Cold seeps in Monterey Bay, California: Geochemistry of pore waters and relationship to benthic foraminiferal calcite

An extensive geochemical and biogeochemical examination of CH₄ seeps in the Clam Flats area of Monterey Bay provides insight into the character of relationships between seep geochemistry and benthic foraminiferal geochemistry. The area is characterized by sulfide-rich fluids. Sulfide increases are associated with large increases in alkalinity, as well as small decreases in dissolved Ca and Mg. In addition, only small increases in NH₄ are observed, but values of δ¹³C of dissolved inorganic C are as low as −60‰ at shallow depths (<3 cm). These observations indicate that all these processes are related to the bacterial oxidation of CH₄, which is transported upward by slow seepage of pore fluids. The geochemistry of the pore fluids should be relevant to the geochemistry of the carbonate tests of living and dead foraminifera. However, a profound disequilibrium of approximately an order of magnitude occurs between the δ¹³C values of stained (cytoplasm-containing) foraminiferal carbonate and the C isotope values of ambient pore water dissolved inorganic C. Reasons are unclear for this isotopic disequilibrium, but have important implications for interpretations of foraminiferal carbonate as a paleoenvironmental proxy. Much fine scale work is needed to fully understand the relationships between the biogeochemistry of benthic foraminifera and the geochemistry of the pore waters where they live.     

Groundwater level trends and recharge event characterization using historical observed data in semi-arid Chile

ABSTRACT

Groundwater is an important resource in semi-arid Chile to meet local social, economic and environmental water demands. Historical ground water level (GWL) data (1986–2014) in the Coquimbo Region were analysed to characterize short and long-term alluvial aquifer dynamics. Long-term trends were assessed using a seasonal Mann-Kendall trend test, which indicated that more than 80% of the time series exhibit a negative trend. Short-term analysis using cross-correlation provided information on recharge origin and its spatial pattern. Runoff and GWL are highly correlated depending on elevation, signifying that stream to aquifer flow is an important recharge process at higher altitudes. Long-term recharge behaviour was characterized using time-frequency wavelet power spectra. The results show significant amplitude of the 5-year recharge period for GWL, which is driven by a 5-year El Niño index periodicity. Such results provide key information of the spatiotemporal functioning of aquifers.     

The effects of a large destructive local earthquake on earthquake preparedness as assessed by an earthquake preparedness scale

A multi-act scale for measuring the earthquake preparedness of individuals and small businesses was developed and used to assess the earthquake preparedness and the perceived difficulty of becoming prepared for earthquakes of 291 University of Southern California undergraduate students approximately 3 weeks prior to the 5.9 magnitude Whittier Narrows earthquake on 1 October 1987. These data were then compared with similar information collected over a 2 1/2 month period following the earthquake from randomly selected samples of subjects that had participated in the original survey. In one case, levels of preparedness of a single group were measured at approximately 2 week intervals (the repeated measures study). In a second case, this information was collected at different points in time following the earthquake from different groups of subjects (the between groups study). Results indicated an initial increase in earthquake preparedness which was significant for subjects in the repeated measures group and which approached significance for subjects in the between groups. This increase in preparedness was maintained for subjects in the repeated measure study but gradually declined to pre-earthquake levels for subjects in the between subjects study. Subjects in the repeated measures study also perceived earthquake preparedness as a significantly less difficult task following the earthquake. Level of perceived difficulty continued to decline over the 2 1/2 month study period. Declines in perceived difficulty for the between subjects study were more erratic, and were only approximately 1/3 of that for the repeated measures group at the end of 2 1/2 months.     

A ca. 800-Year Lithologic Record of Drought from Sub-annually Laminated Lake Sediment, East Java

Lithostratigraphic analyses of a sub-annually laminated core from Ranu Lamongan, a maar lake on the island of Java, document considerable changes in the lake’s chemistry and water balance over the past ca. 800 calendar years. Composition of the dark (clastics) and light (diatoms and/or calcium carbonate minerals) couplets suggests that these laminations form in response to seasonal changes in rainfall and water-column overturn in the lake. Calcium carbonate is not continuous in the core, and when it occurs it varies, sometimes abruptly, in carbonate phase and elemental composition (low Mg-calcite Mg-calcite, and aragonite). A significant correlation between Mg/Ca changes and δ¹⁸O variations in authigenic calcium carbonate suggest the basin is highly sensitive to hydrologic variation. Lithologic data suggest calcium carbonate precipitates and thus records hydrologic conditions during the dry season – a season in which rainfall anomalies are highly correlated with the phase of ENSO. Our carbonate-based record of Mg/Ca shows variability in evaporative concentration on a quasi-seasonal frequency for the past ca. 800 years. Our record shows two multi-decadal periods of drought – ca. 1275–1325 and ca. 1450–1650 CE – the latter of which was especially strong and/or prolonged. Our record also shows a possible change in drought frequency at around 1650 CE, in which periods of calcium carbonate precipitation and Mg/Ca change shifted from multi-decadal to interannual variability. Given the strong correlations between modern-day drought in East Java and ENSO variability, our drought record may indicate a regime shift in the behavior of the ENSO system about 350 years ago. Finally, comparisons between our record and others suggest that variation in ENSO on centennial and sub-centennial scales is not strongly associated with changes in the global mean climate state.     

