Spherulites and thundereggs from pitchstones of the Deccan Traps: geology,petrochemistry, and emplacement environments

Spherulites and thundereggs are rounded, typically spherical, polycrystalline objects found in glassy silicic rocks. Spherulites are dominantly made up of radiating microscopic fibers of alkali feldspar and a silica mineral (commonly quartz). They form due to heterogeneous nucleation in highly supercooled rhyolitic melts or by devitrification of glass. Associated features are lithophysae (“stone bubbles”), which have an exterior (sometimes concentric shells) of fine quartz and feldspar, and internal cavities left by escaping gas; when filled by secondary silica, these are termed thundereggs. Here, we describe four distinct occurrences of spherulites and thundereggs, in pitchstones (mostly rhyolitic, some trachytic) of the Deccan Traps, India. The thundereggs at one locality were previously misidentified as rhyolitic lava bombs and products of pyroclastic extrusive activity. We have characterized the thundereggs petrographically and geochemically and have determined low contents of magmatic water (0.21–0.38 wt.%) in them using Fourier transform infrared spectroscopy. We consider that the spherulite-bearing outcrops at one of the localities are of lava flows, but the other three represent subvolcanic intrusions. Based on the structural disposition of the Deccan sheet intrusions studied here and considerations of regional geology, we suggest that they are cone sheets emplaced from a plutonic center now submerged beneath the Arabian Sea.     

Mathematical modeling of biologically mediated redox processes of iron and arsenic release in groundwater

A one dimensional reactive transport model was developed in order to illustrate the biogeochemical behavior of arsenic and iron reduction and release to groundwater that accounts for the reaction coupling the major redox elements under reducing environment. Mass transport equation and the method of characteristics were used considering fundamental geochemical processes to simulate transport processes of different pollutants in mobile phase. The kinetic sub-model describes the heterotrophic metabolisms of several microorganisms. To model a complete redox sequence (aerobic or denitrifiers, Fe(III)-reduction, respiration bacteria of iron and arsenic compounds, and As(V) reduction) four functional bacterial groups (X ₁, X ₂, X ₃, and X ₄) were defined. Microbial growth was assumed to follow Monod type kinetics. The exchange between the different phases (mobile, bio, and matrix) was also considered in this approach. Results from a soil column experiment were used to verify the simulation results of the model. The model depicts the utilization of oxygen, nitrate, iron oxide and arsenic as electron acceptors for oxidation of organic carbon (OC) in a column. The OC as electron donor is one of the most important factors that affect the iron and arsenic reduction bacterial activity.     

Fluid-rock interaction in the Kangankunde Carbonatite Complex,Malawi: SEM based evidence for late stage pervasive hydrothermal mineralisation

The Kangankunde Carbonatite Complex from the Cretaceous Chilwa Alkaline Province in southern Malawi contains ankeritic and siderite carbonatite that are affected by late stage remobilisation by a carbothermal or hydrothermal fluid. The coarse pegmatitic siderite carbonatite that hosts exotic minerals like monazite, synchysite, bastnasite, strontianite and apatite in vugs and cavities constitutes some of the richest rare earth deposits in the world. Besides these minerals, our studies reveal the presence of collinsite and aragonite from the siderite carbonatite. Fine drusy monazites are seen as overgrowths on thin veinlets of siderite within the rare earth mineralised zones. We present unambiguous SEM-based surface textural evidence such as presence of dissolution-corrosion features like etching along cleavage, solution channels, solution pits, sinstered scaly surface, etc. along with rare earth mineralisation that suggests the exotic minerals in the siderite carbonatite did not crystallise from carbonate magma and are a result of sub-solidus processes involving carbonatite-derived fluids. We believe that the monazite-synchysitebastnasite-strontianite-collinsite assemblages were formed by juvenile post magmatic hydrothermal alteration of pre-existing carbonatite by a complex CO₂-rich and alkali chloride-carbonate-bearing fluid at ～250 to 400°C in an open system. This late ‘magmatic’ to ‘hydrothermal’ activity was responsible for considerable changes in rock texture and mineralogy leading to mobility of rare earth elements during fluid-rock interaction. These aspects need to be properly understood and addressed before using trace and rare earth element (REE) geochemistry in interpreting carbonatite genesis.     

Analysis of wheat farmers’ risk perceptions and attitudes: evidence from Punjab,Pakistan

Natural Hazards - Agriculture involves multiple risks of which environmental and production threats are major ones. Farmers’ risk attitudes and risk perceptions have a significant role in...     

Plane symmetric cosmological models with perfect fluid and dark energy

We consider a self-consistent system of Plane symmetric cosmology and binary mixture of perfect fluid and dark energy. The perfect fluid is taken to be one obeying the usual equation of state p=γρ with γ∈[0,1]. The dark energy is considered to be either the quintessence or Chaplygin gas. Exact solutions to the corresponding Einstein’s field equations are obtained as a quadrature. The cases of Zeldovich Universe, Dust Universe and Radiation Universe and models with power-law and exponential expansion have discussed in detail. For large t, the models tend to be isotropic.     

