Platinum solubility and partitioning in a felsic melt-vapor-brine assemblage

The solubility and partitioning of Pt in a S-free vapor - brine - rhyolite melt - Pt metal assemblage has been quantified at 800 °C, f_O2=NNO and pressures of 100 and 140 MPa. Vapor and brine were sampled at run conditions by trapping these phases as glass-hosted fluid inclusions as the melt cooled through the glass transition temperature. The vapor and brine were in equilibrium with the melt at the time of trapping and, thus, represent fluids which were sampled at the termination of each experimental run. The microthermometrically determined salinities of vapor and brine are ∼2 and ∼63 wt.% NaCl eq. and ∼9 and ∼43 wt.% NaCl eq. at 100 and 140 MPa, respectively. Platinum solubilities in vapor, brine and glass (i.e., quenched melt) were quantified by using laser ablation - inductively coupled plasma - mass spectrometry (LA-ICP-MS). Equilibrium is discussed with reference to the major and trace element concentrations of glass-hosted fluid inclusions as well as the silicate melt over run times that varied from 110 to 377 h at 140 MPa and 159 to 564 h at 100 MPa. Platinum solubility values (±1σ) in H₂O-saturated felsic melt are 0.28 ± 0.13 μg/g and 0.38 ± 0.06 μg/g at 140 and 100 MPa, respectively. Platinum solubility values () at 140 and 100 MPa, respectively, in aqueous vapor are 0.91 ± 0.29 μg/g and 0.37 ± 0.17 μg/g and in are brine 16 ± 10 μg/g and 3.3 ± 1.0 μg/g. The measured solubility data were used to calculate Nernst-type partition coefficients for Pt between vapor/melt, brine/melt and vapor/brine. The partition coefficient values () for vapor/melt, brine/melt and vapor/brine at 140 MPa are 2.9 ± 1.0, 67 ± 27, and 0.13 ± 0.05 and at 100 MPa are 1.0 ± 0.2, 6.8 ± 2.4, and 0.15 ± 0.05. The partitioning data were used to model the Pt-scavenging capacity of vapor and brine during the crystallization-driven degassing (i.e., second boiling) of a felsic silicate melt over a depth range (i.e., 3-6 km) consistent with the evolution of magmatic-hydrothermal ore deposits. Model calculations suggest that aqueous vapor and brine can scavenge sufficient quantities of Pt, and by analogy other platinum group elements (PGE), to produce economically important PGE-rich magmatic-hydrothermal ore deposits in Earth’s upper continental crust.     

Geomorphology and glacial history of Rauer Group, East Antarctica

The presence of glacial sediments across the Rauer Group indicates that the East Antarctic ice sheet formerly covered the entire archipelago and has since retreated at least 15 km from its maximum extent. The degree of weathering of these glacial sediments suggests that ice retreat from this maximum position occurred sometime during the latter half of the last glacial cycle. Following this phase of retreat, the ice sheet margin has not expanded more than ∼ 1 km seaward of its present position. This pattern of ice sheet change matches that recorded in Vestfold Hills, providing further evidence that the diminutive Marine Isotope Stage 2 ice sheet advance in the nearby Larsemann Hills may have been influenced by local factors rather than a regional ice-sheet response to climate and sea-level change.     

The significant role of sediment bio-retexturing within a contemporary carbonate platform system: Implications for carbonate microfacies development

