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491.
Pattern analysis techniques currently common within geography tend to focus either on characterizing patterns of spatial and/or temporal recurrence of a single event type (e.g., incidence of flu cases) or on comparing sequences of a limited number of event types where relationships between events are already represented in the data (e.g., movement patterns). The availability of large amounts of multivariate spatiotemporal data, however, requires new methods for pattern analysis. Here, we present a technique for finding associations among many different event types where the associations among these varying event types are not explicitly represented in the data or known in advance. This pattern discovery method, known as T-pattern analysis, was first developed within the field of psychology for the purpose of finding patterns in personal interactions. We have adapted and extended the T-pattern method to take the unique characteristics of geographic data into account and implemented it within a geovisualization toolkit for an integrated computational-geovisual environment we call STempo. To demonstrate how T-pattern analysis can be employed in geographic research for discovering patterns in complex spatiotemporal data, we describe a case study featuring events from news reports about Yemen during the Arab Spring of 2011–2012. Using supplementary data from the Global Database of Events, Language, and Tone, we briefly summarize and reference a separate validation study, then evaluate the scalability of the T-pattern approach. We conclude with ideas for further extensions of the T-pattern technique to increase its utility for spatiotemporal analysis.  相似文献   
492.
Historical and proxy records document that there is a substantial asynchronous development in temperature, precipitation and glacier variations between European regions during the last few centuries. The causes of these temporal anomalies are yet poorly understood. Hence, highly resolved glacier reconstructions based on historical evidence can give valuable insights into past climate, but they exist only for few glaciers worldwide. Here, we present a new reconstruction of length changes for the Glacier des Bossons (Mont Blanc massif, France), based on unevaluated historical material. More than 250 pictorial documents (drawings, paintings, prints, photographs, maps) as well as written accounts have been critically analysed, leading to a revised picture of the glacier’s history, especially from the mid-eighteenth century up to the 1860s. Very important are the drawings by Jean-Antoine Linck, Samuel Birmann and Eugène Viollet-le Duc, which depict meticulously the glacier’s extent during the vast advance and subsequent retreat during the nineteenth century. The new glacier reconstruction extends back to AD 1580 and proves maxima of the Glacier des Bossons around 1610/1643, 1685, 1712, 1777, 1818, 1854, 1892, 1921, 1941, and 1983. The Little Ice Age maximum extent was reached in 1818. Until the present, the glacier has lost about 1.5 km in length, and it is now shorter than at any time during the reconstruction period. The Glacier des Bossons reacts faster than the nearby Mer de Glace (glacier reconstruction back to AD 1570 available). The Mont Blanc area is, together with the valley of Grindelwald in the Swiss Alps (two historical glacier reconstructions available back to AD 1535, and 1590, respectively), among the two regions that are probably best-documented in the world regarding historical glacier data.  相似文献   
493.
We investigate the response of a climate system model to two different methods for estimating snow cover fraction. In the control case, snow cover fraction changes gradually with snow depth; in the alternative scenarios (one with prescribed vegetation and one with dynamic vegetation), snow cover fraction initially increases with snow depth almost twice as fast as the control method. In cases where the vegetation was fixed (prescribed), the choice of snow cover parameterization resulted in a limited model response. Increased albedo associated with the high snow caused some moderate localized cooling (3–5°C), mostly at very high latitudes (>70°N) and during the spring season. During the other seasons, however, the cooling was not very extensive. With dynamic vegetation the change is much more dramatic. The initial increases in snow cover fraction with the new parameterization lead to a large-scale southward retreat of boreal vegetation, widespread cooling, and persistent snow cover over much of the boreal region during the boreal summer. Large cold anomalies of up to 15°C cover much of northern Eurasia and North America and the cooling is geographically extensive in the northern hemisphere extratropics, especially during the spring and summer seasons. This study demonstrates the potential for dynamic vegetation within climate models to be quite sensitive to modest forcing. This highlights the importance of dynamic vegetation, both as an amplifier of feedbacks in the climate system and as an essential consideration when implementing adjustments to existing model parameters and algorithms.  相似文献   
494.
