Geochemical and mineralogical characterization of surficial sediments from the Northern Rias: Implications for sediment provenance and impact of the source rocks

A multidisciplinary study of the elemental geochemistry and mineralogical characteristics of the marine surficial sediment in the Northern Rias (NW Iberian Peninsula) has been carried out. The linkages between the marine sediment composition and their potential sources were examined.The influence of the river-borne sediments is only detected in the innermost part of the three Rias. Regional variations of the mineral assemblages are governed by the source-rock composition of the different geological complexes and the relative source-rock contribution controlled by the continental hydrology. Mineralogical composition of the Ortigueira Ria and adjacent shelf surficial sediments are mainly made up of mafic and ultramafic rocks of the Cape Ortegal complex indicated by the high content of Mg, Mn and chrysotile and riebeckite minerals. In areas nearby Ortegal complex the imprint of heavy minerals present in the surrounding rocks has also been recorded. Barqueiro and Viveiro Rias bed-sediments are influenced by granitic and metamorphic rocks from the Ollo de Sapo complex as revealed by the high contribution of muscovite and quartz.Mining activities in the continental domain left strong imprints on marine surficial sediments. Pyrite content is high in the innermost areas of the Ortigueira Ria since this mineral is exploited in the Mera River basin, whereas high muscovite percentages characterize the Viveiro Ria owing to the abundance of granitic rocks and its exploitation in the Landro River basin. Quartz content is high nearby Cape Estaca de Bares, induced by the presence of an important excavation of this material.     

Relationship between tilt changes and effusive-explosive episodes at an andesitic volcano: the 2004–2005 eruption at Volcán de Colima,México

Continuous tilt changes during the 2004–2005 effusive-explosive episodes at Volcán de Colima (México) were recorded simultaneously by two tiltmeters installed on opposite sides of the volcano at elevations of 2200 m and 3060 m above sea level. Data indicate that the 2004 lava extrusion was preceded by an inflation accompanied by a deflation. The 2005 explosion sequences were associated with a deflationary–inflationary tilt. The period between the 2004 extrusion and the 2005 explosions was characterized by an inflationary tilt during a 3 month period. Two deformation sources were located. The first was situated at a depth between 300 m and 1800 m beneath the crater at the northern flank of the volcano and was responsible for volcano deformation during the preliminary September 2004 stage, the October 2004 extrusion, and the initial stage of the transition period and the March 2005 explosion sequence. The second source was located at a depth between 1800 m and 2800 m beneath the crater at the southern flank of the volcano and was responsible for volcano deformation during the final stage of the transition period and the May–June 2005 explosion sequence.     

The Kwakshua Watersheds Observatory,central coast of British Columbia,Canada

The Kwakshua Watersheds Observatory (KWO) is an integrative watersheds observatory on the coastal margin of a rain-dominated bog-forest landscape in British Columbia (BC), Canada. Established in 2013, the goal of the KWO is to understand and model the flux of terrestrial materials from land to sea – the origins, pathways, processes and ecosystem consequences – in the context of long-term environmental change. The KWO consists of seven gauged watersheds and a network of observation sites spanning from land to sea and along drainage gradients within catchments. Time-series datasets include year-round measurements of weather, soil hydrology, streamflow, aquatic biogeochemistry, microbial ecology and nearshore oceanographic conditions. Sensor measurements are recorded every 5 min and water samples are collected approximately monthly. Additional observations are made during high-flow conditions. We used remote sensing to map watershed terrain, drainage networks, soils and terrestrial ecosystems. The watersheds range in size from 3.2 to 12.8 km², with varying catchment characteristics that influence hydrological and biogeochemical responses. Despite local variation, the overall study area is a global hotspot for yields of dissolved organic carbon, dissolved organic nitrogen and dissolved iron at the coastal margin. This observatory helps fill an important gap in the global network of observatories, in terms of spatial location (central coast of BC), climate (temperate oceanic), hydrology (very high runoff, pluvial regime), geology (igneous intrusive, glacially scoured), vegetation (bog rainforest) and soils (large stores of organic carbon).     