Assessments of carbonate platform reef–lagoon sediments and benthic habitats around Rodrigues Island (south-west Indian Ocean) have been undertaken in order to examine carbonate sediment textural properties and the controls on texturally-defined sediment fabrics. Reef–lagoon sediments, sampled from across the expansive (~ 8 km wide) carbonate-dominated windward platform, principally comprise poorly sorted medium- to coarse-grained bioclastic sands, composed of a low diversity of grain constituents — predominantly non-geniculate coralline algal bioclasts. Despite a marked homogeneity in sediment compositional and grain size properties, eight distinct sediment textural groups can be identified that form a heterogeneous mosaic across the contemporary reef–lagoon system. Only along the narrow outer platform margins (reef crest, sand apron and outermost lagoon environments) do we observe consistent (predictable) transitions in sediment textural groups, where physical processes are the primary drivers of selective sediment transport and sorting. In contrast, across the main expanse of the lagoon, the sediment substrates are characterised by an irregular mosaic of texturally-defined sediment groups — formed primarily as a function of sediment bio-retexturing. The burrowing activities of alpheid and callianassid shrimps are particularly important in this respect and impart a distinctly unique textural fabric to the upper sediment horizons in the environments in which the respective organisms occur. The consequence of this is that, at the platform system scale, individual, texturally-defined sediment groups are relatively poor indicators of prevailing hydrodynamic regimes or of local sediment production, reflecting more the biological action of organisms inhabiting the substrate. This has important implications for understanding the development of carbonate sediment fabrics in the context of palaeoenvironmental reconstructions and for interpreting a key diagnostic criteria of carbonate microfacies.     

Fine‐grained meandering systems of the Lower Permian Clear Fork Formation of north‐central Texas,USA: Lateral and oblique accretion on an arid plain

Facies models that adequately represent the diverse range of fine‐grained fluvial systems are currently lacking from the literature. In this paper, the spectrum of these systems on the arid plains of western equatorial Pangea is explored, as well as the source and nature of the fine‐grained sediments. Eight fluvial elements in the Early Permian Clear Fork Formation of north‐central Texas represent channel systems up to 7 m deep with coarse basal deposits, three types of lateral‐accretion deposits and sandstone sheets, with laminated, disrupted and massive mudstones laid down in abandoned channels and on floodplains. The three fine‐grained fluvial styles represent a continuum between two end‐members: sustained lateral accretion of bedload composed of quartzose sediments and mud aggregates on point bars, and oblique accretion of suspended sediment on steep accretionary benches and banks with limited lateral migration. This spectrum is controlled, in part, by grain size and the proportion of suspended to bedload sediments. The presence of rarely documented swept ripples on exhumed accretion surfaces is attributed to rapid decline in water levels and downstream re‐entry of overbank floodwaters into the channel. Rill casts, roots and disrupted mudstones low down in channel bodies indicate periods of near‐dryness. Laterally extensive sheet sandstones were formed by episodic flows in broad, sandbed channels. The fluvial sediments were primarily intrabasinally sourced with extrabasinal sediments brought in during major floods from upland source areas or reworked from local storage in the basin, representing a supply limited system. The upward change in cement composition from mainly calcite and ankerite to dolomite and gypsum with minor celestine implies increasingly saline groundwater and progressive aridification, supporting Late Palaeozoic palaeoclimatic models. By integrating petrographic data with sedimentology, a plethora of information about ancient landscapes and climate is provided, allowing a fuller comparison between the Clear Fork Formation and modern dryland alluvial plains.     

Monitoring and early warning of the 2012 Preonzo catastrophic rockslope failure

In this paper, we describe the investigations and actions taken to reduce risk and prevent casualties from a catastrophic 210,000 m³ rockslope failure, which occurred near the village of Preonzo in the Swiss Alps on May 15, 2012. We describe the geological predisposition and displacement history before and during the accelerated creep stage as well as the development and operation of an efficient early warning system. The failure of May 15, 2012, occurred from a large and retrogressive instability in gneisses and amphibolites with a total volume of about 350,000 m³, which formed an alpine meadow 1250 m above the valley floor. About 140,000 m³ of unstable rock mass remained in place and might collapse partially or completely in the future. The instability showed clearly visible signs of movements along a tension crack since 1989 and accelerated creep with significant hydromechanical forcing since about 2006. Because the active rockslide at Preonzo threatened a large industrial facility and important transport routes located directly at the toe of the slope, an early warning system was installed in 2010. The thresholds for prealarm, general public alarm, and evacuation were derived from crack meter and total station monitoring data covering a period of about 10 years, supplemented with information from past failure events with similar predisposition. These thresholds were successfully applied to evacuate the industrial facility and to close important roads a few days before the catastrophic slope failure of May 15, 2012. The rock slope failure occurred in two events, exposing a compound rupture plane dipping 42° and generating deposits in the midslope portion with a travel angle of 39°. Three hours after the second rockslide, the fresh deposits became reactivated in a devastating debris avalanche that reached the foot of the slope but did not destroy any infrastructure. The final run-out distance of this combined rock collapse–debris avalanche corresponded to the predictions made in the year 2004.     

