A 150-year isotopic record of lead deposition in Yancheng coastal wetland,China

Radioactive markers are useful in dating lead(Pb) deposition patterns from industrialization in sedimentary archives. As a well-known natural reserve in the world, Yancheng coastal wetland in Jiangsu Province is one of areas most sensitive to global sea level change and is located in the most developed and polluted region of China. Two cores were collected in Yancheng wetland in October 2013 and dated using ~(210)Pb and ~(137)Cs radiometric techniques. Sediments in both cores were sectioned into depth bands and examined systematically for dry bulk density, water content, magnetic susceptibility and grain-size. Multiple elements including Pb were also measured using inductively coupled plasma systems. Unsupported ~(210)Pb activities decreased with depth in both of the two cores, and ~(210)Pb chronologies were established(covering 150 years) using the constant rate of supply(CRS) model. The measured Pb contents ranged from 14.97 mg/kg to 29.40 mg/kg with average values of 17.17–22.79 mg/kg, and the Pb fluxes ranged from 41.70 mg/(m~2·yr) to 172.70 mg/(m~2·yr) with averages of 95.59–123.41 mg/(m~2·yr). Temporal variations of Pb flux, enrichment factors and Pb isotopes show a gradual and continuous increase over time and clearly reflect increased emissions from anthropogenic activities in the region. The Pb isotopic compositions show that most of Pb deposition in Yancheng wetland is input from natural sources by water flows and has the same levels of Pb as in the surface sediment of the Yangtze River and the Pacific mineral aerosol. We also stress the anthropogenic Pb contribution in Yangcheng wetland sediment and the reason of our Pb isotopes not showing anthropogenic signature is likely the instability of anthropogenic Pb in high Fe/Mn oxide conditions. Therefore, more attention should be paid to current local pollution problems, and society should take action to seek a balance between economic development and environmental protection.     

Anthropogenic,detritic and atmospheric soil-derived sources of lead in an alpine poor fen in northeast China

Ombrotrophic bogs are faithful archive of atmospheric metal deposition,but the potential for fens to reconstruct environmental change is often underestimated.In this study,some new data on the Pb depositional history in northeast China were provided using two 210Pb-dated peat sequences from a poor fen in the Fenghuang Mountain of Heilongjiang province.Anthropogenic,detritic and atmospheric soil sources were discriminated using a two-step sequential digestion(weak acid leaching to liberate mobile Pb which is often regarded as anthropogenic Pb,especially for recent samples)and a ratio of unsupported 210 Pb and supported 210 Pb with the logic of that the 214 Pb mainly represents the residual detritus(constant throughout the core)and the unsupported 210 Pb arises from atmospheric fallout.A higher 210Pb/214 Pb suggests more contributions from atmospheric deposition to the Pb content in the peat,and a ratio of 10 was defined to indicate the boundary between detritic input and atmospheric deposition.The detritic Pbwas estimated to be 10~(-1)3 mg·kg~(-1),the anthropogenic Pb ranged from 10-80 mg·kg~(-1),and the atmospheric soil-derived Pb ranged from 5 mg·kg~(-1) to 30mg·kg~(-1).The history of anthropogenic Pb pollution over the last 150 years was reconstructed,and the calculated Pb deposition rate(AR Pb) ranged from 5to 56 mg·m-2·yr~(-1).Using Ti as a reliable reference,the enrichment factor of Pb(EF Pb) relative to the upper continental crust was calculated.Both AR Pb and EF Pb increased with time,especially after the foundation of the People's Republic of China.This is consistent with increasing industrialization and coal burning in the last 60 years in northeast China.The present record of anthropogenic Pb deposition was consistent with the previous reports and an increasing trend of environmental pollution due to anthropogenic activities,in contrasts to Europe and North America which have experienced a major environmental cleanup.For the first time,this work estimates atmospheric Pb deposition via a minerotrophic peat core in China.This will enhance the use of peat archives for studies of environmental change.     

Effect of benzo[a]pyrene on detoxification and the activity of antioxidant enzymes of marine microalgae

The objective of this study was to examine the effect of benzo[a]pyrene(Ba P) on the detoxification and antioxidant systems of two microalgae,Isochrysis zhanjiangensis and Platymonas subcordiformis.In our study,these two algae were exposed to Ba P for 4 days at three different concentrations including 0.5 μg~(L-1)(low),3 μg~(L-1)(mid) and 18 μg~(L-1)(high).The activity of detoxification enzymes,ethoxyresorufin O-deethylase(EROD) and glutathione S-transferase(GST) increased in P.subcordiformis in all Ba P-treated groups.In I.zhanjiangensis,the activity of these two enzymes increased at the beginning of exposure,and then decreased in the groups treated with mid-and high Ba P.The activity of antioxidant enzyme superoxide dismutase(SOD) increased in I.zhanjiangensis in all Ba P-treated groups,and then decreased in high Ba P-treated group,while no significant change was observed in P.subcordiformis.The activity of antioxidant enzyme catalase(CAT) increased in I.zhanjiangensis and P.subcordiformis in all Ba Ptreated groups.The content of malondialdehyde(MDA) in Isochrysis zhanjiangensis increased first,and then decreased in high Ba P-treated group,while no change occurred in P.subcordiformis.These results demonstrated that Ba P significantly influenced the activity of detoxifying and antioxidant enzymes in microalgae.The metabolic related enzymes(EROD,GST and CAT) may serve as sensitive biomarkers of measuring the contamination level of Ba P in marine water.     

GPS基线快速计算与跟踪方法探讨

为减少中国地壳运动观测网络提供的GPS最终解的滞后时间,及时跟踪地壳形变的动态,利用提取的GPS长期运动背景外推GPS每日最终解;同时以松弛解H文件中的协方差矩阵为约束条件,对松弛解H文件中的坐标进行7参数转换,得到ITRF2000框架下的GPS当日坐标;用外推的GPS当日解、GPS最终解和H文件分别计算基线长,并对结果进行比较,然后,为了从大量的基线中找出变化幅度较大的基线,利用经验正交函数分析（EOF）方法对活动地块内基线的空间特征进行分析,实现对GPS基线的动态跟踪与监视。     

地面重力时空变化向卫星高度的解析延拓

为研究卫星在不同高度对地面重力变化的检测能力,利用地面获得的重力场时间和空间变化,采用空间域向上解析延拓原理,将地面数据向上解析延拓到数百千米的不同高度。计算分析表明,如果地表存在93×10-8ms-2的重力变化量,在450km高度可观测到20×10-8ms-2的重力变化。所以利用卫星重力观测技术进行地震监测,其观测精度应优于20×10-8ms-2。     

地壳形变与密度变化耦合运动探析

为整体解释现代大地测量数据,提出了地壳变形与密度变化耦合运动的基本思想;分析了地壳变形与密度变化耦合运动的基本理论;导出了由地壳形变与密度变化耦合运动引起的重力时间变化一般严格公式。     

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航空重力测量中牛顿中心差分器对确定载体加速度的影响

讨论不同点数的牛顿中心差分器对航空重力测量中确定载体加速度的影响。理论分析表明,当航空重力测量的有效频段位于牛顿中心差分器的通带时,不同点数的牛顿中心差分器所得结果经低通滤波后几乎没有差异。实验表明,当采样间隔为1 s、载体平均速度为155 m/s、所需重力数据的分辨率为10 km时,低通滤波后不同点数的牛顿中心差分器输出结果之间的较差优于2.1 mGal。     

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