Paleolimnological records reveal biotic homogenization driven by eutrophication in tropical reservoirs

Biodiversity changes in response to eutrophication, climate variability and species invasions. These pressures have been shown to reduce community heterogeneity at various scales; however, how productivity drives homogenization patterns in a community of primary producers, such as diatoms, has not been studied. Using a dataset with good temporal resolution, obtained from cores collected from seven tropical reservoirs, we evaluated patterns of spatial and temporal homogenization, i.e. the trends in temporal α-diversity and spatial β-diversity (change in community composition), of diatom assemblages over the past 60–100 years. The paleolimnological records allowed us to study biodiversity trends since the initial community (reservoir construction) in those systems with low anthropogenic impact and also those undergoing eutrophication. No clear trend of spatial β-diversity change over time was found when all reservoirs were analyzed together. However, when only eutrophic reservoirs were considered, a marked decrease in the spatial β-diversity occurred, suggesting that eutrophication leads to homogenization of the diatom assemblage. These findings were reinforced by the lack of change in β-diversity when the age of the reservoirs was standardized, indicating that the reservoirs’ ontogeny did not influence the spatial β-diversity trend and β-diversity did not increase even in the reservoirs with low anthropogenic impact. In addition, the results showed a decrease of α-diversity over time for almost all the eutrophic reservoirs, as well as a decrease in the total species pool for the reservoirs, although periphytic diatoms may be favored by the appearance and sometimes mass development of floating macrophytes in warm, shallow eutrophic reservoirs. This study supports the role of eutrophication as one of the main drivers of diatom assemblage homogenization in tropical reservoirs, with a significant loss of species over time.     

A Mini‐Review of E‐Waste Management in Brazil: Perspectives and Challenges

The accelerated production and replacement of new electrical and electronic equipment demonstrates a tendency for the proportional increase in the generation of e‐waste. Developing countries experience similar social and environmental consequences from this trend, which compounds the other challenges associated with the already poor solid waste management in these regions. Moreover, the dangerous composition of some e‐waste amplifies the problems related to managing these materials. This mini‐review presents a brief overview of e‐waste management in Brazil, including technical aspects, scientific studies, and the challenges ahead. With the Brazilian National Policy of Solid Waste already in place, technical and scientific studies endorse measures that range from incorporating the informal recycling sector into the e‐waste management sector to encouraging the expansion of the recycling industry. All such actions, combined with an intensified commitment of electronic equipment manufacturers to reverse logistics, can improve e‐waste management in Brazil.     

Experimental determination of magnesia and silica solubilities in graphite-saturated and redox-buffered high-pressure COH fluids in equilibrium with forsterite + enstatite and magnesite + enstatite

We experimentally investigated the dissolution of forsterite, enstatite and magnesite in graphite-saturated COH fluids, synthesized using a rocking piston cylinder apparatus at pressures from 1.0 to 2.1 GPa and temperatures from 700 to 1200 °C. Synthetic forsterite, enstatite, and nearly pure natural magnesite were used as starting materials. Redox conditions were buffered by Ni–NiO–H₂O (ΔFMQ = ??0.21 to ??1.01), employing a double-capsule setting. Fluids, binary H₂O–CO₂ mixtures at the P, T, and fO₂ conditions investigated, were generated from graphite, oxalic acid anhydrous (H₂C₂O₄) and water. Their dissolved solute loads were analyzed through an improved version of the cryogenic technique, which takes into account the complexities associated with the presence of CO₂-bearing fluids. The experimental data show that forsterite?+?enstatite solubility in H₂O–CO₂ fluids is higher compared to pure water, both in terms of dissolved silica (mSiO₂?=?1.24 mol/kg_H2O versus mSiO₂?=?0.22 mol/kg_H2O at P?=?1 GPa, T?=?800 °C) and magnesia (mMgO?=?1.08 mol/kg_H2O versus mMgO?=?0.28 mol/kg_H2O) probably due to the formation of organic C–Mg–Si complexes. Our experimental results show that at low temperature conditions, a graphite-saturated H₂O–CO₂ fluid interacting with a simplified model mantle composition, characterized by low MgO/SiO₂ ratios, would lead to the formation of significant amounts of enstatite if solute concentrations are equal, while at higher temperatures these fluid, characterized by MgO/SiO₂ ratios comparable with that of olivine, would be less effective in metasomatizing the surrounding rocks. However, the molality of COH fluids increases with pressure and temperature, and quintuplicates with respect to the carbon-free aqueous fluids. Therefore, the amount of fluid required to metasomatize the mantle decreases in the presence of carbon at high P–T conditions. COH fluids are thus effective carriers of C, Mg and Si in the mantle wedge up to the shallowest level of the upper mantle.     

