Geochemistry and Mineralogy of Paleocene Coal from the Padhrar and Darra Adam Khel Coalfields of Pakistan

Pakistan is rich in coal resources, which amount to around 186 billion tons. The Paleocene Padhrar and Darra Adam Khel coalfields are located in the Central Salt Range Punjab Province and the Khyber Pakhtunkhwa Province, Pakistan, respectively. Padhrar coal has not been studied in detail and the Darra Adam Khel coalfields are newly-discovered, so no research has been done, due to security considerations. In this study, an attempt has been made to study the geochemical and mineralogical characteristics of the Padhrar and Darra Adam Khel coals, in order to learn about the coal quality, element enrichment mechanism, sedimentary medium conditions and potentially valuable elements for coal utilization. The Padhrar and Darra Adam Khel coals are low to medium ash, low moisture content, high in volatiles and high total sulfur coal. The vitrinite reflectance in Darra Adam Khel coal is higher than in Padhrar coal, indicating either a greater burial depth or the effects of Himalayan tectonism. The vitrinite content is dominant in the Padhrar and Darra Adam Khel coals, followed by inertinite and liptinite, the major minerals including quartz, clay minerals, calcite and pyrite. The trace elements Ni, As, Be Zn, Ge, Mo, Ta, W, Co and Nb, Sn, Hf, Ta, Pb, Th, Cd, In, Be, V, Cr, Zr, Ag, Li, W and Co are concentrated in some of the Padhrar and Darra Adam Khel coal samples, respectively. The Padhrar coal shows positive Ce, Eu and Gd anomalies, with most of the Darra Adam Khel coal showing negative Ce, Eu and positive Gd anomalies with high LREE. The Al2O3/TiO2 values indicate that the sediment source of the Padhrar and Darra Adam Khel coals is mostly related to intermediate igneous rocks. The Sr/Ba, SiO2 + Al2O3, Fe2O3 + CaO + MgO/SiO2 + Al2O3 and high sulfur content in the Padhrar and Darra Adam Khel coals indicate epithermal and marine water influence with a tidal flat, coal-forming environment and a deltaic coal-forming environment, respectively.     

Photo-induced degradation of emamectin benzoate: effect of iron amendments and solvent system

Photodegradation is the major dissipation pathway for emamectin benzoate (EB) in water. Therefore, the photolysis of EB was studied in distilled water (DW) and methanol under different irradiation conditions such as natural sunlight, UV tube, and artificially stimulated light (mercury lamp 125 W). The results of the study showed that EB degrades rapidly in DW than in methanol as evidenced by a photodegradation efficiency of about 75 % achieved in DW, after 24 h of irradiation with UV light, while in methanol, it was only 59.3 %. The addition of iron to EB solution in DW further enhanced its photodegradation. The rate of photodegradation of EB was recorded to be increased from 5.5 × 10^?2 to 1.0 × 10^?1 k/h after amendment with iron. The order for the rate of photodegradation of EB was DW + Fe > DW > methanol, with their respective t _1/2 values of 6.5, 12.6, and 18.7 h. Fe amendment was also found to enhance the degradation efficiency of EB even in the absence of any light (dark).     

Offshore Carbonate Facies Characterization and Reservoir Quality of Miocene Rocks in the Southern Margin of South China Sea

Carbonate rocks are important hydrocarbon reservoirs around the globe and in Southeast Asia a key one, particularly, is the Central Luconia province. Understanding the internal characteristics, distribution, geometry and lateral extent of these rocks is essential for exploration and production success. Detailed work on Miocene carbonate reservoir facies, north of Bintulu, offshore Sarawak includes qualitative and quantitative analysis of photomicrographs and reservoir quality, considering especi...     

Studies of clump structure of photodissociation regions at millimeter and sub-millimeter wavelengths

To interpret the millimeter and sub-millimeter line emissions of atomic and molecular species from galactic and extragalactic photodissociation regions, warm gas components and molecular clouds, generally, escape probability formalism of Tielens & Hollenbach (herein referred as TH) are employed which is based on the assumption of plane parallel geometry of infinite slab allowing photons to escape only from the front. Contrary to the assumption observationally it is found that these lines are optically thin except OI(63μ m) and low rotational transitions of CO and some other molecules. This observational evidence led us to assume that emitting regions are finite parallel plane slab in which photons are allowed to escape from both the surfaces (back and front). Therefore, in the present study escape of radiations from both sides of the homogeneous and also clumpy PDR/molecular clouds are taken into consideration for calculating the line intensities at millimeter and sub-millimeter wavelengths (hereinafter referred as QA). Results are compared with that of the TH model. It is found that thermal and chemical structures of the regions are almost similar in both the formalisms. But line intensities are modified by differing factors. Particularly at low density and low kinetic temperature and also for optically thin lines line intensities calculated from TH and QA model differ substantially. But at density higher than the critical density and also for optically thick lines TH and QA models converge to almost same values. An attempt has been made to study the physical conditions of the M17 region employing the present formalism.     