A unified mechanical and retention model for saturated and unsaturated soil behaviour

The coupled mechanical and water retention elasto-plastic constitutive model of Wheeler, Sharma and Buisson (the Glasgow coupled model, GCM) predicts unique unsaturated isotropic normal compression and unsaturated critical state planar surfaces for specific volume and degree of saturation when soil states are at the intersection of mechanical (M) and wetting retention (WR) yield surfaces. Experimental results from tests performed by Sivakumar on unsaturated samples of compacted speswhite kaolin confirm the existence and form of these unique surfaces. The GCM provides consistent representation of transitions between saturated and unsaturated conditions, including the influence of retention hysteresis and the effect of plastic volumetric strains on retention behaviour, and it gives unique expressions to predict saturation and de-saturation conditions (air-exclusion and air-entry points, respectively). Mechanical behaviour is modelled consistently across these transitions, including appropriate variation of mechanical yield stress under both saturated and unsaturated conditions. The expressions defining the unsaturated isotropic normal compression planar surfaces for specific volume and degree of saturation are central to the development of a relatively straightforward methodology for determining values of all GCM parameters (soil constants and initial state) from a limited number of laboratory tests. This methodology is demonstrated by application to the experimental data of Sivakumar. Comparison of model simulations with experimental results for the full set of Sivakumar’s isotropic loading stages demonstrates that the model is able to predict accurately the variation of both specific volume and degree of saturation during isotropic stress paths under saturated and unsaturated conditions.     

Thermal infrared and optical observations of four near-Earth asteroids

We present thermal infrared photometry and spectrophotometry of four near-Earth asteroids (NEAs), namely (433) Eros, (66063) 1998 RO₁, (137032) 1998 UO₁, and (138258) 2000 GD₂, using the United Kingdom Infrared Telescope (UKIRT) in 2002. For two objects, i.e. (433) Eros and (137032) 1998 UO₁, quasi-simultaneous optical observations were also obtained, using the Jacobus Kapteyn Telescope (JKT). For (127032) 1998 UO₁, we obtain a rotation period P=3.0±0.1 h and an absolute visual magnitude HV=16.7±0.4. The Standard Thermal Model (STM), Fast Rotating Model (FRM) and near-Earth asteroid Thermal Model (NEATM) have been fitted to the IR fluxes to determine effective diameters Deff, geometric albedos pv, and beaming parameters η. The derived values are (433) Eros: Deff=23.3±3.5 km (at lightcurve maximum), pv=0.24±0.07, η=0.95±0.19; (66063) 1998 RO₁: , ; (137032) 1998 UO₁: Deff<1.13 km, pv>0.29; (138258) 2000 GD₂: Deff=0.27±0.04 km, , η=0.74±0.15. (66063) 1998 RO₁ is a binary asteroid from lightcurve characteristics [Pravec, P., and 56 colleagues, 2006. Icarus 181, 63-93] and we estimate the effective diameter of the primary (Dp) and secondary (Ds) components: and . The diameter and albedo of (138258) 2000 GD₂ are consistent with the trend of decreasing diameter for S- and Q-type asteroids found by Delbó et al. [Delbó, M., Harris, A.W., Binzel, R.P., Pravec, P., Davies, J.K., 2003. Icarus 166, 116-130]. A possible trend of increasing beaming parameter with diameter for small (less than about 3 km) S- and Q-type asteroids is found.     

