Influences of forest canopy on snowpack accumulation and isotope ratios

The stable water isotopes, ²H and ¹⁸O, can be useful environmental tracers for quantifying snow contributions to streams and aquifers, but characterizing the isotopic signatures of bulk snowpacks is challenging because they can be highly variable across the catchment landscape. In this study, we investigate one major source of isotopic heterogeneity in snowpacks: the influence of canopy cover. We measured amounts and isotopic compositions of bulk snowpack, throughfall, and open precipitation during seven campaigns in mid-winter 2018 along forest-grassland transects at three different elevations (1196, 1297, and 1434 m above sea level) in a pre-Alpine catchment in Switzerland. Snowpack storages under forest canopies were 67 to 93% less than in adjacent open grasslands. On average, the water isotope ratios were higher in the snowpacks under forest canopy than in open grasslands (by 13.4 ‰ in δ²H and 2.3 ‰ in δ¹⁸O). This isotopic difference mirrored the higher isotope values in throughfall compared with open snowfall (by 13.5 ‰ in δ²H and 2.2 ‰ in δ¹⁸O). Although this may suggest that most of the isotopic differences in snowpacks under forests versus in open grasslands were attributable to canopy interception effects, the temporal evolution of snowpack isotope ratios indicated preferential effluxes of lighter isotopes as energy inputs increased and the snowpack ripened and melted. Understanding these effects of forest canopy on bulk snowpack snow water equivalent and isotopic composition are useful when using isotopes to infer snowmelt processes in landscapes with varying forest cover.     

Climate–water quality relationships in Texas reservoirs

Water temperature, dissolved oxygen, and concentrations of salts in surface water bodies can be affected by the natural environment and local human activities such as surface and ground water withdrawals, land use and energy extraction, and variability and long‐term trends in atmospheric conditions including temperature and precipitation. Here, we quantify the relationship between 121 indicators of mean and extreme temperature and precipitation and 24 water quality parameters in 57 Texas reservoirs using observational data records covering the period 1960 to 2010. Over time scales ranging from 1 week to 2 years, we find that water temperature, dissolved oxygen, pH, specific conductance, chloride, sulfate, and phosphorus all show consistent correlations with atmospheric predictors, including high and low temperature extremes, dry days, heavy precipitation events, and mean temperature and precipitation. Based on these relationships combined with regional climate projections, we expect climate change to increase water temperatures, decrease dissolved oxygen levels, decrease pH, increase specific conductance, and increase levels of sulfate and chloride in Texas reservoirs. Over decadal time scales, this may affect aquatic ecosystems in the reservoirs, including altering the risk of conditions conducive to algae occurrence, as well as affecting the quality of water available for human consumption and recreation. Copyright © 2015 John Wiley & Sons, Ltd.     

Quantifying the impacts of climate change and land use/cover change on runoff in the lower Connecticut River Basin

Climate change and land use and cover change (LUCC) have had great impacts on watershed hydrological processes. Although previous studies have focused on quantitative assessment of the impacts of climate change and human activities on decreasing run‐off change, few studies have examined regions that have significant increasing run‐off due to both climate variability and land cover change. We show that annual run‐off had a significant increasing trend from 1956 to 2014 in the U.S. lower Connecticut River Basin. Abrupt change point years of annual run‐off for four subbasins are detected by nonparametric Mann–Kendall–Sneyers test and reconfirmed by the double mass curve. We then divide the study period into 2 subperiods at the abrupt change point year in the early 1970s for each subbasin. The Choudhury–Yang equation based on Budyko hypothesis was used to calculate precipitation and potential evapotranspiration, and landscape elasticities of run‐off. The results show that the difference in mean annual run‐off between 2 subperiods for each subbasin ranged from 102 to 165.6 mm. Climate variations were the primary drivers of increasing run‐off in this region. Quantitative contributions of precipitation and potential evapotranspiration in all subbasins are 106.5% and ?3.6% on average, respectively. However, LUCC contributed both positively and negatively to run‐off: ?18.6%, ?13.3%, and 10.1% and 9.9% for 4 subbasins. This may be attributed to historical LUCC occurring after the abrupt change point in each subbasin. Our results provide critical insight on the hydrological dynamics of north‐east tidal river systems to communities and policymakers engaged in water resources management in this region.     

Reactive trace element enrichment in a highly modified, tidally inundated acid sulfate soil wetland: East Trinity, Australia

This study examines the abundance of trace elements in surface sediments of a former acid sulfate soil (ASS) wetland subjected to marine tidal inundation. Sediment properties of this highly modified study site are compared with those of an adjacent unmodified, intertidal mangrove forest. Whilst some trace elements (Al, Cd, Mn, Ni and Zn) were clearly depleted due to mobilisation and leaching in the previous oxic-acidic phase, other trace elements (As and Cr) displayed significant enrichment in the tidally inundated ASS. Many trace elements were strongly associated with the reactive Fe and acid volatile sulfide (AVS) fractions, suggesting that trace elements may be adsorbed to abundant reactive Fe phases or sequestered as sulfide minerals. These findings provide an important understanding of the fate and mobility of reactive iron, AVS and trace elements during tidal remediation of a formerly acidified Great Barrier Reef (GBR) catchment.     

Composition,pre-eruptive zonation,and geochronologic significance of the ∼450 ka Diamante Tuff,Andean Cordillera (34°S), Argentina

Vertical geochemical sampling through the Diamante Tuff establishes patterns of zonation in the pre-eruption magma. Volcanic glass demonstrates a roofward increase in Fe and Cl, and a roofward decrease in Ca. Trace elements have no measurable zonation. Welded volcanic glass shows post-eruption loss of Fe, Mg and Cl as well as K gain. Our reported glass chemistry provides robust criteria for correlation to other localities. The Diamante Tuff is an important stratigraphic marker and recognition of this unit provides age control on Quaternary deposits, allowing determination of process rates and elucidating timing of tectonic and geomorphic activity.     