High Resolution Simulation of the Variability of Surface Energy Balance Fluxes Across Central London with Urban Zones for Energy Partitioning

The parameterization of surface heat-flux variability in urban areas relies on adequate representation of surface characteristics. Given the horizontal resolutions (e.g. $\approx $ 0.1–1 km) currently used in numerical weather prediction (NWP) models, properties of the urban surface (e.g. vegetated/built surfaces, street-canyon geometries) often have large spatial variability. Here, a new approach based on Urban Zones to characterize Energy partitioning (UZE) is tested within a NWP model (Weather Research and Forecasting model; WRF v3.2.1) for Greater London. The urban land-surface scheme is the Noah/Single-Layer Urban Canopy Model (SLUCM). Detailed surface information (horizontal resolution 1 km) in central London shows that the UZE offers better characterization of surface properties and their variability compared to default WRF-SLUCM input parameters. In situ observations of the surface energy fluxes and near-surface meteorological variables are used to select the radiation and turbulence parameterization schemes and to evaluate the land-surface scheme and choice of surface parameters. For radiative fluxes, improved performance (e.g. $>$ 25 W m $^{-2}$ root-mean-square error reduction for the net radiation) is attained with UZE parameters compared to the WRF v3.2.1 default for all three methods from the simplest to the most detailed. The UZE-based spatial fluxes reproduce a priori expectations of greater energy storage and less evaporation in the dense city centre compared to the residential surroundings. Problems in Noah/SLUCM partitioning of energy between the daytime turbulent fluxes are identified with the overestimation of the turbulent sensible heat and underestimation of the turbulent latent heat fluxes.     

Effects of fish farm waste on Posidonia oceanica meadows: synthesis and provision of monitoring and management tools

This paper provides a synthesis of the EU project MedVeg addressing the fate of nutrients released from fish farming in the Mediterranean with particular focus on the endemic seagrass Posidonia oceanica habitat. The objectives were to identify the main drivers of seagrass decline linked to fish farming and to provide sensitive indicators of environmental change, which can be used for monitoring purposes. The sedimentation of waste particles in the farm vicinities emerges as the main driver of benthic deterioration, such as accumulation of organic matter, sediment anoxia as well as seagrass decline. The effects of fish farming on P. oceanica meadows are diverse and complex and detected through various metrics and indicators. A safety distance of 400 m is suggested for management of P. oceanica near fish farms followed by establishment of permanent seagrass plots revisited annually for monitoring the health of the meadows.     

Boron isotope composition of geothermal fluids and borate minerals from salar deposits (central Andes/NW Argentina)

We have measured the boron concentration and isotope composition of regionally expansive borate deposits and geothermal fluids from the Cenozoic geothermal system of the Argentine Puna Plateau in the central Andes. The borate minerals borax, colemanite, hydroboracite, inderite, inyoite, kernite, teruggite, tincalconite, and ulexite span a wide range of δ¹¹B values from −29.5 to −0.3‰, whereas fluids cover a range from −18.3 to 0.7‰. The data from recent coexisting borate minerals and fluids allow for the calculation of the isotope composition of the ancient mineralizing fluids and thus for the constraint of the isotope composition of the source rocks sampled by the fluids. The boron isotope composition of ancient mineralizing fluids appears uniform throughout the section of precipitates at a given locality and similar to values obtained from recent thermal fluids. These findings support models that suggest uniform and stable climatic, magmatic, and tectonic conditions during the past 8 million years in this part of the central Andes. Boron in fluids is derived from different sources, depending on the drainage system and local country rocks. One significant boron source is the Paleozoic basement, which has a whole-rock isotopic composition of δ¹¹B=−8.9±2.2‰ (1 SD); another important boron contribution comes from Neogene-Pleistocene ignimbrites (δ¹¹B=−3.8±2.8‰, 1 SD). Cenozoic andesites and Mesozoic limestones (δ¹¹B≤+8‰) provide a potential third boron source.     

