Trace element distribution in annual stalagmite laminae mapped by micrometer-resolution X-ray fluorescence: Implications for incorporation of environmentally significant species

Stalagmite ER78, from Grotta di Ernesto cave in NE Italy displays clear annual lamination consistent with its shallow depth below a forest ecosystem subject to autumnal peaking of water infiltration. Synchrotron radiation scanning micro-X-ray fluorescence analyses of heavy elements at European Synchrotron Radiation Facility beamline ID22, and light elements at ID21, with 1-3 μm resolution has been combined with data from ion microprobe analyses to reveal chemical variability across the visible layers of these annual laminae. A series of elements display a symmetrical peak, centered around the thin, dark layer at the top of each lamina. The peak concentration is ordered Y > Zn, Cu and Pb > P and Br. This hierarchy is thought to reflect the selectivity of transport of these elements, possibly by organic colloids flushed from the soil zone during autumn infiltration. Ion microprobe analysis indicates Na and F also increase, as does H, the latter reflecting increased microporosity. Sr displays a trough around the dark and thin autumn layer implying that its incorporation may be limited by competition with other elements. Mg and S show a different pattern of annual variation and Fe displays none. The trace metals, Br and Y display peak abundance in the early 20th century, which appears to reflect a period of tree-felling rather than a climatic anomaly. The results demonstrate the power of the high spatial resolution and low detection limits of the synchrotron technique, and its ability to produce quantitative maps that allow distinction of layered structure from that of isolated particles, or irregular inhomogeneities.     

Vertical deformation partitioning across a collapsing large and hot orogen

Featuring 3 000-km-long large and hot orogen, the Mantiqueira Province provides a rare opportunity to study the process of gravitational collapse at mid to deep crustal levels. Distinct but contemporary (~500 Ma) post-collisional intrusions show structures and anisotropy of magnetic susceptibility (AMS) fabrics related to their emplacements, recording different flow patterns. In southern deep-seated intrusions, ellipsoidal-shaped roots with gabbroic-to-hybrid cores surrounded by granitic rocks show concentric patterns of AMS fabrics that cut across the NE-trending regional foliation. In contrast, northern intrusions, exposed as the upper sections of batholith-size bodies of coarse-grained granite emplaced at the shallow to mid-crust, show general NS-trending magnetic fabrics roughly parallel to strike of the orogen and the regional foliation of host rocks. These contrasting magnetic patterns from shallow to deeper crust suggest vertical magma migration from the overthickened orogenic core to be emplaced across its thinner stretched flanks during the gravitational collapse of the orogenic edifice.