A statistical approach to disentangle environmental forcings in a lacustrine record: the Lago Chungará case (Chilean Altiplano)

A high resolution multiproxy study (magnetic susceptibility, X-ray diffraction, XRF scanner, gray-colour values, Total Organic Carbon, Total Inorganic Carbon, Total Carbon and Total Biogenic Silica) of the sedimentary infill of Lago Chungará (northern Chilean Altiplano) was undertaken to unravel the environmental forcings controlling its evolution using a number of different multivariate statistical techniques. Redundancy analyses enabled us to identify the main provenance of the studied proxies whereas stratigraphically unconstrained cluster analyses allowed us to distinguish the “outsiders” as result of anomalous XRF scanner acquisitions. Principal Component Analysis (PCA) was employed to identify and isolate the main underlying environmental gradients that characterize the sedimentary infill of Lago Chungará. The first eigenvector of the PCA could be interpreted as an indicator of changes in the input of volcaniclastic material, whereas the second one would indicate changes in water availability. The chronological model of this sedimentary sequence was constructed using 17 AMS ¹⁴C and 1 ²³⁸U/²³⁰Th dates in order to characterize the volcaniclastic input and the changes in water availability in the last 12,300 cal years BP. Comparison of the reconstructed volcaniclastic input of Lago Chungará with the dust particle record from the Nevado Sajama ice core suggested that the Parinacota volcano eruptions were the main source of dust during the mid and Late Holocene rather than the dry out lakes as has previously been pointed out. The comparison of the water availability reconstruction of Lago Chungará with three of the most detailed paleoenvironmental records of the region (Paco Cocha, Lake Titicaca and Salar Uyuni) showed an heterogeneous (and sometimes contradictory) temporal and spatial pattern distribution of moisture. Although the four reconstructions showed a good correlation, each lacustrine ecosystem responded differently to the moisture oscillations that affected this region. The variations in the paleoenvironmental records could be attributed to the dating uncertainities, lake size, lake morphology, catchment size and lacustrine ecosystem responses to the abrupt arid events.     

Damage analysis of simulated I-880 structures under the Loma Prieta Earthquake

This paper analyzes the collapse of the Cypress portion of the Nimitz freeway in Oakland, California, during the Loma Prieta Earthquake of 17 October 1989. The most important bent configuration is chosen to carry out a nonlinear dynamic analysis and damage evaluation using the program SARCF-III. The acceleration history recorded at a nearby location with similar soil properties is used as the input ground motion. In order to cover the uncertainty about the structural properties and reinforcing details six different structures models are utilized. The maximum dynamic internal forces are compared to the structural capacity. It is investigated whether the collapse can be explained using a simplified structural model and one of the available computer codes.     

Massive star formation in local luminous infrared galaxies

Luminous infrared galaxies (LIRGs) provide insights into star formation (SF) and nuclear activity (AGN) under extreme conditions. We are carrying out a multi-wavelength (X-rays, ultraviolet through mid-infrared, and radio) program to obtain high angular resolution observations of a volume-limited sample of local LIRGs. The typical distances to these LIRGs (D=35–75 Mpc) allow us to identify star clusters and H II regions on scales of tens to hundreds of parsecs. We present here recent results on properties of the massive star-forming regions and star clusters in two LIRGs in our sample, Arp 299 and NGC7469.     

Differential Late Paleozoic active margin evolution in South-Central Chile (37°S–40°S) – the Lanalhue Fault Zone

The N–S oriented Coastal Cordillera of South Central Chile shows marked lithological contrasts along strike at 38°S. Here, the sinistral NW–SE-striking Lanalhue Fault Zone (nomen novum) juxtaposes Permo-Carboniferous magmatic arc granitoids and associated, frontally accreted metasediments (Eastern Series) in the northeast with a Late Carboniferous to Triassic basal-accretionary forearc wedge complex (Western Series) in the southwest. The fault is interpreted as an initially ductile deformation zone with divergent character, located in the eastern flank of the basally growing, upwarping, and exhuming Western Series. It was later transformed and reactivated as a semiductile to brittle sinistral transform fault. Rb–Sr data and fluid inclusion studies of late-stage fault-related mineralizations revealed Early Permian ages between 280 and 270 Ma for fault activity, with subsequent minor erosion. Regionally, crystallization of arc intrusives and related metamorphism occurred between 306 and 286 Ma, preceded by early increments of convergence-related deformation. Basal Western Series accretion started at >290 Ma and lasted to 250 Ma. North of the Lanalhue fault, Late Paleozoic magmatic arc granitoids are nearly 100 km closer to the present day Andean trench than further south. We hypothesize that this marked difference in paleo-forearc width is due to an Early Permian period of subduction erosion north of 38°S, contrasting with ongoing accretion further south, which kinematically triggered the evolution of the Lanalhue Fault Zone. Permo-Triassic margin segmentation was due to differential forearc accretion and denudation characteristics, and is now expressed in contrasting lithologies and metamorphic signatures in todays Andean forearc region north and south of the Lanalhue Fault Zone.     

