Effects of humic substances on Fe(II) sorption onto aluminum oxide and clay

We studied the effects of humic substances (HS) on the sorption of Fe(II) onto Al-oxide and clay sorbents at pH 7.5 with a combination of batch kinetic experiments and synchrotron Fe K-edge EXAFS analyses. Fe(II) sorption was monitored over the course of 4 months in anoxic clay and Al-oxide suspensions amended with variable HS types (humic acid, HA; or fulvic acid, FA) and levels (0, 1, and 4 wt%), and with differing Fe(II) and HS addition sequences (co-sorption and pre-coated experiments, where Fe(II) sorbate was added alongside and after HS addition, respectively). In the Al-oxide suspensions, the presence of HS slowed down the kinetics of Fe(II) sorption, but had limited, if any, effect on the equilibrium aqueous Fe(II) concentrations. EXAFS analyses revealed precipitation of Fe(II)–Al(III)-layered double hydroxide (LDH) phases as the main mode of Fe(II) sorption in both the HA-containing and HA-free systems. These results demonstrate that HS slow down Fe(II) precipitation in the Al-oxide suspensions, but do not affect the composition or stability of the secondary Fe(II)–Al(III)-LDH phases formed. Interference of HS with the precipitation of Fe(II)–Al(III)-LDH was attributed to the formation organo-Al complexes HS limiting the availability of Al for incorporation into secondary layered Fe(II)-hydroxides. In the clay systems, the presence of HA caused a change in the main Fe(II) sorption product from Fe(II)–Al(III)-LDH to a Fe(II)-phyllosilicate containing little structural Al. This was attributed to complexation of Al by HA, in combination with the presence of dissolved Si in the clay suspension enabling phyllosilicate precipitation. The change in Fe(II) precipitation mechanism did not affect the rate of Fe(II) sorption at the lower HA level, suggesting that the inhibition of Fe(II)–Al(III)-LDH formation in this system was countered by enhanced Fe(II)-phyllosilicate precipitation. Reduced rates of Fe(II) sorption at the higher HA level were attributed to surface masking or poisoning by HA of secondary Fe(II) mineral growth at or near the clay surface. Our results suggest that HS play an important role in controlling the kinetics and products of Fe(II) precipitation in reducing soils, with effects modulated by soil mineralogy, HS content, and HS properties. Further work is needed to assess the importance of layered Fe(II) hydroxides in natural reducing environments.     

Chandrayaan-1 observation of distant secondary craters of Copernicus exhibiting central mound morphology: Evidence for low velocity clustered impacts on the Moon

Analysis of the Chandrayaan-1 Terrain Mapping Camera image of a 20 km×27 km area in the Mare Imbrium region revealed a cluster of thousands of fresh and buried impact craters in the size range of 20-1300 m. A majority of the large fresh craters with diameter ranging from 160 to 1270 m exhibit near-circular mounds (30-335 m diameter and 10-40 m height) in the crater floor, and their size depends on the host crater size. The origin of this cluster of secondary craters may be traced to Copernicus crater, based on global lunar image and the analysis of Chandrayaan-1 Hyper Spectral Imager data. Our findings provide further evidence for secondary crater formation by low-velocity impact of a cloud of clustered fragments. The presence of central mounds can also distinguish the secondary craters from the primary craters and refine the chronology of lunar surface based on counting of small craters.     

Possible role of warm SST bias in the simulation of boreal summer monsoon in SINTEX-F2 coupled model

Reasonably realistic climatology of atmospheric and oceanic parameters over the Asian monsoon region is a pre-requisite for models used for monsoon studies. The biases in representing these features lead to problems in representing the strength and variability of Indian summer monsoon (ISM). This study attempts to unravel the ability of a state-of-the-art coupled model, SINTEX-F2, in simulating these characteristics of ISM. The coupled model reproduces the precipitation and circulation climatology reasonably well. However, the mean ISM is weaker than observed, as evident from various monsoon indices. A wavenumber–frequency spectrum analysis reveals that the model intraseasonal oscillations are also weaker-than-observed. One possible reason for the weaker-than-observed ISM arises from the warm bias, over the tropical oceans, especially over the equatorial western Indian Ocean, inherent in the model. This warm bias is not only confined to the surface layers, but also extends through most of the troposphere. As a result of this warm bias, the coupled model has too weak meridional tropospheric temperature gradient to drive a realistic monsoon circulation. This in turn leads to a weakening of the moisture gradient as well as the vertical shear of easterlies required for sustained northward propagation of rain band, resulting in weak monsoon circulation. It is also noted that the recently documented interaction between the interannual and intraseasonal variabilities of ISM through very long breaks (VLBs) is poor in the model. This seems to be related to the inability of the model in simulating the eastward propagating Madden–Julian oscillation during VLBs.     

