顶空气相色谱法测定地层水中的苯系物

利用极性聚乙二醇弹性石英毛细管柱分离苯系物，在线顶空气相色谱法测定地层水中的苯系物。讨论了色谱柱、载气压力、液相体积、顶空压力、顶空加热温度等因素对测定的影响。该方法实现了地层水中苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、异丙苯、苯乙烯等各组分的完全分离，方法的检出限在0．07—0．23μg／L，8次测定相对标准偏差在2．98％-4．91％，加标回收率为95．2％-104％。方法可用于地层水等液体样品中苯系物的测定。     

铜陵地区中生代中酸性侵入岩的地球化学特征及其成矿-地球动力学意义

本文对铜陵地区晚侏罗世-早白垩世高钾钙碱性中酸性侵入岩进行了研究,发现该类岩体具有埃达克岩的地球化学特征,具体表现为:SiO2≥56％,Al2O3含量高(>15％),Na2O/K2O>1,亏损HREE,(La/Yb)N>12,负Eu异常不明显(Eu*/Eu=0.71-0.96),Sr含量高(>750μg/g),Sr/Y比值高(>38)。但是,由于岩石的K2O含量较高、εNd(t)较低和ISr值较高,又不同于典型的与板块俯冲有关的埃达克岩,而与中国东部中生代的C型埃达克岩比较类似,暗示铜陵地区的高钾钙碱性岩可能是加厚的下地壳底部基性岩部分熔融的产物。本文主要依据铜陵埃达克质岩的HREE特征,将其分为三类:第一类岩体为HREE平坦型,Yb含量较高(>1.8μg/g);第二类为HREE平坦型,Yb<1.8μg/g,(Ho/Yb)N≈1;第三类岩体HREE亏损,Yb<1.8μg/g,(Ho/Yb)N<1.2。上述三类岩石地球化学性质上的差异不太可能是分离结晶作用或地壳混染的 结果,而可能是由于幔源岩浆与下地壳物质混合的程度不同引起源区成分不同形成的。铜陵地区及中国东部埃达克质岩石可能代表了中国东部中生代时的地壳增生和加厚过程。铜陵埃达克岩主要是古老下地壳和底侵玄武岩不同比例混合部分熔融形成的,在岩浆演化过程中可能还不同程度地叠加了分离结晶作用和岩浆混合作用的影响。铜陵埃达克岩具岛弧特征,但并不表明其     

Origin and tectonic significance of a Mesozoic multi-layer over-thrust system within the Yangtze Block (South China)

In the Yangtze Block (South China), a well-developed Mesozoic thrust system extends through the Xuefeng and Wuling mountains in the southeast to the Sichuan basin in the northwest. The system comprises both thin- and thick-skinned thrust units separated by a boundary detachment fault, the Dayin fault. To the northwest, the thin-skinned belt is characterized by either chevron anticlines and box synclines to the northwest or chevron synclines to the southeast. The former structural style displays narrow exposures for the cores of anticlines and wider exposures for the cores of synclines. Thrust detachments occur along Silurian (Fs) and Lower Cambrian (Fc) strata and are dominantly associated with the anticlines. To the southeast, this style of deformation passes gradually into one characterized by chevron synclines with associated principal detachment faults along Silurian (Fs), Cambrian (Fc) and Lower Sinian (Fz) strata. There are, however, numerous secondary back thrusts. Therefore, the thin-skinned belt is like the Valley and Ridge Province of the North American Applachian Mountains. The thick-skinned belt structurally overlies the thin-skinned belt and is characterized by a number of klippen including the Xuefeng and Wuling nappes. It is thus comparable to the Blue Ridge Province of Appalachia.The structural pattern of this thrust system in South China can be explained by a model involving detachment faulting along various stratigraphic layers at different stages of its evolution. The system was developed through a northwest stepwise progression of deformation with the earliest delamination along Lower Sinian strata (Fz). Analyses of balanced geological cross-sections yield about 18.1–21% (total 88 km) shortening for the thin-skinned unit and at least this amount of shortening for the thick-skinned unit. The compressional deformation from southeast to northwest during Late Jurassic to Cretaceous time occurred after the westward progressive collision of the Yangtze Block with the North China Block and suggests that the orogenic event was intracontinental in nature.     

用时间序列模拟和预报天山乌鲁木齐河源1号冰川年径流总量

本文把1958—1984年天山乌鲁木齐河源1号冰川的融水径流总量的时间序列X(t),分解为趋势项L(t)、周期项P(t)、平稳项S(t)、随机项ε(t),使该时间序列表示为X(t)=L(t)+P(t)+S(t)+ε(t)。采用非线性回归提取L(t),用谱分析和Fourier级数提取P(t),余差用自回归方程建模,用上述项的叠加作出预报,按相关指数公式计算R=0.90,效果良好。     

大坪金矿床石英的标型特征及其地质意义

文章论述石英的物理性质、化学成分、包裹体特征及同位素组成,从而提供了有关大坪金矿床的成矿作用、矿床成因及找矿远景等方面的矿物学标志.     