Geomorphology and geochronology of sackung features (uphill-facing scarps) in the Central Spanish Pyrenees

The paper analyses uphill-facing scarps and associated troughs developed in the oversteepened slopes of two neighbouring glacial valleys in the central Spanish Pyrenees. Previous studies of sackung landforms in the Pyrenees have argued for deglacial unloading as the genetic mechanism, but this causal and temporal relationship has not been proved due to the lack of chronological data. The antislope scarps in the two studied locations, Vallibierna and Estós, are developed in Palaeozoic metasedimentary rocks (parallel to the contour lines and the structural grain), occur in the intermediate sector of the hillslope, and are up to 0.5 km long and several meters high. A trench was excavated in a sackung trough fill in each of the valleys in order to gain information about their chronology and genesis. Charcoal from the lowermost unit in Vallibierna provided an age of 5.9 cal. ka for the sackung and extrapolation of the three dates obtained in Estós indicates that the trough formed ca. 7.6–7.8 cal. ka. Deglaciation of the studied sectors of the valleys occurred between 16 and 13 ka. The time lag of >5 ka suggests that glacial erosion and the subsequent debutressing of the oversteepened valley walls created slopes predisposed to sackung development, but did not initiate the movement. Seismic shaking is proposed as a probable triggering factor. This hypothesis, although supported by the sudden deformation event recorded by a failure plane exposed in Vallibierna trench, and by the seismic and neotectonic activity of the area, cannot be proved due to the lack of chronological information about paleoearthquakes.     

Experimental data on SOA formation from mixtures of anthropogenic and biogenic organic compounds

Secondary organic aerosols (SOA) constitute a significant fraction of the atmospheric particulate matter. Theses particles are formed as a consequence of the oxidation reaction of certain organic gases that leads to the formation of low-volatility compounds. As for other pollutants, air quality models allow the simulation of particle levels and thus models constitute a powerful tool in air quality management. Nevertheless, the accepted use of models must be based on the validation of its capacity to reproduce observed concentrations. Air monitoring sites provide measured information of a large variety of ambient pollutants. Unfortunately, measurements on SOA are not normally available, as current monitoring networks do not include instrumentation to distinguish primary from secondary sources of organic carbonaceous aerosol. This paper presents a set of photooxidation experiments performed in the European Photorreactor (EUPHORE) smog chamber (CEAM, Spain) under different experimental conditions to investigate SOA formation. The use of chambers allows the isolation of atmospheric chemistry and aerosol formation processes. Thus, although these measurements were obtained at initial precursor concentrations higher than those in atmospheric conditions, they constitute a valuable set of information for SOA model evaluation purposes.     

Deforestation of water‐repellent soils in Galicia (NW Spain): effects on surface runoff and erosion under simulated rainfall

At three adjacent sites in steeply sloping woodland in Galicia (NW Spain), surface runoff and associated erosion under simulated rainfall (64 mm h^?1) were measured on five occasions between June 1998 and July 1999. Two of the three sites had recently been deforested and topsoil added, and one of these two had been sown with grass, which was germinating at the onset of the study. Deforestation greatly increased runoff and erosion rates, and the recovery of plant cover reduced erosion. All three soils were very hydrophobic due to high levels of poorly humified organic matter, which led to higher runoff rates than expected, especially during dry periods. However, great structural stability prevented there being a significant correlation between runoff rate and soil erosion. Copyright © 2003 John Wiley & Sons, Ltd.