On the Use of Interferometric Synthetic Aperture Radar Data for Monitoring and Forecasting Natural Hazards

Mathematical Geosciences - Recent advances in satellite technologies, statistical and mathematical models, and computational resources have paved the way for operational use of satellite data in...     

Intercalibration of Mg Isotope Delta Scales and Realisation of SI Traceability for Mg Isotope Amount Ratios and Isotope Delta Values

The continuous improvement of analytical procedures using multi‐collector technologies in ICP‐mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM‐AE143, ERM‐AE144, ERM‐AE145, IRMM‐009 and NIST SRM 980 were cross‐calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ^25/24Mg values and less than 0.037‰ for the δ^26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM‐AE143 anchors all magnesium δ‐scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM‐AE144 and ERM‐AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θ_app, the fractionation relationship ln α(^25/24Mg)/ln α(^26/24Mg).     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: IV. Lacustrine paleoecology

Fossil invertebrates from cores collected in Lake Tanganyika provide a record of probable nearshore ecological response to recent watershed deforestation and sediment erosion in several East African watersheds. We compared paleoecological profiles (primarily from ostracodes) from watersheds spanning a range of sizes and present-day deforestation disturbance levels to understand the timing and magnitude of faunal changes, and their relationship in time to terrestrially-derived disturbance indicators. Profiles from the Lubulungu and Nyasanga/Kahama Rivers (Tanzania) provide a record of faunal variability in watersheds that are currently undisturbed with respect to deforestation. These records indicate continuous faunal turnover through time. However, this pattern of turnover is accompanied by relatively high levels of diversity throughout the record, with no wholesale extinction events. Ostracode taphonomic data and other fossil abundance data from the Lubulungu area provide strong evidence in support of at least two episodes of lower lake levels, associated with episodes of Late Holocene aridity. Records from deltas of disturbed watersheds at the Kabesi River (Tanzania) and those of Northern Burundi all show a combination of profound and abrupt faunal turnover, in some cases accompanied by local extinction and establishment of a few dominant taxa. At the Mwamgongo River delta, fed from a very small, disturbed watershed, species turnover was subtler. In disturbed watershed cores showing abrupt faunal changes the transitions mostly occurred in the late 19th to early 20th centuries, predating the major mid-20th century increase in sediment mass accumulation rates, with the latter only correlated with changing fossil abundance and flux. However, the earlier faunal community changes are contemporaneous with both palynological and geochemical changes in the core profiles indicative of changing land-use patterns. This suggests that lacustrine ecosystem response to deforestation was a two-stage process, with an earlier phase of response to changing quality of sediments or dissolved matter being discharged from the watershed, and a subsequent phase responding to increased quantity of sediment.     

Intense drought and flooding events in the Rio Negro and relation with the tropical Pacific and Atlantic variability modes

The relationship of the hydrological variability of the Rio Negro in Manaus and the dominant large-scale climate variability patterns for the 1902–2007 period is investigated using the quantile method and composite analyses. Variations of the Rio Negro Level (RNL) during its 3-month high (May to July—MJJ) and low (October to December—OND) phases are examined separately. The El Niño (La Niña) related maximum warming (cooling) in the central tropical Pacific during its mature and decaying stages modulates the atmospheric circulation in the tropics and displaces the Walker circulation cell eastward (westward), so that its sinking (rising) branch occurs over western Amazon and causes negative (positive) precipitation anomalies in this region. These anomalous climate conditions occur before the Rio Negro high phase (MJJ) and contribute to reduce (increase) the RNL and lead to a very low (very high) event in the river. On the other hand, the SST variability modes in the tropical Atlantic mainly during the transition from wet to dry season modulate the precipitation variations over western Amazon in OND. The very high events are more frequent after the 1960’s decade and the very low events, before the 1930’s decade. Therefore, the occurrence of these events contains a multidecadal scale variability. The results also indicate that the variations in the rainfall in western Amazon occur up to 9 months in advance and modulate the RNL in Manaus. The results presented here might be useful for monitoring purposes of the RNL.