Seasonal disparity in the co-occurrence of arsenic and fluoride in the aquifers of the Brahmaputra flood plains,Northeast India

Arsenic (As) and fluoride (F^?) in groundwater are increasing global water quality and public health concerns. The present study provides a deeper understanding of the impact of seasonal change on the co-occurrence of As and F^?, as both contaminants vary with climatic patterns. Groundwater samples were collected in pre- and post-monsoon seasons (n = 40 in each season) from the Brahmaputra flood plains (BFP) in northeast India to study the effect of season on As and F^? levels. Weathering is a key hydrogeochemical process in the BFP and both silicate and carbonate weathering are enhanced in the post-monsoon season. The increase in carbonate weathering is linked to an elevation in pH during the post-monsoon season. A Piper diagram revealed that bicarbonate-type water, with Na⁺, K⁺, Ca²⁺, and Mg²⁺ cations, is common in both seasons. Correlation between Cl^? and NO₃ ^? (r = 0.74, p = 0.01) in the post-monsoon indicates mobilization of anthropogenic deposits during the rainy season. As was within the 10 µg L^?1 WHO limit for drinking water and F^? was under the 1.5 mg L^?1 limit. A negative correlation between oxidation reduction potential and groundwater As in both seasons (r = ?0.26 and ?0.49, respectively, for pre-monsoon and post-monsoon, p = 0.05) indicates enhanced As levels due to prevailing reducing conditions. Reductive hydrolysis of Fe (hydr)oxides appears to be the predominant process of As release, consistent with a positive correlation between As and Fe in both seasons (r = 0.75 and 0.73 for pre- and post-monsoon seasons, respectively, at p = 0.01). Principal component analysis and hierarchical cluster analysis revealed grouping of Fe and As in both seasons. F^? and sulfate were also clustered during the pre-monsoon season, which could be due to their similar interactions with Fe (hydr)oxides. Higher As levels in the post-monsoon appears driven by the influx of water into the aquifer, which drives out oxygen and creates a more reducing condition suitable for reductive dissolution of Fe (hydr)oxides. An increase in pH promotes desorption of As oxyanions AsO₄ ^3? (arsenate) and AsO₃ ^3? (arsenite) from Fe (hydr)oxide surfaces. Fluoride appears mainly released from F^?-bearing minerals, but Fe (hydr)oxides can be a secondary source of F^?, as suggested by the positive correlation between As and F^? in the pre-monsoon season.     

Magnetic Evidence for Volcanism at Eastern Continental Margin of India: Juxtaposition with Elan Bank (Southern Indian Ocean)

The rifted Eastern Continental Margin of India (ECMI) has evolved as a result of breakup of East Gondwanaland. Previous geophysical studies of the continental margin have not elucidated upon its volcanic nature. Magnetics plays a useful role in the study of continental margins, particularly in identifying the volcanic units. The aeromagnetic map of the offshore Mahanadi basin of ECMI displays a conspicuous linear anomaly along the continental shelf. A comprehensive study of the published aeromagnetic, marine magnetic and gravity data of the offshore Mahanadi basin reveals the existence of a seaward dipping volcanic unit in the offshore Mahanadi basin bordering the Hinge zone. This inference suggests that the ECMI is a volcanic rifted margin. The study further indicates the deepening of the basement towards the sea. In addition, the existing geological studies on the ECMI demarcated the probable limit of the continental crust by studying the basement detached tectonic style of the sedimentation in sub-surface configuration of the East coast basins of India. The probable continental crustal limit, the Hinge zone, and the inner edge of the presently inferred volcanic unit conform to one another spatially in the offshore Mahanadi region. These features characterize the inferred volcanic body as seaward dipping reflectors (SDRs) that usually occur at the rifted continental margins. The deepening of the basement towards the sea and the presence of the volcanic body on the continental margin are indicative of the transitional nature of the crust. It is generally accepted that Antarctica and India were juxtaposed before the breakup of Gondwanaland. But the microcontinents in the southern Indian Ocean are neglected in the reconstruction of Gondwanaland continents. The recent studies of the discovery of continental crust within the Elan Bank (EB) microcontinent show that the EB was contiguous with the East coast of India before the breakup of Gondwanaland. Moreover, it is reported that the upper igneous crust of the EB consists of a 2–3 km thick layer of accumulated lava flows originating from the Kerguelen hotspot. An estimate shows that the total volume of volcanic and plutonic component of the Elan Bank is about 0.3 million cubic kilometers. The present inference of a volcanic body from the offshore Mahanadi basin is in agreement with the above observations of the juxtaposition of EB with ECMI.     

