Distribution of the CO2 partial pressure along an Atlantic meridional transect

Atmospheric and oceanic pCO₂ were measured continuously along an Atlantic Meridional transect (50°N–50°S) in September–October 1995 and 1996 (U.K. to the Falklands Islands) and in April–May 1996 (Falklands Islands to the UK). The Atlantic ocean was a net sink for atmospheric CO₂ for all 3 transects. The largest sinks were located at high latitudes, in regions of high wind speed, where strong CO₂ undersaturations, associated with high biological activity, were observed. In these regions the partial pressure difference between the ocean and the atmosphere reached −110 μatm. A CO₂ source occurred in the equatorial region between 0° and 10°S, where ΔpCO₂ of up to 40 μatm was found. Another source was in the northern subtropical gyre where its extension varied according to the season. Along the whole transect the October cruises exhibited similar pCO₂ distributions suggesting a dominance of the seasonal variability and small year to year changes.     

Recruitment patterns of Serpula vermicularis L. (Polychaeta, Serpulidae) in Loch Creran, Scotland

This study aimed to contribute to conservation management of reefs of Serpula vermicularis by increasing understanding of the factors influencing larval settlement. The study was carried out in Loch Creran, which supports the most extensive known development of S. vermicularis reefs in the world. Settlement plates were deployed to examine the influence of season, depth, reef density, substrate type and orientation. Monthly deployment of plates revealed settlement of S. vermicularis to occur predominantly from mid-June to mid-October, peaking in late August to early September. Settlement of Pomatoceros spp. peaked much earlier, in late May to early June. Deployment of plates at different depths revealed a marked reduction in S. vermicularis settlement intensity between 6 and 12 m. As this corresponds with the deeper limit of the peripheral fringe of serpulid reefs in the loch, it is suggested that this limit is imposed by a depth-correlated settlement response, rather than reduction in available substrata. Comparisons of various substrata showed a preference by S. vermicularis larvae for a slate over a scallop substrate and no evidence of enhanced recruitment to occupied or unoccupied tubes of S. vermicularis, suggesting that gregarious attraction is unlikely to be a factor causing reef formation. Settlement onto the upper side of a horizontal scallop substrate was found to be insignificant in comparison with the underside or a vertically orientated scallop. Evidence for the role of light in controlling the depth and substrate-orientation preferences of S. vermicularis larvae is discussed. Based on the results of this study, recommendations are made regarding remediation of areas suffering reef damage.     

The Aristarchus-Harbinger region of the moon: Surface geology and history from recent remote-sensing observations

The region including the Aristarchus Plateau and Montes Harbinger is probably the most diverse, geologically, of any area of comparble size on the Moon. This part of the northwest quadrant of the lunar near side includes unique dark mantling material; both the densest concentration and the largest of the sinuous rilles; apparent volcanic vents, sinks, and domes; mare materials of various ages and colors; one of the freshest large craters (Aristarchus) with ejecta having unique colors and albedos; and three other large craters in different states of flooding and degradation (krieger, Herodotus, and Prinz). The three best-authenticated lunar transient phenomena were also observed here.This study is based principally on photographic and remote sensing observations made from Earth and Apollo orbiting space craft. Results include (1) delineation of geologic map units and their stratigraphic relationships; (2) discussion of the complex interrelationships between materials of volcanic and impact origin, including the effects of excavation, redistribution and mixing of previously deposited materials by younger impact craters; (3) deduction of physical and chemical properties of certain of the geologic units, based on both the remote-sensing information and on extrapolation of Apollo data to this area; and (4) development of a detailed geologic history of the region, outlining the probable sequence of events that resulted in its present appearance.A primary concern of the investigation has been anomalous red dark mantle on the Plateau. Based on an integration of Earth- and lunar orbit-based data, this layer seems to consist of fine-grained, block-free material containing a relatively large fraction of orange glass. It is probably of pyroclastic origin, laid down at some time during the Imbrian period of mare flooding.     

Large-scale galactic turbulence: can self-gravity drive the observed H i velocity dispersions?

Observations of turbulent velocity dispersions in the H  i component of galactic discs show a characteristic floor in galaxies with low star formation rates and within individual galaxies the dispersion profiles decline with radius. We carry out several high-resolution adaptive mesh simulations of gaseous discs embedded within dark matter haloes to explore the roles of cooling, star formation, feedback, shearing motions and baryon fraction in driving turbulent motions. In all simulations the disc slowly cools until gravitational and thermal instabilities give rise to a multiphase medium in which a large population of dense self-gravitating cold clouds are embedded within a warm gaseous phase that forms through shock heating. The diffuse gas is highly turbulent and is an outcome of large-scale driving of global non-axisymmetric modes as well as cloud–cloud tidal interactions and merging. At low star formation rates these processes alone can explain the observed H  i velocity dispersion profiles and the characteristic value of  ∼10 km s⁻¹  observed within a wide range of disc galaxies. Supernovae feedback creates a significant hot gaseous phase and is an important driver of turbulence in galaxies with a star formation rate per unit area  ≳10⁻³ M_⊙ yr⁻¹ kpc⁻²  .     