Emission quantification of refrigerant CFCs,HCFCs and HFCs in megacity Lahore (Pakistan) and contributed ODPs and GWPs

An integrated assessment of emissions of some important refrigerant ozone depleting substances (ODSs) (CFC-11, CFC-12, HCFC-141b and HFC-134a) and their contributed ozone depletion potentials (ODPs) and global warming potentials (GWPs) have been made in the megacity Lahore (Pakistan) for the period from 2005 to 2013. During the production of 6.488 million refrigerator units, the cumulative estimated emissions of CFC-11, CFC-12, HCFC-141b and HFC-134a were 129.7, 6.8, 1257 and 104 mega grams (1 Mg = 10⁶ grams). The estimated GWP (CO₂-eq) and ODP (CFC 11-eq) associated with production phase emissions of these four gases were 616.07, 73.52, 910.96, and 87.36 kilotonnes, and 129.7, 6.8, 139.4, and 0 tonnes, respectively. ODP of HFC-134a is considered to be zero. In addition, the repair and maintenance of 81.2 thousand units resulted in 10.8 Mg emissions of CFC-12 with 10.8 tonnes ODP(CFC 11-eq) and 117,802 tonnes GWP (CO₂-eq) that were higher than the HFC-134a emissions recorded at 4.3 Mg causing 4563 tonnes GWP(CO₂-eq). A decrease in ODP (CFC 11-eq) and GWP (CO₂-eq) at the rate of ?8.3% and ?8.2% per year is observed to be contributed by all the selected ODSs during the study period.     

Recent Sea Level and Sea Surface Temperature Changes Along the Maldives Coast

Maldives, a South Asian small island nation in the northern part of the Indian Ocean is extremely vulnerable to the impacts of Sea Level Rise (SLR) due to its low altitude from the mean sea level. This artricle attempts to estimate the recent rates of SLR in Maldives during different seasons of the year with the help of existing tidal data recorded in the Maldives coast. Corresponding Sea Surface Temperature (SST) trends, utilizing reliable satellite climatology, have also been obtained. The relationships between the SST and mean sea level have been comprehensively investigated. Results show that recent sea level trends in the Maldives coast are very high. At Male, the capital of the Republic of Maldives, the rising rates of Mean Tidal Level (MTL) are: 8.5, 7.6, and 5.8 mm/year during the postmonsoon (October-December), Premonsoon (March-May) and southwest monsoon (June-September) seasons respectively. At Gan, a station very close to the equator, the increasing rate of MTL is maximum during the period from June to September (which is 6.2 mm/year). These rising trends in MTL along the Maldives coast are certainly alarming for this small developing island nation, which is hardly one meter above the mean sea level. Thus there is a need for careful monitoring of future sea level changes in the Maldives coast. The trends presented are based on the available time-series of MTL for the Maldives coast, which are rather short. These trends need not necessarily reflect the long-term scenario. SST in the Maldives coast has also registered significant increasing trend during the period from June to September. There are large seasonal variations in the SST trends at Gan but SST and MTL trends at Male are consistently increasing during all the seasons and the rising rates are very high. The interannual mode of variation is prominent both in SST as well as MTL. Annual profile of MTL along the Maldives coast is bimodal, having two maxima during April and July. The April Mode is by far the dominant one. The SST appears to be the main factor governing the sea level variations along the Maldives coast. The influence of SST and sea level is more near the equatorial region (i.e., at Gan). There is lag of about two months for the maximum influence of SST on the sea level. The correlation coefficient between the smoothed SST and mean tidal level at Gan with lag of two months is as high as ~ +0.8, which is highly significant. The corresponding correlation coefficients at Male with the lags of one and two months are +0.5 and +0.3, respectively. Thus, the important finding of the present work for the Maldives coast is the dominance of SST factor in sea level variation, especially near the region close to the equator.     

Image data fusion for the remote sensing of freshwater environments

Remote sensing based mapping of diverse and heterogeneous freshwater environments requires high-resolution images. Data fusion is a useful technique for producing a high-resolution multispectral image from the merging of a high-resolution panchromatic image with a low-resolution multispectral image. Given the increasing availability of images from different satellite sensors that have different spectral and spatial resolutions, data fusion techniques that combine the strengths of different images will be increasingly important to Geography for land-cover mapping. Different data fusion methods however, add spectral and spatial distortions to the resultant data depending on the geographical context; therefore a careful selection of the fusion method is required. This paper compares a technique called subtractive resolution merge, which has not previously been formally tested, with conventional techniques such as Brovey transformation, principal component substitution, local mean and variance matching, and optimised high pass filter addition. Data fusion techniques are grouped into spectral and spatial centric methods. Subtractive resolution merge belongs to a new class of data fusion techniques that uses a mix of both spatial and spectral centric approaches. The different data fusion techniques were applied to a QuickBird image of a semi-aquatic freshwater environment in New Zealand. The results were compared both qualitatively and quantitatively using spectral and spatial error metrics. This research concludes that subtractive resolution merge performed better than all the other techniques and will be a valuable technique for enhancing images for freshwater land-cover mapping.     

Effect of Fe2+ amendment on photodegradation kinetics of imidacloprid in moist soil

The present study deals with the effect of Fe²⁺ on degradation kinetics of imidacloprid in moist soil under UV system. The moist soil samples were spiked with imidacloprid and irradiated in specially designed UV-photoreactor. The analysis of imidacloprid was carried out by using HPLC–DAD system. UV irradiation caused about ten fold increase in photodegradation rate of the pesticide. Amendment of soil with Fe²⁺ at concentrations of 30 mg/kg led to a further increase in the rate of photodegradation, i.e., a 98 % degradation of imidacloprid was observed in the presence of iron after 32 days of irradiation. Moreover, the half-life of imidacloprid in Fe²⁺ -amended soil was observed to be reduced to 7 days that in the absence of Fe²⁺ was recorded to be 21 days. Iron was also observed to affect the half-life of imidacloprid in dark. When compared with unsterilized Fe²⁺-amended batch treatments, the t _1/2 in sterilized Fe²⁺-amended batch treatments increased from 58 to 96 days. Imidacloprid-urea was detected by HPLC as the only stable photodegradation byproduct of imidacloprid in the soil.