A 150-year isotopic record of lead deposition in Yancheng coastal wetland,China

Radioactive markers are useful in dating lead(Pb) deposition patterns from industrialization in sedimentary archives. As a well-known natural reserve in the world, Yancheng coastal wetland in Jiangsu Province is one of areas most sensitive to global sea level change and is located in the most developed and polluted region of China. Two cores were collected in Yancheng wetland in October 2013 and dated using ~(210)Pb and ~(137)Cs radiometric techniques. Sediments in both cores were sectioned into depth bands and examined systematically for dry bulk density, water content, magnetic susceptibility and grain-size. Multiple elements including Pb were also measured using inductively coupled plasma systems. Unsupported ~(210)Pb activities decreased with depth in both of the two cores, and ~(210)Pb chronologies were established(covering 150 years) using the constant rate of supply(CRS) model. The measured Pb contents ranged from 14.97 mg/kg to 29.40 mg/kg with average values of 17.17–22.79 mg/kg, and the Pb fluxes ranged from 41.70 mg/(m~2·yr) to 172.70 mg/(m~2·yr) with averages of 95.59–123.41 mg/(m~2·yr). Temporal variations of Pb flux, enrichment factors and Pb isotopes show a gradual and continuous increase over time and clearly reflect increased emissions from anthropogenic activities in the region. The Pb isotopic compositions show that most of Pb deposition in Yancheng wetland is input from natural sources by water flows and has the same levels of Pb as in the surface sediment of the Yangtze River and the Pacific mineral aerosol. We also stress the anthropogenic Pb contribution in Yangcheng wetland sediment and the reason of our Pb isotopes not showing anthropogenic signature is likely the instability of anthropogenic Pb in high Fe/Mn oxide conditions. Therefore, more attention should be paid to current local pollution problems, and society should take action to seek a balance between economic development and environmental protection.     

Complete nuclear ribosomal DNA sequence amplification and molecular analyses of <Emphasis Type="Italic">Bangia</Emphasis> (Bangiales,Rhodophyta) from China

Filamentous Bangia, which are distributed extensively throughout the world, have simple and similar morphological characteristics. Scientists can classify these organisms using molecular markers in combination with morphology. We successfully sequenced the complete nuclear ribosomal DNA, approximately 13 kb in length, from a marine Bangia population. We further analyzed the small subunit ribosomal DNA gene (nrSSU) and the internal transcribed spacer (ITS) sequence regions along with nine other marine, and two freshwater Bangia samples from China. Pairwise distances of the nrSSU and 5.8S ribosomal DNA gene sequences show the marine samples grouping together with low divergences (00.003; 0–0.006, respectively) from each other, but high divergences (0.123–0.126; 0.198, respectively) from freshwater samples. An exception is the marine sample collected from Weihai, which shows high divergence from both other marine samples (0.063–0.065; 0.129, respectively) and the freshwater samples (0.097; 0.120, respectively). A maximum likelihood phylogenetic tree based on a combined SSU-ITS dataset with maximum likelihood method shows the samples divided into three clades, with the two marine sample clades containing Bangia spp. from North America, Europe, Asia, and Australia; and one freshwater clade, containing Bangia atropurpurea from North America and China.     

阿尔金中段大通沟花岗岩体年代学、地球化学特征及其成因

出露于阿尔金中段的大通沟花岗岩体,岩性主要为二长花岗岩,LA-ICP-MS锆石U-Pb年龄为(353.7±1.1)Ma。SiO_2为74.5%~76.2%,Al_2O_3为12.62%~14.15%,(Na_2O+K_2O)为7.71%~8.29%,K_2O/Na_2O为0.9~1.22,A/CNK介于1.0~1.19之间,属高钾钙碱性系列的过铝质-强过铝质花岗岩。该岩石富集大离子亲石元素(LILE),亏损素Ba、Nb、Sr、P、Ti等高场强元素(HFSE);∑REE变化范围大(∑REE=85.7×10~(-6)~153.2×10~(-6),平均为111×10~(-6)),具有强烈的负Eu异常(δEu=0.03~0.59,平均0.33),LREE/HREE=3.52~11.9,轻稀土相对富集,轻重稀土分馏明显。微量元素地球化学特征表明,其源区物质主要来源于上地壳的变杂砂岩和变泥质岩类。锆石饱和温度计演算结果显示锆石的结晶温度为722~745℃(平均735℃),估算二长花岗岩源区的压力为0.8~1.6GPa。综合区域地质资料,阿尔金中段大通沟花岗岩体的形成与造山带根部块体的拆沉作用有关。     

Characterizing groundwater/surface-water interactions in the interior of Jianghan Plain,central China

Hydrogeology Journal - Quantifying groundwater/surface-water interactions is essential for managing water resources and revealing contaminant fate. There has been little concern on the exchange...     

