthesized materials were characterized by XRD, BET, SEM, FTIR, XPS and ICP. The total iron content was determined by ICP. Fe-ZSM-5 zeolites prepared by the ammonium iron citrate source method contain the highest iron concentration within the framework of a Mobil five structure, which has a high surface area and crystallinity. The prepared materials were used to remove phenol and ammonium. The catalytic results demonstrated that Fe-ZSM-5 prepared with ammonium iron citrate is the best catalyst.     

Turbidity control in downstream of the reservoir: the Nakdong River in Korea

High turbid water in the river has been one of the major concerns to the downstream residence. During heavy local rainfall, high turbid water occurs in many countries located in the Asian monsoon climate region. The Andong and the Imha reservoir, two adjacent multipurpose dams, located in the upstream of the Nakdong River in Korea have suffered from severe turbid water problem. This study applied hydrodynamic water quality model CE-Qual-Riv1 to simulate turbidity propagation in downstream coupled with long-term watershed hydrologic model SWAT to consider contributions of tributaries. The outputs of runoff and suspended sediment in tributaries are incorporated into the input data necessary for the hydrodynamic water quality model. The simulation focused on the joint dam operation to minimize the negative impact of high turbid water in downstream river. Simulated turbidity in downstream shows a good agreement with the observed data, and the approach proposed in this study is applicable for establishing a sound turbid water management in downstream of the reservoir.     

Archaeological site distribution by geomorphic setting in the southern lower Cuyahoga River Valley,northeastern Ohio: Initial observations from a GIS database

In this study, we compiled unpublished archival documentation of archaeological site locations from the southern part of the Cuyahoga River Valley in northeastern Ohio, USA, registered at the State of Ohio Historic Preservation Office into a Geographic Information Systems (GIS) database. Using digitized soil shapefiles to generate a geomorphic data layer, we assessed the spatial and temporal distribution of 79 known archaeological sites by landform association. This digital compilation indicates that Woodland period, Late Prehistoric, and Historic sites occur in most geomorphic settings along the river valley. In contrast, Paleoindian and Archaic sites only occur on Wisconsinan cut terraces and in upland interfluve settings, indicating that most of these documented sites are in primary contexts and have not been reworked. We discuss the distribution of archaeological sites in the study region as a function of various factors, including cultural activities, taphonomic processes, landform development, and the nature and extent of the original archaeological surveys. Observed spatial patterns of known sites clearly reflect local geomorphological controls; artifactual contexts from the earlier prehistoric periods are underrepresented in the database. We conclude that additional site surveys, as well as the excavation and documentation of new sites in this part of Ohio, are required to understand local prehistoric economies and to ascertain patterns of culturally mediated land use. © 2004 Wiley Periodicals, Inc.     

Sedimentological characteristics and new detrital zircon SHRIMP U–Pb ages of the Babulu Formation in the Fohorem area,Timor-Leste

Sedimentological characteristics and zircon provenance dating of the Babulu Formation in the Fohorem area, Timor-Leste, provide new insights into depositional process, detailed sedimentary environment and the distribution of source rocks in the provenance. Detrital zircon sensitive high-resolution ion microprobe (SHRIMP) U–Pb ages range from Neoarchean to Triassic, with the main age pulses being Paleozoic to Triassic. In addition, the maximum deposition ages based on the youngest major age peak (ca 256–238 Ma) of zircon grains indicate that the basal sedimentation of the Babulu Formation occurred after the early Upper Triassic. The formation consists predominantly of mudstone with minor sandstone, limestone and conglomerate that were deposited in a deep marine environment. These deposits are composed of six lithofacies that can be grouped into three facies associations (FAs) based on the constituent lithofacies and bedding features: basin plain deposits (FA I), distal fringe lobe deposits (FA II) and medial to distal lobe deposits (FA III). The predominance of mudstone (FA I) together with intervening thin-bedded sandstones (FA II) suggest that the paleodepositional environment was a low energy setting with slightly basin-ward input of the distal part of the depositional lobes. Discrete and abrupt occurrences of thick-bedded sandstone (FA III) within the FA I mudstone suggests that sandstone originated from a collapse of upslope sediments rather than a progressive progradation of deltaic turbidites. This combined petrological and geochronological study demonstrates that the Babulu Formation in the Fohorem area of the Timor-Leste was initiated as a submarine lobe system in a relatively deep marine environment during the Upper Triassic and represents the extension of the Gondwana Sequence at the Australian margin.     

Emission estimates of methyl chloride from industrial sources in China based on high frequency atmospheric observations

Methyl Chloride (CH₃Cl) is a chlorine-containing trace gas in the atmosphere contributing significantly to stratospheric ozone depletion (Carpenter et al. 2014). In the global CH₃Cl budget, the atmospheric CH₃Cl emissions is predominantly maintained by natural sources, of which magnitudes have been relatively well-constrained. However, significant uncertainties still remain in the CH₃Cl emission strengths from anthropogenic sources. High-frequency and high-precision in situ measurements of atmospheric CH₃Cl concentrations obtained since 2008 at Gosan station (a remote background site in the East Asia) reveal significant pollution events superimposed on the seasonally varying regional background levels. Back trajectory statistics showed that air masses corresponding to the observed CH₃Cl enhancement largely originated from regions of intensive industrial activities in China. Based on an inter-species correlation method, estimates of CH₃Cl emissions from manufacturing industries including coal combustion, use of feedstocks, or process agents in chemical production for China (2008–2012) are 297 ± 71 Gg yr.^?1 in 2008 to 480 ± 99 Gg yr.^?1 in 2009, followed by a gradual decrease of about 25% between 2009 and 2012 (398 ± 92 Gg yr.^?1 for 2010; 286 ± 68 Gg yr.^?1 for 2011; 358 ± 92 Gg yr.^?1 for 2012). The annual average of industrial CH₃Cl emissions for 2008–2012 (363 ± 85 Gg yr.^?1) in China is comparable to the known total global anthropogenic CH₃Cl emissions accounting only for coal combustion and indoor biofuel use. This may suggest that unless emissions from the chemical industry are accounted for, global anthropogenic emissions of CH₃Cl have been substantially underestimated. In particular, since industrial production and use of CH₃Cl have not been regulated under the Montreal Protocol (MP) or its successor amendments, continuous monitoring of Chinese CH₃Cl outflow is important to properly evaluate its anthropogenic emissions.     

Four-dimensional variational data assimilation for mesoscale and storm-scale applications

Summary ?The status and progress of the four-dimensional variational data assimilation (4DVAR) are briefly reviewed focusing on application to prediction of mesoscale/storm-scale atmospheric phenomena. Theoretical background is provided for each important component of the 4DVAR system – forecast and adjoint models, observations, background, cost function, preconditioning, and minimization. An overview of practical issues specific for mesoscale/storm-scale 4DVAR is then presented in terms of high-resolution observations, nonlinearity and discontinuity problem, model error, errors from lateral boundary condition, and precipitation assimilation. Practical strategies for efficient and simplified 4DVAR are also introduced, e.g., incremental 4DVAR, poor man’s 4DVAR, and inverse 3DVAR. A new concept on hybrid approach is proposed to combine an efficient 4DVAR scheme and the standard 4DVAR scheme aiming at reducing computational demand required by the standard 4DVAR while improving the accuracy of the simplified 4DVAR. Applications to both hydrostatic and nonhydrostatic models are illustrated and our vision on opportunities and directions for future research is provided. Received March 12, 2001; revised July 24, 2001; accepted September 5, 2001