The Regional Ocean Modeling System (ROMS) 4-dimensional variational data assimilation systems: Part II - Performance and application to the California Current System

The Regional Ocean Modeling System (ROMS) 4-dimensional variational (4D-Var) data assimilation systems have been systematically applied to the mesoscale circulation environment of the California Current to demonstrate the performance and practical utility of the various components of ROMS 4D-Var. In particular, we present a comparison of three approaches to 4D-Var, namely: the primal formulation of the incremental strong constraint approach; the dual formulation “physical-space statistical analysis system”; and the dual formulation indirect representer approach. In agreement with theoretical considerations all three approaches converge to the same ocean circulation estimate when using the same observations and prior information. However, the rate of convergence of the dual formulation was found to be inferior to that of the primal formulation. Other aspects of the 4D-Var performance that relate to the use of multiple outer-loops, preconditioning, and the weak constraint are also explored. A systematic evaluation of the impact of the various components of the 4D-Var control vector (i.e. the initial conditions, surface forcing and open boundary conditions) is also presented. It is shown that correcting for uncertainties in the model initial conditions exerts the largest influence on the ability of the model to fit the available observations. Various important diagnostics of 4D-Var are also examined, including estimates of the posterior error, the information content of the observation array, and innovation-based consistency checks on the prior error assumptions. Using these diagnostic tools, we find that more than 90% of the observations assimilated into the model provide redundant information. This is a symptom of the large percentage of satellite data that are used and to some extent the nature of the data processing employed. This is the second in a series of three papers describing the ROMS 4D-Var systems.     

Upwelling in the Alaskan Beaufort Sea: Atmospheric forcing and local versus non-local response

The spin up and relaxation of an autumn upwelling event on the Beaufort slope is investigated using a combination of oceanic and atmospheric data and numerical models. The event occurred in November 2002 and was driven by an Aleutian low storm. The wind field was strongly influenced by the pack-ice distribution, resulting in enhanced winds over the open water of the Chukchi Sea. Flow distortion due to the Brooks mountain range was also evident. Mooring observations east of Barrow Canyon show that the Beaufort shelfbreak jet reversed to the west under strong easterly winds, followed by upwelling of Atlantic Water onto the shelf. After the winds subsided a deep eastward jet of Atlantic Water developed, centered at 250 m depth. An idealized numerical model reproduces these results and suggests that the oceanic response to the local winds is modulated by a propagating signal from the western edge of the storm. The disparity in wave speeds between the sea surface height signal—traveling at the fast barotropic shelf wave speed—versus the interior density signal—traveling at the slow baroclinic wave speed—leads to the deep eastward jet. The broad-scale response to the storm over the Chukchi Sea is investigated using a regional numerical model. The strong gradient in windspeed at the ice edge results in convergence of the offshore Ekman transport, leading to the establishment of an anti-cyclonic gyre in the northern Chukchi Sea. Accordingly, the Chukchi shelfbreak jet accelerates to the east into the wind during the storm, and no upwelling occurs west of Barrow Canyon. Hence the storm response is fundamentally different on the Beaufort slope (upwelling) versus the Chukchi slope (no upwelling). The regional numerical model results are supported by additional mooring data in the Chukchi Sea.     

The formation and stability of carbonic acid on outer Solar System bodies

The radiation chemistry, thermal stability, and vapor pressure of solid-phase carbonic acid (H₂CO₃) have been studied with mid-infrared spectroscopy. A new procedure for measuring this molecule’s radiation stability has been used to obtain intrinsic IR band strengths and half-lives for radiolytic destruction. We report, for the first time, measurements of carbonic acid’s vapor pressure (0.290-2.33 × 10⁻¹¹ bar for 240-255 K) and its enthalpy of sublimation (71 ± 9 kJ mol⁻¹). We also report the first observation of a chemical reaction involving solid-phase carbonic acid. Possible applications of these findings are discussed, with an emphasis on the outer Solar System icy surfaces.     

Trace-element distribution in an active hydrothermal system, Roosevelt hot springs thermal area, Utah

Chemical interaction of thermal fluids with reservoir rock in the Roosevelt Hot Springs thermal area, Utah, has resulted in the development of characteristic trace-element dispersion patterns. Multielement analyses of surface rock samples, soil samples and drill cuttings from deep exploration wells provide a three-dimensional perspective of chemical redistribution within this structurally-controlled hot-water geothermal system.Five distinctive elemental suites of chemical enrichment are recognized, each characteristic of a particular combination of physical and chemical conditions within the geothermal system. These are: (1) concentrations of As, Sb, Be, and Hg associated with siliceous material at locations of liquid discharge, fluid mixing or boiling; (2) concentrations of Mn, Ba, W, Be, Cu, Co, As, Sb and Hg in manganese and iron oxide deposits; (3) high concentrations of Hg in argillized rock near fumaroles and lower concentrations in a broad diffuse halo surrounding the thermal center; (4) concentrations of As in sulfides and Li in silicate alteration minerals immediately surrounding high-temperature fluid flow-controlling fractures; (5) deposits of CaCO₃ at depth where flashing of brine to steam has occurred due to pressure release. The geochemical enrichments are not, in general, widespread, pervasively developed zones of regular form and dimension as are typical in many ore-forming hydrothermal systems.As the geothermal system develops, changes and eventually declines through time, the chemical deposits are developed, remobilized or superimposed upon each other, thus preserving within the rocks a record of the history of the geothermal system. Recognition of trace-element distribution patterns during the exploration of a geothermal system may aid definition of the present geometry and interpretation of the history of the system.