Climate change, adaptation and economic growth

This paper explores the links between economic growth and the impacts of climate change. Inclusive, pro-poor growth is central to the development of low-income countries. There is also a broad consensus that growth and development are important to reduce vulnerability to climate change. Growth does not automatically reduce vulnerability, only the right kind of growth does. The paper aims to develop a better understanding of what the ??right kind of growth?? may be. We find that many growth policies, such as investment in skills and access to finance, indeed reduce vulnerability to climate change. However, climate change calls for some adjustments in growth policy. In particular, investment in infrastructure and efforts to stimulate entrepreneurship and competitive markets must take more of a risk management perspective and recognise climate risks.     

Tropical precipitation, SSTs and the surface energy budget: a zonally symmetric perspective

The relative importance of sea surface temperatures (SSTs) and the surface energy budget to tropical precipitation is examined by comparing models with zonally symmetric climates, both fixed SST and coupled to a slab mixed layer ocean. Two models are considered with differing surface flux formulations and in each case solutions that are symmetric about the equator are perturbed to create interhemispheric asymmetry. When SSTs are prescribed in the two models with different flux formulations, the magnitude of tropical precipitation response to identical SST anomalies is significantly different, but the differences can be understood in terms of the altered surface fluxes. In contrast, when the net surface energy fluxes are constrained to be identical in mixed layer simulations of the two different models, the response of tropical precipitation to perturbations in the surface energy balance is very similar. Both perspectives predict qualitatively the same precipitation response, but the energy budget better predicts the magnitude of the precipitation response. Thus, we argue that the atmospheric energy budget, controlled in these experiments primarily by the surface energy budget, is more fundamental to the control of tropical precipitation than the SSTs, in these simulations with axisymmetric climates. We touch briefly on a complication in the interpretation of the model results due to the fact that fixed SST and slab-ocean versions of the model can produce different Hadley cell strengths for the same SSTs.     

Envisioning carbon capture and storage: expanded possibilities due to air capture,leakage insurance,and C-14 monitoring

In order to meet the challenge of climate change while allowing for continued economic development, the world will have to adopt a net zero carbon energy infrastructure. Due to the world’s large stock of low-cost fossil fuels, there is strong motivation to explore the opportunities for capturing the CO₂ that is produced in the combustion of fossil fuels and keeping it out of the atmosphere. Three distinct sets of technologies are needed to allow for climate neutral use of fossil fuels: (1) capture of CO₂ at concentrated sources like electric power plants, future hydrogen production plants and steel and cement plants; (2) capture of CO₂ from the air; and (3) the safe and permanent storage of CO₂ away from the atmosphere. A strong regime of carbon accounting is also necessary to gain the public’s trust in the safety and permanence of CO₂ storage. This paper begins with an extensive overview of carbon capture and storage technologies, and then presents a vision for the potential implementation of carbon capture and storage, drawing upon new ideas such as air capture technology, leakage insurance, and monitoring using a radioactive isotope such as C-14. These innovations, which may provide a partial solution for managing the risks associated with long-term carbon storage, are not well developed in the existing literature and deserve greater study.     

Grooves on small saturnian satellites and other objects: Characteristics and significance

High-resolution images from the Cassini Imaging Science Subsystem (ISS) show parallel sets of grooves on Epimetheus and Pandora. Grooves have previously been observed on other satellites and asteroids, including Phobos, Gaspra, Ida, Eros, and minor occurrences on Phoebe. Sets of parallel grooves are so far observed only on satellites known or likely to be subject to significant tidal stresses, such as forced librations. Grooves on asteroids and on satellites not subject to significant forced librations occur in more globally disorganized patterns that may reflect impacts, varying internal structures, or even thermal stresses. The patterns and individual morphologies of grooves on the tidally-affected satellites suggest fracturing in weak materials due to tidal stresses and forced librations.     

An alkaline spring system within the Del Puerto Ophiolite (California,USA): A Mars analog site

Mars appears to have experienced little compositional differentiation of primitive lithosphere, and thus much of the surface of Mars is covered by mafic lavas. On Earth, mafic and ultramafic rocks present in ophiolites, oceanic crust and upper mantle that have been obducted onto land, are therefore good analogs for Mars. The characteristic mineralogy, aqueous geochemistry, and microbial communities of cold-water alkaline springs associated with these mafic and ultramafic rocks represent a particularly compelling analog for potential life-bearing systems. Serpentinization, the reaction of water with mafic minerals such as olivine and pyroxene, yields fluids with unusual chemistry (Mg–OH and Ca–OH waters with pH values up to ～12), as well as heat and hydrogen gas that can sustain subsurface, chemosynthetic ecosystems. The recent observation of seeps from pole-facing crater and canyon walls in the higher Martian latitudes supports the hypothesis that even present conditions might allow for a rock-hosted chemosynthetic biosphere in near-surface regions of the Martian crust. The generation of methane within a zone of active serpentinization, through either abiogenic or biogenic processes, could account for the presence of methane detected in the Martian atmosphere. For all of these reasons, studies of terrestrial alkaline springs associated with mafic and ultramafic rocks are particularly timely. This study focuses on the alkaline Adobe Springs, emanating from mafic and ultramafic rocks of the California Coast Range, where a community of novel bacteria is associated with the precipitation of Mg–Ca carbonate cements. The carbonates may serve as a biosignature that could be used in the search for evidence of life on Mars.     