Band parameters for self-broadened ammonia gas in the range 0.74 to 5.24 μm to support measurements of the atmosphere of the planet Jupiter

We present new measurements and modelling of low-resolution transmission spectra of self-broadened ammonia gas, one of the most important absorbers found in the near-infrared spectrum of the planet Jupiter. These new spectral measurements were specifically designed to support measurements of Jupiter's atmosphere made by the Near-Infrared Mapping Spectrometer (NIMS) which was part of the Galileo mission that orbited Jupiter from 1995 to September 2003. To reach approximate jovian conditions in the lab, a new gas spectroscopy facility was developed and used to measure self-broadened ammonia spectra from 0.74 to 5.2 μm, virtually the complete range of the NIMS instrument, for the first time. Spectra were recorded at temperatures varying from 300 to 215 K, pressures from 1000 to 33 mb and using three different path lengths (10.164, 6.164 and 2.164 m). The spectra were then modelled using a series of increasingly complex physically based transmittance functions.     

Ichnology of prodeltaic hyperpycnite–turbidite channel complexes and lobes from the Upper Cretaceous Prairie Canyon Member of the Mancos Shale,Book Cliffs,Utah, USA

The Upper Cretaceous Prairie Canyon Member of the Mancos Shale, Book Cliffs, Utah, contain outstanding examples of prodeltaic turbidity and hyperpycnal flow deposits. Sandstone‐rich, heterolithic and mudstone‐rich channel fills occur near the north‐west entrance to Tusher Canyon, Gunnison Butte and Bootlegger Wash. Mudstone‐rich and heterolithic‐rich hyperpycnal channel deposits are mostly unbioturbated, locally displaying a few specimens of Phycosiphon incertum, Protovirgularia dichotoma, Rosselia socialis, Schaubcylindrichnus coronus and Palaeophycus tubularis. Sandstone‐rich channel deposits consist of wave‐reworked turbidites and hyperpycnites, containing Helminthoidichnites tenuis, Lockeia siliquaria, Phycodes isp., Phycosiphon incertum, Protovirgularia dichotoma, Rosselia socialis, Skolithos linearis and Fugichnia. Scolicia isp. and Chondrites isp. occur locally. Strata along the south‐west entrance of Tusher Canyon record deposition in a prodelta turbidite lobe, but far from its axis. With the exception of a few specimens of Ophiomorpha isp., bioturbation is restricted to the top of the succession, where Curvolithus simplex, Gyrochorte comosa, Lockeia siliquaria, Palaeophycus tubularis and Ptychoplasma excelsum occur. Strata at Hatch Mesa record deposition in a hyperpycnal lobe, near to its axis. Sandstone beds include Curvolithus simplex, Gyrochorte comosa, Ophiomorpha nodosa, Palaeophycus tubularis, Phycosiphon incertum, Protovirgularia dichotoma, Ptychoplasma excelsum, Schaubcylindrichnus freyi, Skolithos linearis, large specimens of Rosselia socialis and indeterminate crustacean burrows. Chondrites isp. is present in the mudstone. High rates of both episodic and sustained sedimentation, degree of substrate consolidation, freshwater discharge and water turbidity are the most important stress factors in both channels and lobes. Taxonomic composition, uneven distribution of bioturbation through the successions, and overall low ichnodiversity help to distinguish these prodeltaic deposits from bathymetrically equivalent offshore strata in the same basin. Hyperpycnal flow deposits are formed in a wide variety of environmental settings, therefore displaying high ichnological variability. Such variability is summarized by characterising ichnofaunas from four different depositional settings: (i) lakes; (ii) shelf deltas; (iii) shelf‐edge deltas; and (iv) deep‐marine systems.