Cemeteries are understudied integral components to urban watersheds, which provide ecosystem services but can also export nutrients, trace elements, and other contaminants to nearby water bodies. In this study, we focus on Meadowbrook Creek, an urban headwater stream in Syracuse, New York (USA), which has shown significant nitrate contributions from a local cemetery. We collected biweekly surface water samples over the course of 1 year from 2022 to 2023 for analysis of major and trace elemental concentrations including Na, Ca, Mg, K, F, Cl, sulfate, and nitrate. Here, we aim to assess the impact of various human infrastructures on urban stream water quality with a particular focus on the cemetery and nitrate. A comparison between the new dataset in this study and previously reported water chemistry data in Meadowbrook in 2012 suggests a decade-long impact of road salting and the cemetery on water quality particularly with respect to Na, Cl, and nitrate. Sulfate, Mg, Ca, and K are likely mainly geogenic. Stable nitrogen isotope data, the usage of concrete or steel vaults in the cemetery in the past 50 years, and the lack of correlation between nitrate and fluoride concentrations in stream water argue against burial decay products being a major source of nitrate to the stream. Instead, other nitrate sources that exist in the cemetery such as, fertilizer, decaying plant material, and wastewater, are more viable dominant nitrate sources. In addition, nitrate loading calculations indicate that the groundwater-connected reach, including the cemetery, acts as an annual net sink for nitrate despite the seasonally varying sink-source patterns.  相似文献   
495.
A method has been developed for the analysis of D/H ratios of non-exchangeable hydrogen in plant cellulose. Plant samples are nitrated at low temperature and pure cellulose nitrate is extracted by acetone dissolution. Tests of this nitrated product have demonstrated that the nitration-extraction procedure eliminates the OH hydrogen and does not alter the D/H ratio of the cellulose carbon-bound hydrogen. Significant differences exist between δD values of plant total hydrogen and δD values of cellulose nitrate hydrogen. This difference is due to the effect of chemical heterogeneity of the δD value of plant material. Plant-extracted cellulose nitrate D/H ratios are systematically related to the D/H ratios of the associated environmental water. The overall relationship is linear with slope of one and intercept of ?22%. Five aquatic plants which grew at 16–17°C are related isotopically to the water by a linear curve with a slope of 1 and intercept of ?36%. Three plants which grew at 28–29°C have an intercept of ?11%. The general dependence of plant cellulose non-exchangeable hydrogen D/H ratios on the D/H ratios of the associated environmental water suggests that variations of the extracted cellulose nitrate δD values of plants can be used as indicators of climatic change.  相似文献   
496.
Due to the severity related to extreme flood events, recent efforts have focused on the development of reliable methods for design flood estimation. Historical streamflow series correspond to the most reliable information source for such estimation; however, they have temporal and spatial limitations that may be minimized by means of regional flood frequency analysis (RFFA). Several studies have emphasized that the identification of hydrologically homogeneous regions is the most important and challenging step in an RFFA. This study aims to identify state‐of‐the‐art clustering techniques (e.g., K ‐means, partition around medoids, fuzzy C‐means, K ‐harmonic means, and genetic K ‐means) with potential to form hydrologically homogeneous regions for flood regionalization in Southern Brazil. The applicability of some probability density function, such as generalized extreme value, generalized logistic, generalized normal, and Pearson type 3, was evaluated based on the regions formed. Among all the 15 possible combinations of the aforementioned clustering techniques and the Euclidian, Mahalanobis, and Manhattan distance measures, the five best were selected. Several watersheds' physiographic and climatological attributes were chosen to derive multiple regression equations for all the combinations. The accuracy of the equations was quantified with respect to adjusted coefficient of determination, root mean square error, and Nash–Sutcliffe coefficient, whereas, a cross‐validation procedure was applied to check their reliability. It was concluded that reliable results were obtained when using robust clustering techniques based on fuzzy logic (e.g., K ‐harmonic means), which have not been commonly used in RFFA. Furthermore, the probability density functions were capable of representing the regional annual maximum streamflows. Drainage area, main river length, and mean altitude of the watershed were the most recurrent attributes for modelling of mean annual maximum streamflow. Finally, an integration of all the five best combinations stands out as a robust, reliable, and simple tool for estimation of design floods.  相似文献   
497.
We undertook a boat expedition to explore the geological framework of a very remote, lesser-known island, in the Chilean Patagonia: the Diego de Almagro Island(latitude S51°330'). This uninhabited, ca.400 km~2 Island is one of the very rare exposures of the Mesozoic accretionary subduction complex along the Chilean margin. Unstable weather, strong winds, steep topography, and very dense vegetation make an on-land mission difficult. Careful preparation based on high-resolution satellite images is advised to optimize shore access and minimize risks of injury. Despite a relatively important degree of regional reequilibration of metamorphic assemblages due to sluggish exhumation through the forearc crust, our results have shown that the island is composed of a nappe stack of ocean-floor derived slivers of metasedimentary units that exhibit very different pressure-temperature-time paths during burial by subduction under the Chilean margin and subsequent exhumation. These rocks are witness to a complex thermal evolution of the subduction zone between Jurassic and Cretaceous times from granulite facies to blueschist facies conditions as well as multiple episodes of accretion at ca. 35 -40 km in depth for almost100 Ma over the Mesozoic era.  相似文献   
498.