Whistler wave cascades in solar wind plasma

Non-linear, three-dimensional, time-dependent fluid simulations of whistler wave turbulence are performed to investigate role of whistler waves in solar wind plasma turbulence in which characteristic turbulent fluctuations are characterized typically by the frequency and length-scales that are, respectively, bigger than ion gyrofrequency and smaller than ion gyroradius. The electron inertial length is an intrinsic length-scale in whistler wave turbulence that distinguishably divides the high-frequency solar wind turbulent spectra into scales smaller and bigger than the electron inertial length. Our simulations find that the dispersive whistler modes evolve entirely differently in the two regimes. While the dispersive whistler wave effects are stronger in the large-scale regime, they do not influence the spectral cascades which are describable by a Kolmogorov-like   k ^−7/3  spectrum. By contrast, the small-scale turbulent fluctuations exhibit a Navier–Stokes-like evolution where characteristic turbulent eddies exhibit a typical   k ^−5/3  hydrodynamic turbulent spectrum. By virtue of equipartition between the wave velocity and magnetic fields, we quantify the role of whistler waves in the solar wind plasma fluctuations.     

Assessment of degradation of agricultural soils arising from brick burning in selected soil profiles

The study was conducted with the selected soil profile of burnt (soil around brick kilns) and unburnt (agricultural land) soils in the Dinajpur, Rangpur, Rajshahi, Khulna and Patuakhali districts at the western part of Bangladesh to evaluate the effects of brick kilns on soil degradation and environmental pollution. The pH values of the unburnt soils increased as a function of the soil depth for Rangpur, Khulna and Patuakhali, while decreased for the soil profiles in Dinajpur. Burning of soils significantly (p<0.05) decreased the average pH values of soils by 0.4 pH units (7 % increased over average content = IOAC), but strikingly increased the average EC values from 0.26 to 1.77 mS/cm (592 % IOAC) and the effect was pronounced with the depth function. The average sand content of the soil profiles increased by 330%, while the silt and clay contents decreased by 49 and 40 %, respectively. The average losses arising from the burning of agricultural soils were amounted to 63% for organic matter, 56 to 86 % and 23 to 88 % for available and total N, P, K and S, respectively. This huge loss through the burning of 1 m deep soil profile, i.e. almost 3/4^th of the deterioration of soil fertility is not only reducing the crop production but also polluting the associated environment and atmosphere. The burning of enormous C, N and S not only degrade the agricultural soils but also contributing to the changes in the global climate.     

Comprehensive geochemical/hydrochemical and geo-thermometry analysis of Unai geothermal field,Gujarat, India

Acta Geochimica - The knowledge of water temperature produced from a geothermal reservoir and its composition is of utmost importance in designing utilization strategies, the surface production...     

Trace elements in ferromanganese nodules from the central indian ocean basin

Thirty-three bulk ferromanganese nodules from the sediment–water interface of siliceous sediment domain from the Central Indian Ocean Basin were analyzed for 50 elements including 6 new (Be, As, Se, Sn, Sb, and Bi) using inductively coupled plasma–mass spectrometer. The Mn/Fe ratio and triangular plot (Fe-Mn-{Cu+Ni+Co?×?10}) suggest that ferromanganese nodules are of hydrogenetic, early diagenetic, and diagenetic origin. In the ferromanganese nodules, Mo, Sb, Bi, and As are highly enriched ～320, 160, 90, and 50 times compared with upper continental crust, respectively. A majority of the elements such as Be, Sc, Ti, V, Co, As, Se, Sr, Y, Zr, Nb, Sn, rare earth elements (REEs), Pb, Bi, P, Th, U, Hf, and Ta are associated with Fe, whereas, Cu, Ni, Zn, Mo, Li, Ga, Sb, Mg, and Cs are associated with Mn in the ferromanganese nodules. Redox proxies such as U/Th (0.14) and Mo/Mn (0.0019) ratio in the ferromanganese nodules suggest their formation under oxic conditions.     

Coastal landform mapping around the Gulf of Khambhat using Landsat TM data

Landsat TM data was utilised for coastal geomorphic mapping around the Gulf of Khambhat. Various landforms like shoreline, estuaries, mudflats, islands, mangroves, relict aluvium, cliffs, dunes, flood plains, paleochannel, paleomeanders, oxbow lake, etc. were delineated. The estuaries were divided into salt-wedge estuary, fully mixed estuary and partially mixed estuary based on amount of freshwater discharge and nature of tidal currents. The mudflats were classified into high tide flats, intertidal slopes and subtidal zones. These classes were further classified based on their composition. It was concluded that TM data has broughtout many new features and improved the classification of coastal landforms. The presence of coastal features like drowned river valleys, paleomudflats, relict alluvium, dunes, paleomeanders, oxbow lake and terraces clearly indicate the sea-level changes of the Quarternary period.