An Implicit Scheme for Shallow Water Flow with Wet Dry Interface

A finite difference implicit scheme is presented in this paper for solution of the shallow water equations in one dimensional (1D) form. The present model has many advantages like, handling of discontinuous and complex bed topography, satisfying C-property (preservation of motionless water surface over a wet or dry bed) and capability of handling large value of temporal step etc. Another very important feature of the present model is that, no special treatment of the source vector of the governing equations is required here to deal with very less water depth. To investigate the performance of the present model in diverse situations, it is used to replicate four different problems of known analytical solution, and the model is found to be quite capable for varied situations.     

What triggers Koyna region earthquakes? Preliminary results from seismic tomography digital array

The cause for prolific seismicity in the Koyna region is a geological enigma. Attempts have been made to link occurrence of these earthquakes with tectonic strain as well as the nearby reservoirs. With a view to providing reliable seismological database for studying the earth structure and the earthquake process in the Koyna region, a state of the art digital seismic network was deployed for twenty months during 1996–97. We present preliminary results from this experiment covering an area of 60 × 80 km² with twenty seismic stations. Hypocentral locations of more than 400 earthquakes confined to 11×25 km² reveal fragmentation in the seismicity pattern — a NE — SW segment has a dip towards NW at approximately 45°, whilst the other two segments show a near vertical trend. These seismic segments have a close linkage with the Western Ghat escarpment and the Warna fault. Ninety per cent of the seismicity is confined within the depth range of 3–10 km. The depth distribution of earthquakes delimits the seismogenic zone with its base at 10 km indicating a transition from an unstable to stable frictional sliding regime. The lack of shallow seismicity between 0 and 3 km indicates a mature fault system with well-developed gouge zones, which inhibit shallow earthquake nucleation. Local earthquake travel time inversion for P- and S-waves show ≈ 2% higher velocity in the seismogenic crust (0–10 km) beneath the epicentral tract relative to a lower velocity (2–3%) in the adjoining region. The high P- and S-wave velocity in the seismogenic crust argues against the presence of high pressure fluid zones and suggests its possible linkage with denser lithology. The zone of high velocity has been traced to deeper depths (≈ 70 km) through teleseismic tomography. The results reveal segmented and matured seismogenic fault systems in the Koyna region where seismicity is possibly controlled by strain build up due to competent lithology in the seismic zone with a deep crustal root.     

The Cadmium Zinc Telluride Imager on AstroSat

The Cadmium Zinc Telluride Imager (CZTI) is a high energy, wide-field imaging instrument on AstroSat. CZTI’s namesake Cadmium Zinc Telluride detectors cover an energy range from 20 keV to \(>200\) keV, with 11% energy resolution at 60 keV. The coded aperture mask attains an angular resolution of 17\(^\prime \) over a 4.6\(^\circ \) \(\times \) 4.6\(^\circ \)  (FWHM) field-of-view. CZTI functions as an open detector above 100 keV, continuously sensitive to GRBs and other transients in about 30% of the sky. The pixellated detectors are sensitive to polarization above \(\sim \)100 keV, with exciting possibilities for polarization studies of transients and bright persistent sources. In this paper, we provide details of the complete CZTI instrument, detectors, coded aperture mask, mechanical and electronic configuration, as well as data and products.     

Estimating of gas transfer velocity using triple isotopes of dissolved oxygen

The atmosphere-ocean exchange of climatically important gases is determined by the transfer velocity (k) and concentration gradient across the interface. Based on observations in the northwestern subarctic Pacific and Sagami Bay, we report here the results of the first ever application of the natural abundance of triple isotopes of dissolved oxygen (¹⁶O, ¹⁷O and ¹⁸O) for direct estimation of k and propose a new relationship with wind speed. The k values estimated from nighttime variations in oxygen isotopes are found to be higher than the direct estimations at low wind speed (<5 m s⁻¹) and lower at high wind speeds (>13 m s⁻¹) and showed significant spatial variability. The method presented here can be used to derive seasonal and spatial variations in k and the influence of surface conditions on the value, leading to improved estimates of biogenic/anthropogenic gas exchange at the air-sea interface.     

