Heterogeneous C<Subscript>16</Subscript>Zn<Subscript>8</Subscript>O<Subscript>8</Subscript> nanocluster as a selective CO/NO nanosensor: computational investigation

Density functional theory (DFT) calculations were employed to investigate the effects of adsorption of toxic carbon monoxide (CO) and nitrogen monoxide (NO) molecules on heterogeneous C₁₆Zn₈O₈ nanocage. A detailed analysis of the energetic, geometry, and electronic structure of various CO and NO adsorptions on the cluster surface was performed. It has been shown that CO molecule was adsorbed on the surface of the cluster resulting in more stable complex system, while NO molecule adsorption led to less stable system. These processes also changed the electronic properties of the cluster by reducing the HOMO/LUMO energy gap after adsorption process. Since this phenomenon led to an increment in the electrical conductivity of the cluster at a definite temperature, the C₁₆Zn₈O₈ was transformed to a stronger semiconductor substance upon the CO and NO adsorption. We believe that this research may be helpful in the several fields study such as sensor and catalyst investigation.     

Product formation from the gas-phase reactions of OH radicals and O3 with a series of monoterpenes

The formation yields of nine carbonyl products are reported from the gas-phase OH radical-initiated reactions (in the presence of NO _x ) and the O₃ reactions with seven monoterpenes. The products were identified using GC/MS and GC-FTIR and quantified by GC-FID analyses of samples collected on Tenax solid adsorbent cartridges. The identities of products from camphene, limonene and -pinene were confirmed by comparison with authentic standards. Sufficient quantities of products from the 3-carene, limonene, -pinene, sabinene and terpinolene reactions were isolated to allow structural confirmation by proton NMR spectroscopy. The measured total carbonyl formation yields ranged from non-detectable for the OH radical reaction with camphene and the O₃ reactions with 3-carene and limonene to 0.5 for the OH radical reaction with limonene and the O₃ reaction with sabinene.     

Backcasting long-term climate data: evaluation of hypothesis

Most often than not, incomplete datasets or short-term recorded data in vast regions impedes reliable climate and water studies. Various methods, such as simple correlation with stations having long-term time series, are practiced to infill or extend the period of observation at stations with missing or short-term data. In the current paper and for the first time, the hypothesis on the feasibility of extending the downscaling concept to backcast local observation records using large-scale atmospheric predictors is examined. Backcasting is coined here to contrast forecasting/projection; the former is implied to reconstruct in the past, while the latter represents projection in the future. To assess our hypotheses, daily and monthly statistical downscaling models were employed to reconstruct past precipitation data and lengthen the data period. Urmia and Tabriz synoptic stations, located in northwestern Iran, constituted two case study stations. SDSM and data-mining downscaling model (DMDM) daily as well as the group method of data handling (GMDH) and model tree (Mp5) monthly downscaling models were trained with National Center for Environmental Prediction (NCEP) data. After training, reconstructed precipitation data of the past was validated against observed data. Then, the data was fully extended to the 1948 to 2009 period corresponding to available NCEP data period. The results showed that DMDM performed superior in generation of monthly average precipitation compared with the SDSM, Mp5, and GMDH models, although none of the models could preserve the monthly variance. This overall confirms practical value of the proposed approach in extension of the past historic data, particularly for long-term climatological and water budget studies.     

Sedimentation within and among mangrove forests along a gradient of geomorphological settings

Coastal wetlands provide important ecological services to the coastal zone, one of which is sediment retention. In this study we investigated sediment retention across a range of geomorphological settings and across vegetation zones comprising coastal wetlands. We selected six coastal wetlands dominated by mangroves over a gradient from riverine to tidal settings in Southeast Queensland, Australia. Each site was comprised of three distinct vegetation communities distributed as parallel zones to the coast line: seaward fringe mangroves, landward scrub mangroves and saltmarsh/ cyanobacteria mat of the high intertidal zone. We measured suspended sediment retention and sedimentation rates. Additionally, in order to assess the origin of sediment transported and deposited in the mangroves, glomalin, a novel terrestrial soil carbon tracer, was used. Our results show a mean average sedimentation of 0.64 ± 0.01 mg cm⁻² spring tide⁻¹, which was variable within sites, regardless of geomorphological setting. However, geomorphological setting influenced spatial patterns of sediment deposition. Riverine mangroves had a more homogeneous distribution of sediments across the intertidal zone than tidal mangroves, where most sedimentation occurred in the fringe zone. Overall, the fringe zone retained the majority of sediment entering the coastal wetland during a tidal cycle with 0.90 ± 0.22 mg cm⁻² spring tide⁻¹, accounting for 52.5 ± 12.5% of the total sedimentation. The presence of glomalin in suspended sediments, and thus the relative importance of terrigenous sediment, was strongly influenced by geomorphological setting, with riverine mangroves receiving more glomalin in suspended solids than tidal mangroves. Glomalin was also differentially deposited within the vegetation zones at different geomorphological settings: primarily at the fringe zone of tidal mangroves and within the scrub zone of riverine mangroves. The differences we observed in the spatial distribution of sedimentation and the difference in the origin of the sediment deposited in riverine and tidal mangroves are likely to have an impact on ecological processes.     

Cyclic and Dynamic Behavior of Sand–Rubber and Clay–Rubber Mixtures

Geotechnical and Geological Engineering - In this paper, the possibility of using fine scrap tyre&nbsp;rubber to improve the mechanical properties of soil subjected to cyclic loading is...     