Eastward propagating MJO during boreal summer and Indian monsoon droughts

Improved understanding of underlying mechanism responsible for Indian summer monsoon (ISM) droughts is important due to their profound socio-economic impact over the region. While some droughts are associated with ‘external forcing’ such as the El-Niño and Southern Oscillation (ENSO), many ISM droughts are not related to any known ‘external forcing’. Here, we unravel a fundamental dynamic process responsible for droughts arising not only from external forcing but also those associated with internal dynamics. We show that most ISM droughts are associated with at least one very long break (VLB; breaks with duration of more than 10 days) and that the processes responsible for VLBs may also be the mechanism responsible for ISM droughts. Our analysis also reveals that all extended monsoon breaks (whether co-occurred with El-Niño or not) are associated with an eastward propagating Madden–Julian Oscillation (MJO) in the equatorial Indian Ocean and western Pacific extending to the dateline and westward propagating Rossby waves between 10° and 25°N. The divergent Rossby wave associated with the dry phase of equatorial convection propagates westward towards Indian land, couple with the northward propagating dry phase and leads to the sustenance of breaks. Thus, the propensity of eastward propagating MJO during boreal summer is largely the cause of monsoon droughts. While short breaks are not accompanied by westerly wind events (WWE) over equatorial western Pacific favorable for initiating air–sea interaction, all VLBs are accompanied by sustained WWE. The WWEs associated with all VLB during 1975–2005 initiate air–sea interaction on intraseasonal time scale, extend the warm pool eastward allowing the convectively coupled MJO to propagate further eastward and thereby sustaining the divergent circulation over India and the monsoon break. The ocean–atmosphere coupling on interannual time scale (such as El-Niño) can also produce VLB, but not necessary.     

Potential predictability of wet/dry spells transitions during extreme monsoon years: optimism for dynamical extended range prediction

The duration and extreme fluctuations of prolonged wet or dry spells associated with intraseasonal variability during extreme monsoon have devastating impacts on agrarian-based economy over Indian subcontinent. This study examines the potential predictability limit of intraseasonal transitions between rainy to non-rainy phases (i.e., active to break phases) or vice versa over central Indian region during extreme monsoon using very high-resolution (0.25° × 0.25°) daily rainfall datasets. The present study reveals that the transitions from both active to break and break to active conditions are more predictable by ~8 days during the weak monsoon (WM) years compared to the strong monsoon (SM) years. Such asymmetric behavior in the limit of predictability could be linked to the distinct differences in the large-scale seasonal mean background instability during SM and WM years. The achievability of such predictability is further evaluated in a state-of-the-art climate model, the climate forecast system (CFSv2). It is demonstrated that the observed asymmetry in predictability limit could be reproducible in the CFSv2 model, irrespective of its spatial resolution. This study provides impetus for useful dynamical prediction of wet/dry spells at extended range during the extreme monsoon years.     

Urban air pollution: process identification, impact analysis and evaluation of forecast potential

The daily variations in the atmospheric pollutants like suspended particulate matter (SPM), respirable suspended particulate matter (RSPM), sulphur dioxide (SO₂) and nitrogen dioxide (NO₂) depend on both local meteorological processes and various natural as well as anthropogenic sources and sinks. It was shown in an earlier work (Goswami and Baruah in Mon Wea Rev 136(9):3597?C3607, 2008) that the daily variations in SPM over a location could be simulated quite well by considering daily meteorological fields from NCEP Reanalysis in combination with a model for natural and anthropogenic sources over Delhi. In the present work, we extend the scope of the model to include three other pollutants: RSPM, SO₂ and NO₂. While the basic conservation equations and the meteorological fields are common to all the three (and SPM) pollutants, the sources and sinks for each is modeled in a species-specific manner to obtain maximum skill. As we do not consider active chemistry, the present model provides the minimal dynamics of pollution over an urban location in terms of annual load; the model error is about 10% on the average, with no significant bias for any of the species.     