Stable Isotope Composition of Rainfall,Surface Water and Groundwater along the Yellow River

The intention of this work is to consider the stable isotopic compositions of oxygen and deuterium in rainfall, surface water and groundwater along the Yellow River in the North China Plain (NCP). This demonstrated that the δ18O values in groundwater varied from –10.17 to –6.85‰, with mean value of –8.76‰, and that the δD ranged from –68.7 to –58.0‰, with mean value of –63.4‰, respectively. The δ18O values in surface water varied from –8.36 to 1.32‰, with mean value of –6.8‰, and δD ranged from –64.4 to –35.1‰, with mean value of –57.6‰, respectively. Further, The range of Cl- values of groundwater varied from 5.9 to 340.5 mg/L and that values ranged from 30.1 to 81.9 mg/L in surface water samples and Na+ value changed from 27.4 to 321 mg/L in groundwater, while that in surface water varied from 24.8 to 50.5 mg/L. Most of the points fall below the GMWL?, but are close to the LMWL.? Therefore the results indicated that the groundwaters along the Yellow River were influenced by rainfall in heavy events and surface water.     

塔里木盆地侏罗-白垩纪古气候研究

以沉积学理论为指导,结合岩石学和矿物学等学科,通过对塔里木盆地岩相和重矿物类型和组合及其稳定性等的分析,详细探讨了塔里木盆地侏罗纪—白垩纪的岩相特征,并重建古气候的演化特征。塔里木盆地侏罗纪主要属于温暖湿润气候,晚侏罗纪后期到早白垩世属于干旱炎热气候。     

Complexation of Si in hydrothermal systems

The Au-SiO2 and Sn-SiO2 complexes have been experimentally calibrated at varying temperature,silica comcentration and pH: Au^ H2SiO4^-=AuH3SiO4 lgK=-1.65436 9611.21/T; Sn^4 4H3SiO4^-=Sn(H3SiO4)4 lgK200℃=42.73 Compared with Au-Cl,Au-HS and Sn-OH complexes,AuH3SiO4 and Sn(H3SiO4)4complexes can be recognized as the dominant transport forms in Si-bearing solurtions under pH and Eh conditions of general interest.The decrease of SiO2 concentration and oxygen fugacity would reverse the direction of dissolution-complexing reactions,resulting in the precipitation of gold and silica,as well as cassiterite and silica.This study illustrates the significance of SiO2-complexation in hydrothermal solutions for gold,tin and other metallizations.     

Vulnerability of groundwater systems with sea level rise in coastal aquifers, South Korea

Groundwater systems in coastal aquifers may be affected by sea level change as increased seawater intrusion occurs with sea level rise. Artificial pumping taking place at the same time will increase this impact. In order to estimate the vulnerability of groundwater systems with sea level rise within coastal aquifers in South Korea, long-term groundwater data were analyzed using basic statistics, trend analysis, and correlation analysis. Conductivity depth profiling was also periodically conducted. Groundwater levels increased in wells with relatively low groundwater elevations but decreased in wells with higher groundwater elevations. At the same time, conductivity variations were greater in wells located in reclaimed land areas, which vertical conductivity profiles indicated were more affected by sea level variations, but decreased on the mainland. Results of auto-correlation analysis showed a decreasing trend with cyclic variations and significant periodic patterns during dry seasons, indicating that groundwater levels were not affected by artificial factors and that those in reclaimed land areas were less affected by rainfall than on the mainland. These results coincided with those from cross-correlation analysis showing that groundwater level was affected by sea level variation during the dry season. Sea level changes, which may be related to climate change, as well as rainfall in South Korea can influence groundwater levels, and the groundwater system in reclaimed land areas may be more affected than on the mainland, especially under dry conditions.     

桂林典型岩溶峰丛洼地碳储量功能研究

为了揭示不同发展模式下土地利用变化对碳储量的影响,以桂林市阳朔县兴坪镇西塘村的岩溶峰丛洼地为对象,采用InVEST模型对岩溶峰丛洼地的碳储量进行评估,并模拟2种情境（生态保护模式、经济发展模式）下植被类型对碳储量的影响。结果表明：研究区碳储量总量是16 641.68 t,碳密度是221.30 t·hm⁻²,经济总价值是1 997.00 万元,单位面积价值是26.56 万元·hm⁻²;人工林、自然林、经济林生态系统碳储量分别是339.38 t·hm⁻²、261.79 t·hm⁻²、150.34 t·hm⁻²,经济价值分别是40.72 万元·hm⁻²、31.42万元·hm⁻²、18.04万元·hm⁻²,且土壤碳储量是生态系统中最大碳库;自然林和经济林中土壤是最大的碳汇,而人工林中土壤和地上植被的碳汇较大;生态保护模式下研究区碳储量经济价值是2 252.14 万元,相比于现状增加了254.89 万元;经济发展模式下研究区碳储量经济价值是1 595.30 万元,相比于现状损失了401.95 万元。该研究成果为桂林漓江风景名胜区核心景区和桂林喀斯特世界自然遗产地确定未来发展模式和石漠化治理提供参考。