Flare-induced signals in polarization measurements during the X2.6 flare on 2005 January 15

Flare-induced signals in polarization measurements which were manifested as apparent polarity reversal in magnetograms have been reported since 1981. We are motivated to further quantify the phenomenon by asking two questions: can we distinguish the flare-induced signals from real magnetic changes during flares, and what we can learn about flare energy release from the flare-induced signals? We select the X2.6 flare that occurred on 2005 January 15, for further study. The flare took place in NOAA active re-gion (AR) 10720 at approximately the central meridian, which makes the interpretation of the vector magnetograms less ambiguous. We have identified that flare-induced signals during this flare appeared in six zones. The zones are located within an average distance of 5 Mm from their weight center to the main magnetic neutral line, have an average size of (0.6±0.4)×1017 cm2, duration of 13±4 min, and flux density change of 181±125 G in the area of reversed polarity. The following new facts have been revealed by this study: (1) the flare-induced signal is also seen in the transverse magnetograms but with smaller magnitude, e.g., about 50 G; (2) the flare-induced signal mainly manifests itself as apparent polarity reversal, but the signal starts and ends as a weakening of flux density; (3) The flare-induced signals appear in phase with the peaks of hard X-ray emission as observed by the Ramaty High Energy Solar Spectroscopic lmager (RHESSI), and mostly trace the position of RHESSI hard X-ray footpoint sources. (4) in four zones, it takes place cotemporally with real magnetic changes which persist after the flare. Only for the other two zones does the flux density recover to the pre-flare level immediately after the flare.The physical implications of the flare-induced signal are discussed in view of its relevance to the non-thermal electron precipitation and primary energy release in the flare.     

A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores

A new method for the radiogenic isotope (U–Th–Pa–Ra, Sr, Nd, Hf) analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two “clean-up” columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for ²³⁴U/²³⁸U of 1%, ²³⁰Th/²³²Th of 1.5%, [²²⁸Ra] of 9%, and ¹⁷⁶Hf/¹⁷⁷Hf of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: ⁸⁷Sr/⁸⁶Sr of 50 ppm and ¹⁴³Nd/¹⁴⁴Nd of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and Hf.     

The iron-nickel-phosphorus system: Effects on the distribution of trace elements during the evolution of iron meteorites

To better understand the partitioning behavior of elements during the formation and evolution of iron meteorites, two sets of experiments were conducted at 1 atm in the Fe-Ni-P system. The first set examined the effect of P on solid metal/liquid metal partitioning behavior of 22 elements, while the other set explored the effect of the crystal structures of body-centered cubic (α)- and face-centered cubic (γ)-solid Fe alloys on partitioning behavior. Overall, the effect of P on the partition coefficients for the majority of the elements was minimal. As, Au, Ga, Ge, Ir, Os, Pt, Re, and Sb showed slightly increasing partition coefficients with increasing P-content of the metallic liquid. Co, Cu, Pd, and Sn showed constant partition coefficients. Rh, Ru, W, and Mo showed phosphorophile (P-loving) tendencies. Parameterization models were applied to solid metal/liquid metal results for 12 elements. As, Au, Pt, and Re failed to match previous parameterization models, requiring the determination of separate parameters for the Fe-Ni-S and Fe-Ni-P systems.Experiments with coexisting α and γ Fe alloy solids produced partitioning ratios close to unity, indicating that an α versus γ Fe alloy crystal structure has only a minor influence on the partitioning behaviors of the trace element studied. A simple relationship between an element’s natural crystal structure and its α/γ partitioning ratio was not observed. If an iron meteorite crystallizes from a single metallic liquid that contains both S and P, the effect of P on the distribution of elements between the crystallizing solids and the residual liquid will be minor in comparison to the effect of S. This indicates that to a first order, fractional crystallization models of the Fe-Ni-S-P system that do not take into account P are appropriate for interpreting the evolution of iron meteorites if the effects of S are appropriately included in the effort.     

Compound- and enzyme-specific phosphodiester hydrolysis mechanisms revealed by δO of dissolved inorganic phosphate: Implications for marine P cycling

We have studied the oxygen isotope signature of inorganic phosphate (P_i) generated by hydrolysis of nucleic acid phosphodiester (P-diester) compounds by cell-free enzymes (Deoxyribonuclease 1, Phosphodiesterase 1, Alkaline phosphatase) and microbial cultures at natural isotopic abundances. We demonstrate that the diesterase-catalyzed hydrolytic step leads to incorporation of at least one water O into released P_i for a total of two O atoms from water incorporated into P_i released from P-diesters. In the presence of Phosphodiesterase 1, ¹⁶O is preferentially incorporated into nucleotides released from DNA; whereas ¹⁸O is preferentially incorporated into nucleotides released from RNA. A strong consistency between predicted O-isotope regeneration signatures based on results of cell-free enzyme experiments and measured isotopic signatures from independent experiments with E. coli cultures was observed and confirms proposed models for phosphoester hydrolysis. Results from these studies made at natural ¹⁸O abundance levels provide a new tool, enzyme-specific O-isotope fractionation, for investigations of organophosphate metabolism and phosphorus cycling pathways in natural aquatic systems.