Linking subaerial erosion with submarine geomorphology in the western Ionian Sea (south of the Messina Strait), Italy

Sediment supplied by continental sources is commonly suspected to have exerted a strong influence on the development of canyons and other morphological features on the continental slopes, but rarely is the sediment supply known sufficiently quantitatively to test this link. Here, we outline an area where offshore morphology, in the western Ionian Sea, may be linked to estimated sediment fluxes produced by subaerial erosion in NE Sicily and SW Calabria. Shelves in this area are narrow (<1 km), and the bathymetry shows that rivers and adjacent submarine channels are almost directly connected with each other. Integrated topographic analyses were performed on a merged digital elevation model (DEM) of ASTER data for subaerial topography and multibeam sonar data for submarine bathymetry. Spatial variations in sediment fluxes from onshore erosion were assessed using a variety of methods, namely: long‐term sediment flux from Pleistocene uplift rates, decadal sediment flux from landslide occurrences and published long‐term exhumation rates from ¹⁰Be cosmogenic nuclide concentrations. Submarine channels associated with rivers delivering larger sediment fluxes have broad channels, high relief and smooth concave‐upward longitudinal profiles. Conversely, submarine channels that lie offshore small‐flux rivers have straight longitudinal profiles, low relief and steep gradients. Where river catchments supply a greater sediment flux offshore, shelves tend to be wider (ca. 400 m) and submarine channels have gentler gradients. In contrast, where catchments supply less sediment flux, shelves are narrow (250–300 m) and offshore channel gradients are steeper. The variation of submarine morphology with tectonic uplift rate was also studied, but we find that, unlike onshore terrains where tectonics is commonly an important factor influencing channel morphology, in the submarine landscapes, sediment flux appears to dominate here.     

Insights into chondrule formation process and shock-thermal history of the Dergaon chondrite (H4-5)

The Dergaon fall represents a shock-melted H4-5(S5) ordinary chondrite which includes at least ten textural varieties of chondrules and belongs to the high chondrule-matrix ratio type.Our study reveals that the chondrules are of diverse mineralogy with variable olivine-pyroxene ratios(Type Ⅱ),igneous melt textures developed under variable cooling rates and formed through melt fractionations from two different melt reservoirs.Based on the experimental analogues,mineralogical associations and phase compositions,it is suggested that the Dergaon chondrules reflect two contrasting environments:a hot,dust-enriched and highly oxidized nebular environment through melting,without significant evaporation,and an arrested reducing environment concomitant with major evaporation loss of alkali and highly volatile trace elements.Coexistence of chlorapatite and merrillite suggests formation of the Dergaon matrix in an acidic accretionary environment.Textural integration and chemical homogenization occurred at ~ 1 atmospheric pressure and a mean temperature of 765 C mark the radiogenic thermal event.Equilibrated shock features(olivine mosaicism,diaplectic plagioclase,polycrystalline troilite) due to an impact-induced thermal event reflect a shock pressure 45 GPa and temperature of 600 C.By contrast,the local disequilibrium shock features(silicate melt veins comprising of olivine crystallites,troilite melt veins and metal droplets) correspond to a shock pressure up to 75 GPa and temperature950 ℃.     

The longest voyage: Tectonic,magmatic, and paleoclimatic evolution of the Indian plate during its northward flight from Gondwana to Asia