Putting a spin on palaeotsunami deposits

Palaeotsunami research is a relatively young discipline and while considerable progress has been made in identifying the evidence of past events there are still difficulties on occasion in differentiating between palaeotsunami and palaeostorm deposits. This has tended to focus debate on the similarities and differences between deposits laid down by the two differing processes at the expense of alternative hypotheses. Although coastal research in New Zealand a decade ago drew attention to high elevation coarse sediment deposits laid down by waterspouts, it was largely ignored by the research community. Re‐analysis of a possible palaeotsunami deposit on a nearshore island in New Zealand, however, highlights the likelihood that this deposit, and perhaps many similar coastal ones, may have been laid down by waterspouts. In essence, the palaeotsunami–palaeostorm debate can no longer ignore waterspouts as an alternative hypothesis, but only time will tell how significant a contribution waterspouts have made to catastrophic coastal sedimentation. Copyright © 2016 John Wiley & Sons, Ltd.     

Some Physical and Computational Issues in Land Surface Data Assimilation of Satellite Skin Temperatures

Skin temperatures that reflect the radiating temperature of a surface observed by infrared radiometers are one of the most widely available products from polar orbiting and geostationary satellites and the most commonly used satellite data in land surface assimilation. Past work has indicated that a simple land surface scheme with a few key parameters constrained by observations such as skin temperatures may be preferable to complex land use schemes with many unknown parameters. However, a true radiating skin temperature is sometimes not a prognostic variable in weather forecast models. Additionally, recent research has shown that skin temperatures cannot be directly used in surface similarity forms for inferring fluxes. This paper examines issues encountered in using satellite derived skin temperatures to improve surface flux specifications in weather forecast and air quality models. Attention is given to iterations necessary when attempting to nudge the surface energy budget equation to a desired state. Finally, the issue of mathematical operator splitting is examined in which the surface energy budget calculations are split with the atmospheric vertical diffusion calculations. However, the high level of connectivity between the surface and first atmospheric level means that the operator splitting leads to high frequency oscillations. These oscillations may hinder the assimilation of skin temperature derived moisture fluxes.     

Seasonal and spatial heterogeneity of recent sea surface temperature trends in the Caribbean Sea and southeast Gulf of Mexico

Recent changes in ocean temperature have impacted marine ecosystem function globally. Nevertheless, the responses have depended upon the rate of change of temperature and the season when the changes occur, which are spatially variable. A rigorous statistical analysis of sea surface temperature observations over 25 years was used to examine spatial variability in overall and seasonal temperature trends within the wider Caribbean. The basin has experienced high spatial variability in rates of change of temperature. Most of the warming has been due to increases in summer rather than winter temperatures. However, warming was faster in winter in the Loop Current area and the south-eastern Caribbean, where the annual temperature ranges have contracted. Waters off Florida, Cuba and the Bahamas had a tendency towards cooling in winter, increasing the amplitude of annual temperature ranges. These detailed patterns can be used to elucidate ecological responses to climatic change in the region.     

双能CT的基本原理、应用和未来展望(英文)

断层影像(CT)的图像对比度与扫描所用的X光源能谱分布有很大关系。传统CT使用具有能谱分布的一个光源进行成像,有时会出现信息模糊致使两种不同材料在CT图像上完全相同。双能CT使用两个不同分布的能谱对物体进行成像,能够消除单能谱情况下的信息模糊。虽然双能CT的基本概念由来已久,但最近商业系统的出现使双能CT迅速成为一个热点。我们首先概述了双能CT的基本物理原理和双能信号处理方法,包括促使双能CT进入现代医学成像的关键技术。其次,双能CT的应用已非常广泛,本文从其在临床应用角度进行了详细介绍使读者有所了解。最后,我们简要探讨了当前的两个技术发展领域:光子技术探测器和技术合成CT。     

Effects of land use on water column bacterial activity and enzyme stoichiometry in stream ecosystems

Fifty streams, located in southern Ontario, Canada, were visited in September 2008 to investigate the effect of varying land use, land cover, and associated resource inputs on water column bacterial abundance (BACT), production (BP), and extracellular enzyme activity and stoichiometry. Principle components analysis was used to summarize landscape data, producing three components (PCs), which explained 79.2% of the variability in the data. The PCs grouped into the following gradients: (PC1) urban land use and continuous annual cropping to wetland-like cover, (PC2) rotational cropping to forest-like cover, and (PC3) increasing rural and agricultural land uses with increasing watershed size. These landscape gradients created imbalanced resource availability. Nutrient resources were more abundant in streams with more intensive anthropogenic land uses, but carbon availability was primarily controlled by the abundance of natural land covers (wetland and wooded areas). BACT, BP, and enzyme activities were positively related primarily to nutrient availability and/or anthropogenic land use (Stepwise R ² range: 0.33?C0.73). The ratio of ??-glucosidase to alkaline phosphatase activity approached a 1:1 balance with increasing anthropogenic land use, decreased wetland and forest cover, and increased total dissolved nitrogen. The ratio of leucine-aminopeptidase to alkaline phosphatase activity approached 1:1 with both increased dissolved organic carbon and nitrogen. Moreover, enzyme C:N:P ratios moved closer to 1:1:1 with faster water column bacterial turnover times. These results suggest that water column microbial communities are better able to balance resource availability with growth in streams receiving nutrient subsidies from anthropogenic sources and under these conditions when carbon resources increase.