Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)

In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C₂₅ are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C₂₅ content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C₁₇ content compared to n-C₂₇, and phytane compared to n-C₁₈. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C₂₆ (hypersaline depositional environment), or isoprenoid C₂₅ and n-alkane C₂₂ for high alkalinity environment.This study showed that Sq/n-C₂₆ ratio can be used to assess the quality of organic substance in immature lacustrine sediments.     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

Zur Revision der GattungGloeocapsa Kützing (Cyanophyta)

Ohne Zusammenfassung Die vorliegende Arbeit entstand dank der Unterstützung der Alexander-von-Humboldt-Stiftung, Bad Godesberg.     

An estimate of the contribution of high nergy cosmic-ray protons to the absorbed dose inventory of a cometary nucleus

We discuss the contribution of cosmic-ray protons at all energies above 1 MeV to the absorbed doses of the surface layers of a comet. Since there exists no calculation which takes into account proton energy losses by means of losses to electrons and nuclear collisions (in a cascade process), and losses due to the low energy end-products of the cascade, we have made a rough estimate of all of these contributions. An analytical formula is proposed that allows a rapid estimate of ranges and the dose absorbed at any depth. We give dose-depth curves for two extreme values of the energy at which nuclear collisions begin to dominate the slowing-down process, and for an intermediate value we display the dose-depth curve down to 20 m from the surface. The relevance of these findings to dosimetry in comets and some alterations of cometary material are considered. The need for improving the analytical expression proposed is stressed.     

A note on the thermal component of the equation of state in solids

A simple method for determining the thermal component of the EOS of solids under high pressure is proposed. Application to the interior of the Earth gives results in agreement with recent geophysical data.     

A model of neptune according to the Savić-Kašanin theory

A model of the internal structure of Neptune has been calculated according to the Savi?-Ka?anin theory of behaviour of materials under high pressure.     

Identification of heterogeneous aquifer transmissivity using an AE-based method

Determination of hydraulic head, H, as a function of spatial coordinates and time, in ground water flow is the basis for aquifer management and for prediction of contaminant transport. Several computer codes are available for this purpose. Spatial distribution of the transmissivity, T(x,y), is a required input to these codes. In most aquifers, T varies in an erratic manner, and it can be characterized statistically in terms of a few moments: the expected value, the variance, and the variogram. Knowledge of these moments, combined with a few measurements, permits one to estimate T at any point using geostatistical methods. In a review of transmissivity data from 19 unconsolidated aquifers, Hoeksema and Kitanidis (1985) identified two types of the logtransmissivity Y= ln(T) variations: correlated variations with variance sigma2Yc and correlation scale, I(Y), on the order of kilometers, and uncorrelated variations with variance sigma2Yn. Direct identification of the logtransmissivity variogram, Gamma(Y), from measurements is difficult because T data are generally scarce. However, many head measurements are commonly available. The aim of the paper is to introduce a methodology to identify the transmissivity variogram parameters (sigma2Yc, I(Y), and sigma2Yn) using head data in formations characterized by large logtransmissivity variance. The identification methodology uses a combination of precise numerical simulations (carried out using analytic element method) and a theoretical model. The main objective is to demonstrate the application of the methodology to a regional ground water flow in Eagle Valley basin in west-central Nevada for which abundant transmissivity and head measurements are available.     

An analysis of heat waves in Serbia

In this study, heat waves at three meteorological stations in Serbia were analyzed based on the daily maximum temperature during the summer (June, July and August). The warmest summers as regards heat wave duration and severity occurred within the periods 1951–1952, 1987–1998 (especially 1994) and 2000–2007. The longest heat waves were recorded in 1952, lasting 16 days in Smederevska Palanka and 21 days in Ni?, while in 1994 in Belgrade lasting 18 days. The summer of 1994 in Belgrade and Smederevska Palanka, and 2003 in Ni? were characterized with the highest number of consecutive tropical days (21 and 29, respectively).The autoregressive-moving-average models were applied to generate long series of the daily maximum temperature, from which the relative frequencies of heat waves were estimated. The relationships between the longest heat waves, and the circulation conditions were analyzed using the subjective Hess–Brezowsky catalogue of weather types.