Nutrient dynamics in water and sediment of Mediterranean ponds across a wide hydroperiod gradient

In Mediterranean ponds, summer drought enhances seasonality whose intensity varies along topographic and climatic gradients. The alternation of wet and dry periods in rain dependent ponds affects their biogeochemistry and differentiates them from ponds fed by more stable water sources, such as groundwater springs. Superimposed onto this, land use is also a very strong factor of variability. In this study we compared nutrients and organic matter concentrations, in water and in sediment, among different types of Mediterranean ponds based on the source of water, hydroperiod and land use. Forty-three ponds were sampled in Eastern Spain corresponding to five pond types: (1) permanent spring ponds in lowlands, (2) permanent spring ponds in mountains, (3) semi-permanent rain ponds, (4) temporary rain ponds with long hydroperiod and (5) temporary rain ponds with short hydroperiod.The results of this study indicate relevant differences among these pond types. The temporary rain ponds with short hydroperiod are characterized by high turbidity due to suspension of sediment particles rich in phosphorous adsorbed onto them (argillotrophic aquatic systems). They are used for watering domestic sheep that enhance sediment suspension by trampling. Total phosphorous (TP) concentrations in the water are high (like those of hypertrophic lakes), but planktonic chlorophyll a is very low and not correlated with TP, because of the low P-bioavailavility in the water. At the other extreme, we have permanent ponds in lowlands fed by groundwater springs. They are heavily loaded with nitrates due to the surrounding intensive agriculture. In these and other permanent/semipermanent ponds chlorophyll is highly correlated with TP. Sediment characteristics provide a good indication of the hydroperiod, since desiccation has important effects on biogeochemical transformations. A threshold of 5% organic matter (OM) in the sediment separates temporary ponds with a short hydroperiod from those with a long hydroperiod, and a threshold of 8% separates the later from the semi-permanent and permanent ponds. Besides OM reduction, important loss of N occurs during desiccation through mineralization, ammonia volatization and the sequential nitrification/denitrification pathway. On the other hand, the increase of organic P mineralization in dry sediments does not represent a loss of P from the system, since o-P remains adsorbed or bound onto the soil. This leads to a low TN/TP ratio in sediments in temporary ponds with short hydroperiod. These characteristics have to be taken into account when establishing pond typologies and ecological thresholds to assess water quality in these unique aquatic habitats.     

The mass–metallicity relation in galaxy clusters: the relative importance of cluster membership versus local environment

Using a large (14 857), homogenously selected sample of cluster galaxies identified in the Sloan Digital Sky Survey Data Release 4, we investigate the impact of cluster membership and local density on the stellar mass–gas phase metallicity relation (MZR). We show that stellar metallicities are not suitable for this work, being relatively insensitive to subtle changes in the MZR. Accurate nebular abundances can be obtained for 1318 cluster galaxies in our sample and we show that these galaxies are drawn from clusters that are fully representative of the parent sample in terms of mass, size, velocity dispersion and richness. By comparing the MZR of the cluster galaxies with a sample of control galaxies matched in mass, redshift, fibre covering fraction and rest-frame   g − r   colour cluster galaxies are found to have, on average, higher metallicities by up to 0.04 dex. The magnitude of this offset does not depend strongly on galactic half-light radius or cluster properties such as velocity dispersion or cluster mass. The effect of local density on the MZR is investigated, using the presence of a near neighbour and both two- and three-dimensional density estimators. For all three metrics, it is found that the cluster galaxies in locally rich environments have higher median metallicities by up to ∼0.05 dex than those in locally poor environments (or without a near neighbour). Control (non-cluster) galaxies at locally high densities exhibit similar metal enhancements. Taken together, these results show that galaxies in clusters are, on average, slightly more metal rich than the field, but that this effect is driven by local overdensity and not simply cluster membership.     

Coronal Mass Ejections from Magnetic Systems Encompassing Filament Channels Without Filaments

Well-developed filament channels may be present in the solar atmosphere even when there is no trace of filament material inside them. Such magnetic systems with filament channels without filaments can result in coronal mass ejections that might appear to have no corresponding solar surface source regions. In this case study, we analyze CMEs on 9 August 2001 and 3 March 2011 and trace their origins to magnetic systems with filament channels containing no obvious filament material on the days around the eruptions.     

Modelled and measured concentrations of peroxy radicals and nitrate radical in the U.S. Gulf Coast region during TexAQS 2006

Measurements of total peroxy radicals (HO₂?+?RO₂) and nitrate radical (NO₃) were made on the NOAA research vessel R/V?Brown along the U.S. Gulf Coast during the TexAQS 2006 field campaign. The measurements were modelled using a constrained box-model based upon the Master Chemical Mechanism (MCM). The agreement between modelled and measured HO₂?+?RO₂ was typically within ??40% and, in the unpolluted regions, within 30%. The analysis of the model results suggests that the MCM might underestimate the concentrations of some acyl peroxy radicals and other small peroxy radicals. The model underestimated the measurements of NO₃ by 60?C70%, possibly because of rapid heterogeneous uptake of N₂O₅. The MCM model results were used to estimate the composition of the peroxy radical pool and to quantify the role of DMS, isoprene and alkenes in the formation of RO₂ in the different regions. The measurements of HO₂?+?RO₂ and NO₃ were also used to calculate the gas-phase budget of NO₃ and quantify the importance of organic peroxy radicals as NO₃ sinks. RO₂ accounted, on average, for 12?C28% of the total gas-phase NO₃ losses in the unpolluted regions and for 1?C2% of the total gas-phase NO₃ losses in the polluted regions.