A geoarchaeological approach to the analysis of secondary lithic deposits

The methods and techniques presented provide a means for evaluating raw material characteristics in those situations where secondary deposits of lithic materials were exploited for stone tool production. Those aspects of secondary deposits measured or estimated include size, form, roundness, crystallinity, homogeneity, and raw material frequency. A comparison and discussion of two sampled areas in eastern New Mexico demonstrate how these procedures can be used to elucidate meaningful archaeological information. © 1993 John Wiley & Sons, Inc.     

Parameterisation of incoming longwave radiation over glacier surfaces in the semiarid Andes of Chile

A good understanding of radiation fluxes is important for calculating energy, and hence, mass exchange at glacier surfaces. This study evaluates incoming longwave radiation measured at two nearby glacier stations in the high Andes of the Norte Chico region of Chile. These data are the first published records of atmospheric longwave radiation measurements in this region. Nine previously published optimised parameterisations for clear sky emissivity all produced results with a root mean square error (RMSE) ~20 W?m^?2 and bias within ±5 W m^?2, which is inline with findings from other regions. Six optimised parameterisations for incoming longwave in all sky conditions were trialled for application to this site, five of which performed comparably well with RMSE on daytime data <18 W?m^?2 and bias within ±6 W?m^?2 when applied to the optimisation site and RMSE <20 W?m^?2 and bias within ±10 W m^?2 when applied to the validation site. The parameterisation proposed by Mölg et al. (J Glaciol 55:292-302, 2009) was selected for use in this region. Incorporating the proposed elevation modification into the equation reduced the bias in the modelled incoming longwave radiation for the validation site. It was found that applying the parameterisation optimised in the original work at Kilimanjaro produced good results at both the primary and validation site in this study, suggesting that this formulation may be robust for different high mountain regions.     

Energy balance in urban Mexico City: observation and parameterization during the MILAGRO/MCMA-2006 field campaign

The parameterization of the energy balance from a residential and commercial neighborhood of Mexico City was investigated using direct measurements of radiative and heat fluxes carried out during the MILAGRO/MCMA-2006 field campaign as a reference. The measured fluxes were used to evaluate different models of the energy balance based on parameterizations that require standard meteorological observations: ambient temperature, relative humidity, atmospheric pressure and cloudiness. It was found that these models reproduce with reasonable accuracy the diurnal features of the radiative and heat fluxes. The largest differences between modeled and observed fluxes correspond to the incoming longwave radiation, mainly due to errors in the cloudiness data. This paper contributes to the understanding of the energy partitioning in (sub)tropical urban environments, particularly in the developing world, where energy balance models have not been evaluated.     

In situ U-series dating by laser-ablation multi-collector ICPMS: new prospects for Quaternary geochronology

The capabilities and potential applications of in situ dating of Quaternary materials using laser ablation-MC-ICPMS are explored. ²³⁴U/²³⁸U and ²³⁰Th/²³⁴U can be measured with precision sufficient for dating at a spatial resolution of 100 μm or better in samples that contain as a little as 1 ppm uranium. Moreover, U and Th concentrations and U-series isotope ratios can be continuously profiled to determine changes in age that occur with sample growth (e.g. in speleothems). These capabilities additionally permit the dating of bones, teeth and possibly molluscs, which are subject to post-mortem open-system behaviour of U-series isotopes, and can be employed to elucidate processes of U-series migration during weathering and diagenesis. A drawback of laser ablation-MC-ICPMS is that it cannot in general provide U-series age estimates with the high precision and accuracy of conventional TIMS or solution MC-ICPMS methods. However, sample preparation is straightforward, the amount of sample consumed negligible, and it can be used to rapidly characterise or screen and select samples from which more precise and accurate dates can be obtained using conventional methods. Given further instrumental developments and the establishment of suitable matrix-matched standards for carbonates and other materials, we foresee that laser ablation-MC-ICPMS will play an increasingly important role in Quaternary dating research.