Spatial and temporal analyses of air pollutants and meteorological driving forces in Beijing–Tianjin–Hebei region,China

Due to its negative impact on the living environment of human beings, ambient air pollution has become a global challenge to human health. In this study, surface observations of six criteria air pollutants, including PM_2.5, PM₁₀, SO₂, NO₂, CO and O₃, were collected to investigate the spatial and temporal variation in the Beijing–Tianjin–Hebei (BTH) region during 2013–2016 and to explore the relationships between atmospheric pollutants and meteorological variables using quantile regression model (QRM) and multiple linear regression model (MLRM). The results show that BTH region has experienced significant air pollution, and the southern part generally has more severe conditions. The annual average indicates clear decreasing trends of the particulate matters, SO₂ and CO concentrations over the last 4 years and slight increasing trends of NO₂ and O₃ in several cities. The seasonal and monthly characteristics indicate that the concentrations of five species reach their maxima in the winter and their minima in the summer, whereas O₃ has the opposite behaviour. Finally, the pseudo R² values show that the QRMs have the best performance in the winter, followed by spring, fall, and summer. Specifically, all the meteorological factors have significant impacts on air pollution but change with pollutants and seasons. The MLRM results are generally consistent with the QRM results in all seasons, and the inconsistencies are more common in the fall and winter. The results of this research provide foundational knowledge for predicting the response of air quality to climate change in the BTH region.     

Development and verification of the comprehensive model for physical properties of hydrate sediment

Natural gas hydrate is widely distributed all over the world and may be a potential resource in the near future, whereas hydrate dissociation during the development affects wellbore stability and drilling safety. However, the present modeling of hydrate reservoir parameters ignored the influence of effective stress and only considered the hydrate saturation. In this paper, a series of stress sensitivity experiments for the unconsolidated sandstone were carried out, and the influence of mean effective stress on physical parameters was obtained; a comprehensive model for the physical parameters of hydrate reservoir was developed subsequently. With the help of ABAQUS finite element software, the established comprehensive model was verified by the use of the wellbore stability numerical model of hydrate reservoir. The verification results show that ignoring the effect of mean effective stress on the parameters of hydrate formation aggravates the invasion of drilling fluid into the hydrate formation. Besides, ignoring the stress sensitivity of reservoir physical parameters will underestimate the wellbore instability during hydrate drilling, which will be a threat to the safety of gas hydrate drilling. At the end of the drilling operation, the maximum plastic strain of the model for considering and not considering stress sensitivity was 0.0145 and 0.0138, respectively. Therefore, the established comprehensive model will provide a theoretical support for accurately predicting the engineering geological disasters in hydrate development process.     

Network-based triple-frequency carrier phase ambiguity resolution between reference stations using BDS data for long baselines

Network-based ambiguity resolution (AR) between reference stations is the prerequisite to realize a precise real-time kinematic positioning service. With the help of BDS triple-frequency signals, we can efficiently deal with the ionospheric delay and tropospheric delay, and achieve rapid and reliable AR. To overcome the inaccurate ionospheric delay estimated by the geometry-free three carrier ambiguity resolution (GF TCAR) technique, which leads to failure in the original ambiguity resolution, we propose an ionospheric-free (IF) TCAR method to resolve the ambiguity between the reference stations over long baselines. Taking full advantage of the known positions of the reference stations, the easily resolved extra-wide-lane (EWL) ambiguity, and the IF phase combinations, we can reliably fix the wide-lane (WL) ambiguity. A Kalman filter is applied to estimate precise IF ambiguities and the original ambiguity is resolved with the fixed WL ambiguity. A numerical analysis with triple-frequency BDS data from three long baselines of a CORS network is provided to compare the AR performance of GF TCAR with that of IF TCAR. The results show that both methods can reliably resolve the WL ambiguity with a remarkable correctly-fixed rate of higher than 99%, and the reliably-fixed rates of the IF TCAR slightly increase from 92.19, 94.67 and 94.61–98.26, 99.54 and 97.51% for the three baselines. Herein “correctly-fixed” and “reliably-fixed” mean the difference between the float ambiguity and the true one are less than ± 0.5 and ± 0.25 cycles, respectively. On the other hand, the AR performance of the original signals with the IF TCAR method is much better than that with the GF TCAR method attaining a 100% correctly-fixed rate, while the GF TCAR method can hardly fix the original ambiguity with the largest bias being as much as 4 cycles because of the amplified systematic bias.     

甘肃省明舒井地区高光谱蚀变异常及找矿分析

正明舒井地区位于甘肃省北西侧,敦煌市北侧、瓜州县北西侧。前人在该区及周边区域开展了区调、矿调及相关多金属矿的勘查工作(王瑞军等,2014,2017),在遥感地质方面,仅开展了多光谱遥感的应用工作,而针对高光谱遥感的研究工作还未开展。明舒井地区基岩出露好、地形起伏小、切割弱,地表蚀变发育,矿床、矿点分布较多,具备开展高光谱遥感技术的地质和自然地理条件,有利于发挥高光谱的技术优势。