The metasomatism observed in the oceanic and continental lithosphere is generally interpreted to represent a continuous differentiation process forming anhydrous and hydrous veins plus a cryptic enrichment in the surrounding peridotite. In order to constrain the mechanisms of vein formation and potentially clarify the nature and origin of the initial metasomatic agent, we performed a series of high-pressure experiments simulating the liquid line of descent of a basanitic magma differentiating within continental or mature oceanic lithosphere. This series of experiments has been conducted in an end-loaded piston cylinder apparatus starting from an initial hydrous ne-normative basanite at 1.5 GPa and temperature varying between 1,250 and 980°C. Near-pure fractional crystallization process was achieved in a stepwise manner in 30°C temperature steps and starting compositions corresponding to the liquid composition of the previous, higher-temperature glass composition. Liquids evolve progressively from basanite to peralkaline, aluminum-rich compositions without significant SiO2 variation. The resulting cumulates are characterized by an anhydrous clinopyroxene + olivine assemblage at high temperature (1,250–1,160°C), while at lower temperature (1,130–980°C), hydrous cumulates with dominantly amphibole + minor clinopyroxene, spinel, ilmenite, titanomagnetite and apatite (1,130–980°C) are formed. This new data set supports the interpretation that anhydrous and hydrous metasomatic veins could be produced during continuous differentiation processes of primary, hydrous alkaline magmas at high pressure. However, the comparison between the cumulates generated by the fractional crystallization from an initial ne-normative liquid or from hy-normative initial compositions (hawaiite or picrobasalt) indicates that for all hydrous liquids, the different phases formed upon differentiation are mostly similar even though the proportions of hydrous versus anhydrous minerals could vary significantly. This suggests that the formation of amphibole-bearing metasomatic veins observed in the lithospheric mantle could be linked to the differentiation of initial liquids ranging from ne-normative to hy-normative in composition. The present study does not resolve the question whether the metasomatism observed in lithospheric mantle is a precursor or a consequence of alkaline magmatism; however, it confirms that the percolation and differentiation of a liquid produced by a low degree of partial melting of a source similar or slightly more enriched than depleted MORB mantle could generate hydrous metasomatic veins interpreted as a potential source for alkaline magmatism by various authors.  相似文献   
499.
The so-called ‘force-restore method’ has been used with considerable success in numerical weather prediction models to simulate diurnal variations of ground temperature. This note demonstrates that the force-restore equation is no more nor less than an approximation to the surface-energy-balance equation. The applicability of the method to the case of multi-component heating functions and to the case in which the soil is covered by a litter layer is discussed.  相似文献   
500.
Dimethylsulfide (DMS), sulfur dioxide (SO2), methanesulfonate (MSA), nonsea-salt sulfate (nss-SO4 2–), sodium (Na+), ammonium (NH4 +), and nitrate (NO3 ) were determined in samples collected by aircraft over the open ocean in postfrontal maritime air masses off the northwest coast of the United States (3–12 May 1985). Measurements of radon daughter concentrations and isentropic trajectory calculations suggested that these air masses had been over the Pacific for 4–8 days since leaving the Asian continent. The DMS and MSA profiles showed very similar structures, with typical concentrations of 0.3–1.2 and 0.25–0.31 nmol m–3 (STP) respectively in the mixed layer, decreasing to 0.01–0.12 and 0.03–0.13 nmol m–3 (STP) at 3.6 km. These low atmospheric DMS concentrations are consistent with low levels of DMS measured in the surface waters of the northeastern Pacific during the study period.The atmospheric SO2 concentrations always increased with altitude from <0.16–0.25 to 0.44–1.31 nmol m–3 (STP). The nonsea-salt sulfate (ns-SO4 2–) concentrations decreased with altitude in the boundary layer and increased again in the free troposphere. These data suggest that, at least under the conditions prevailing during our flights, the production of SO2 and nss-SO4 2– from DMS oxidation was significant only within the boundary layer and that transport from Asia dominated the sulfur cycle in the free troposphere. The existence of a sea-salt inversion layer was reflected in the profiles of those aerosol components, e.g., Na+ and NO3 , which were predominantly present as coarse particles. Our results show that long-range transport at mid-tropospheric levels plays an important role in determining the chemical composition of the atmosphere even in apparently remote northern hemispheric regions.  相似文献   
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