Photometry of HU Tauri

Photoelectric observations of the bright eclipsing binary system HU Tauri are presented. The observations were made with standardB andV filters. Observations made during the eclipses yielded six epochs of minimum light. A study of all the available times of minimum light has been made. Analysis of all the photoelectric times of minimum light yielded the following new ephemeris: JD 2441275.3166 +2 _. ^d 0563107E. Asymmetries in the light curves of HU Tauri were noticed.     

Stability Dependence of the Eddy-Accumulation Coefficients for Momentum and Scalars

From a set of turbulence data collected with a three-axis sonic anemometer/thermometer and described in a companion paper, we simulate the eddy-accumulation process for sensible heat and momentum fluxes. The resulting eddy-accumulation coefficient for momentum clearly depends on surface-layer stability; at neutral stability, its value is 0.63. On supplementing the scalar eddy-accumulation coefficients that we derive from our sensible heat flux data with values of sensible and latent heat flux coefficients reported by Businger and Oncley, we also find that scalar eddy-accumulation coefficients depend on stability, though more weakly than does the momentum coefficient. The coefficients for sensible and latent heat show no significant difference; we, thus, fit them with one function of stability whose value is 0.52 for neutral stratification.     

Statistics of Surface-Layer Turbulence Over Terrain with Metre-Scale Heterogeneity

Refuge has patchy vegetation in sandy soil. During midday and at night, the surface sources and sinks for heat and moisture may thus be different. Although the Sevilleta is broad and level, its metre-scale heterogeneity could therefore violate an assumption on which Monin-Obukhov similarity theory (MOST) relies. To test the applicability of MOST in such a setting, we measured the standard deviations of vertical (_w) and longitudinal velocity (_u), temperature (_t), and humidity (_q), the temperature-humidity covariance (¯tq), and the temperature skewness (S_t). Dividing the former five quantities by the appropriate flux scales (u_*, _*, and q_*) yielded the nondimensional statistics _w/u_*, _u/u_*, _t/|t_*|, _q/|q_*|, and ¯tq/t_*q_*. _w/u_*, _t/|t_*|, and S_t have magnitudes and variations with stability similar to those reported in the literature and, thus, seem to obey MOST. Though _u/u_* is often presumed not to obey MOST, our _u/u_* data also agree with MOST scaling arguments. While _q/|q_*| has the same dependence on stability as _t/|t_*|, its magnitude is 28% larger. When we ignore ¯tq/t_*q_* values measured during sunrise and sunset transitions – when MOST is not expected to apply – this statistic has essentially the same magnitude and stability dependence as (_t/t_*)². In a flow that truly obeys MOST, (_t/t_*)², (_q/q_*)², and ¯tq/t_*q_* should all have the same functional form. That (_q/q_*)² differs from the other two suggests that the Sevilleta has an interesting surface not compatible with MOST. The sources of humidity reflect the patchiness while, despite the patchiness, the sources of heat seem uniformly distributed.     

Characterisation and quality assessment of groundwater with a special emphasis on irrigation utility: Thirumanimuttar sub-basin, Tamil Nadu, India

Thirumanimuttar sub-basin is of particular importance in the study of groundwater quality due to the release of effluents from industries, agricultural, sewage and urban runoff, brining considerable change in water quality. An investigation was carried out by collecting a total of 194 groundwater samples for two seasons to decipher hydrogeochemistry and groundwater quality for determining its suitability for agricultural purposes. The water is neutral to alkaline in nature with pH ranging from 6.78 to 9.22 with an average of 7.37. Higher electrical conductivity (EC) was noted in NW and mid-downstream parts of the study area. Higher NO ₃ ^? was observed during post-monsoon (POM) due to the action of leaching and anthropogenic process. The piper plot reveals the dominance of Na⁺?CCl^? and Na⁺?CHCO ₃ ^? , mixed Ca²⁺?CNa⁺?CHCO ₃ ^? , mixed Ca²⁺?CMg²⁺?CHCO ₃ ^? and Ca²⁺?CSO ₄ ^? types of hydrogeochemical facies. Higher total hardness in the groundwater is due to the effect of dyeing and bleaching industries discharging effluents affects the quality of water. Residual Sodium Carbonate value indicates 56% of the samples are not suitable for irrigation purposes in both seasons. Higher sodium percentage is noted during PRM indicating the dominance of ion exchange and weathering. Higher sodium adsorption ratio was observed during POM indicating the effect of leaching and dissolution of salts into the aquifer matrix. USSL plot indicates 15% of samples record high salinity to medium sodicity. The Permeability Index indicates water is moderate to good for irrigation purposes. In general, groundwater in the study area is influenced by both natural and anthropogenic activities.