The tectonic evolution of the Indian plate, which started in Late Jurassic about 167 million years ago (~ 167 Ma) with the breakup of Gondwana, presents an exceptional and intricate case history against which a variety of plate tectonic events such as: continental breakup, sea-floor spreading, birth of new oceans, flood basalt volcanism, hotspot tracks, transform faults, subduction, obduction, continental collision, accretion, and mountain building can be investigated. Plate tectonic maps are presented here illustrating the repeated rifting of the Indian plate from surrounding Gondwana continents, its northward migration, and its collision first with the Kohistan–Ladakh Arc at the Indus Suture Zone, and then with Tibet at the Shyok–Tsangpo Suture. The associations between flood basalts and the recurrent separation of the Indian plate from Gondwana are assessed. The breakup of India from Gondwana and the opening of the Indian Ocean is thought to have been caused by plate tectonic forces (i.e., slab pull emanating from the subduction of the Tethyan ocean floor beneath Eurasia) which were localized along zones of weakness caused by mantle plumes (Bouvet, Marion, Kerguelen, and Reunion plumes). The sequential spreading of the Southwest Indian Ridge/Davie Ridge, Southeast Indian Ridge, Central Indian Ridge, Palitana Ridge, and Carlsberg Ridge in the Indian Ocean were responsible for the fragmentation of the Indian plate during the Late Jurassic and Cretaceous times. The Réunion and the Kerguelen plumes left two spectacular hotspot tracks on either side of the Indian plate. With the breakup of Gondwana, India remained isolated as an island continent, but reestablished its biotic links with Africa during the Late Cretaceous during its collision with the Kohistan–Ladakh Arc (~ 85 Ma) along the Indus Suture. Soon after the Deccan eruption, India drifted northward as an island continent by rapid motion carrying Gondwana biota, about 20 cm/year, between 67 Ma to 50 Ma; it slowed down dramatically to 5 cm/year during its collision with Asia in Early Eocene (~ 50 Ma). A northern corridor was established between India and Asia soon after the collision allowing faunal interchange. This is reflected by mixed Gondwana and Eurasian elements in the fossil record preserved in several continental Eocene formations of India. A revised India–Asia collision model suggests that the Indus Suture represents the obduction zone between India and the Kohistan–Ladakh Arc, whereas the Shyok-Suture represents the collision between the Kohistan–Ladakh arc and Tibet. Eventually, the Indus–Tsangpo Zone became the locus of the final India–Asia collision, which probably began in Early Eocene (~ 50 Ma) with the closure of Neotethys Ocean. The post-collisional tectonics for the last 50 million years is best expressed in the evolution of the Himalaya–Tibetan orogen. The great thickness of crust beneath Tibet and Himalaya and a series of north vergent thrust zones in the Himalaya and the south-vergent subduction zones in Tibetan Plateau suggest the progressive convergence between India and Asia of about 2500 km since the time of collision. In the early Eohimalayan phase (~ 50 to 25 Ma) of Himalayan orogeny (Middle Eocene–Late Oligocene), thick sediments on the leading edge of the Indian plate were squeezed, folded, and faulted to form the Tethyan Himalaya. With continuing convergence of India, the architecture of the Himalayan–Tibetan orogen is dominated by deformational structures developed in the Neogene Period during the Neohimalayan phase (~ 21 Ma to present), creating a series of north-vergent thrust belt systems such as the Main Central Thrust, the Main Boundary Thrust, and the Main Frontal Thrust to accommodate crustal shortening. Neogene molassic sediment shed from the rise of the Himalaya was deposited in a nearly continuous foreland trough in the Siwalik Group containing rich vertebrate assemblages. Tomographic imaging of the India–Asia orogen reveals that Indian lithospheric slab has been subducted subhorizontally beneath the entire Tibetan Plateau that has played a key role in the uplift of the Tibetan Plateau. The low-viscosity channel flow in response to topographic loading of Tibet provides a mechanism to explain the Himalayan–Tibetan orogen. From the start of its voyage in Southern Hemisphere, to its final impact with the Asia, the Indian plate has experienced changes in climatic conditions both short-term and long-term. We present a series of paleoclimatic maps illustrating the temperature and precipitation conditions based on estimates of Fast Ocean Atmospheric Model (FOAM), a coupled global climate model. The uplift of the Himalaya–Tibetan Plateau above the snow line created two most important global climate phenomena—the birth of the Asian monsoon and the onset of Pleistocene glaciation. As the mountains rose, and the monsoon rains intensified, increasing erosional sediments from the Himalaya were carried down by the Ganga River in the east and the Indus River in the west, and were deposited in two great deep-sea fans, the Bengal and the Indus. Vertebrate fossils provide additional resolution for the timing of three crucial tectonic events: India–KL Arc collision during the Late Cretaceous, India–Asia collision during the Early Eocene, and the rise of the Himalaya during the Early Miocene.     

Simulation of monsoon intraseasonal variability in NCEP CFSv2 and its role on systematic bias

We have evaluated the simulation of Indian summer monsoon and its intraseasonal oscillations in the National Centers for Environmental Prediction climate forecast system model version 2 (CFSv2). The dry bias over the Indian landmass in the mean monsoon rainfall is one of the major concerns. In spite of this dry bias, CFSv2 shows a reasonable northward propagation of convection at intraseasonal (30–60 day) time scale. In order to document and understand this dry bias over the Indian landmass in CFSv2 simulations, a two pronged investigation is carried out on the two major facets of Indian summer monsoon: one, the air–sea interactions and two, the large scale vertical heating structure in the model. Our analysis shows a possible bias in the co-evolution of convection and sea surface temperature in CFSv2 over the equatorial Indian Ocean. It is also found that the simulated large scale vertical heat source (Q1) and moisture sink (Q2) over the Indian region are biased relative to observational estimates. Finally, this study provides a possible explanation for the dry precipitation bias over the Indian landmass in the simulated mean monsoon on the basis of the biases associated with the simulated ocean–atmospheric processes and the vertical heating structure. This study also throws some light on the puzzle of CFSv2 exhibiting a reasonable northward propagation at the intraseasonal time scale (30–60 day) despite a drier monsoon over the Indian land mass.