Hydrothermal origin for sustained Long-Period (LP) activity at Campi Flegrei Volcanic Complex,Italy

We present a detailed analysis of the source properties of Long-Period (LP) signals recorded at Campi Flegrei Caldera (Italy) during the last (2005–2006) mini-uplift episode. Moment Tensor inversion via full-waveform modelling of broad-band seismograms indicates a crack-like source with a significant volumetric component. From auto-regressive modelling of the signal's tail we evaluate the dominant frequency and the attenuation factor of the oscillating source. Considering the acoustic properties of a fluid-filled crack, these values are consistent with the resonant oscillations of a crack filled by a water–gas mixture at variable gas–volume fraction. For these fluids, the crack size would be on the order of 40–420 m, a size range which is consistent with the spatial spreading of LP hypocenters. Analysis of temporally-correlated time series of seismological and geochemical data indicates that climaxing of LP activity was preceded by swarms of volcano-tectonic (VT) events and rapidly followed by a consistent increase of both thermal emissions and gas fluxes recorded at the surface (1 month — 2/3 days, respectively). Following these observations, we propose a conceptual model where VT activity increases permeability of the medium, thus favouring fluid mobility. As a consequence, the hydrothermal system experiences pressure perturbations able to trigger its resonant, LP oscillations.     

Serpentinization of the martian crust during Noachian

This paper proposes a model of serpentinization of the Southern martian crust that may explain the topographic dichotomy, the absence of an associated free-air gravity anomaly and the presence of strong magnetic anomalies in the Southern Hemisphere. The thermodynamical conditions for serpentinization were likely met in the lithosphere during the Noachian period. This process may have decreased the density in the Southern crust and created the topographic dichotomy. Different reactions of serpentinization that can form magnetite have been considered. Assuming an intense magnetic field (core dynamo), we obtain chemical remanent magnetizations that are in the order of the estimates deduced from martian magnetic anomaly studies. The pertinence and the implications of our model concerning the early thermal evolution of Mars are discussed, with emphasis on the intensity of the paleo-magnetic field.     

K-feldspar rich shales from Jurassic bedded cherts in southeastern Slovenia

The study area in southeastern Slovenia is part of the transitional zone between the internal and the external Dinarides. Within Jurassic bedded cherts there are up to 2 cm thick shale intercalations, consisting of laminated, soft, fine-grained, green to brown material whose origin has been in question. In the majority of Tethyan cherts, the interbedded material is reported to be volcanogenic and/or terrigenous, although a detailed mineralogical analysis of the material is lacking. An XRD analysis confirmed the presence of quartz, illite, chlorite and K-feldspar, which is the prevailing component in some samples. Major and trace element data exclude both a volcanogenic and an hydrothermal origin. Several discrimination diagrams indicate the upper crustal terrigenous nature of shales and a biogenic silica source. The source material was probably from a Variscan crust, which at the time of deposition had already been weathered to kaolinite, and some sporadic muscovite. The MnO/Al₂O₃ ratio suggests a slow sedimentation rate of cherts and a faster one for shales, which probably settled from distal turbidity currents. The negative Ce anomaly indicates prolonged contact with ocean water. Sediments were deposited on a Tethyan passive margin, originally as silica-rich carbonate beds intercalated with mud. During late diagenesis, the mixing of marine and meteoric waters caused the further silicification of limestone and simultaneous potassium enrichment of shale which led to their alteration into illite or chlorite and, in sediments already rich in K-minerals, into K-feldspar.