A survey of main-belt asteroids. II. Positions and improved orbital elements for 62 unnumbered asteroids

More than 7 000 positions of moving objects were detected on 33 films obtained with the Schmidt telescope at the European Southern Observatory in Chile during August and September 1995. The majority of these asteroids are previously unobserved. This paper presents the results for 62 unnumbered asteroids with provisional designations found in the fields. References to the derived positions for these asteroids are given and improved orbital elements have been calculated using all available positions.     

Analysis of ship life cycles—The impact of economic cycles and ship inspections

Due to the shipping industry's international legal framework, there are loopholes in the system, which can increase the risk of incidents with high economic costs due to the substandard operation of vessels. This article uses duration analysis and through the creation of ship life cycles provides insight into the effectiveness of inspections on prolonging ship lives. The analysis accounts for fluctuations in the relevant economic environment and the (possibly time-varying) ship particulars. It is based on a unique dataset containing information on the timing of accidents, inspections and ship particular changes of more than 50,000 vessels over a 29-year time period (1978–2007). The results reveal that the shipping industry is a relatively safe industry but there is a possible over-inspection of vessels. The effect of inspections varies across ship types and the prevention of incidents with high economic costs can be improved by a coordinated approach of all types of inspections that are performed which allows the decrease of unnecessary inspections. Further, more emphasis should be placed on the rectification and follow-up of deficiencies and the implementation of the ISM code. Another added benefit for the industry would be to improve transparency related to class withdrawals and class transfers for all classification societies. Another interesting finding is that for the majority of ship types, an increase in earnings decreases the incident rate. This is in contrast to the industry perception of the impact of earnings.     

Gas hydrate decomposition recorded by authigenic barite at pockmark sites of the northern Congo Fan

The geochemical cycling of barium was investigated in sediments of pockmarks of the northern Congo Fan, characterized by surface and subsurface gas hydrates, chemosynthetic fauna, and authigenic carbonates. Two gravity cores retrieved from the so-called Hydrate Hole and Worm Hole pockmarks were examined using high-resolution pore-water and solid-phase analyses. The results indicate that, although gas hydrates in the study area are stable with respect to pressure and temperature, they are and have been subject to dissolution due to methane-undersaturated pore waters. The process significantly driving dissolution is the anaerobic oxidation of methane (AOM) above the shallowest hydrate-bearing sediment layer. It is suggested that episodic seep events temporarily increase the upward flux of methane, and induce hydrate formation close to the sediment surface. AOM establishes at a sediment depth where the upward flux of methane from the uppermost hydrate layer counterbalances the downward flux of seawater sulfate. After seepage ceases, AOM continues to consume methane at the sulfate/methane transition (SMT) above the hydrates, thereby driving the progressive dissolution of the hydrates “from above”. As a result the SMT migrates downward, leaving behind enrichments of authigenic barite and carbonates that typically precipitate at this biogeochemical reaction front. Calculation of the time needed to produce the observed solid-phase barium enrichments above the present-day depths of the SMT served to track the net downward migration of the SMT and to estimate the total time of hydrate dissolution in the recovered sediments. Methane fluxes were higher, and the SMT was located closer to the sediment surface in the past at both sites. Active seepage and hydrate formation are inferred to have occurred only a few thousands of years ago at the Hydrate Hole site. By contrast, AOM-driven hydrate dissolution as a consequence of an overall net decrease in upward methane flux seems to have persisted for a considerably longer time at the Worm Hole site, amounting to a few tens of thousands of years.     

Comparison of the antioxidant defense system in Crassostrea rhizophorae and Crassostrea gigas exposed to domestic sewage discharges

Oysters Crassostrea rhizophorae and Crassostrea gigas were kept for fourteen days at four sites in S?o José, SC, Brazil, chosen according to a sewage discharge contamination gradient. Enzymatic activities of CAT, GST, G6PDH and GR were evaluated in gills and digestive glands. Higher CAT activity was observed in tissues of C. rhizophorae in response to sewage contamination possibly indicating peroxisome proliferation induction. C. gigas showed elevated G6PDH activity in digestive gland, and GR in gills, after domestic sewage exposure. In conclusion, C. rhizophorae and C. gigas showed different biochemical responses after in situ exposure to domestic sewage. However, C. rhizophorae showed more significant changes in CAT suggesting that this organism could be a better monitor to this kind of effluent.     

A new simple approach to evaluate pedogenic clay transformation in a Vertic Calcisol

The aim of this study is to characterize the pedogenic clay minerals by using simple approach: mixing mineralogical and geochemical findings.The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC).Qualitative and quantitative mineralogical compositions of the clay mixture were determined.Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes.XRD analysis shows a good homogeneity in the mineralogical composition of the soil material, with depth of soil profiles. The identified clay minerals are mainly illite–smectite mixed layers (I/S) and kaolinite. The chemical analysis of saturated paste extracts with clay minerals shows a slight undersaturation of the illitic phase while smectites and also calcite and gypsum reach the thermodynamic equilibrium along the soil profile.     

Differential biomagnification of PCB, PBDE, Hg and Radiocesium in the food web of the European hake from the NW Mediterranean

Consumption of marine organisms represents one of the main exposure sources of contaminants for human populations. To obtain a global view of the contamination in commercial fish in the NW Mediterranean Sea, we analysed four types of priority contaminants (PCBs, PBDEs, Hg and (137)Cs) in the European hake, Merluccius merluccius, from the Gulf of Lions in relation with organism's trophic level (δ(15)N). All contaminants presented a significant increase in concentration in hake muscle with trophic level. However, obvious differences between contaminants were evidenced. Biomagnification factors (BMF and FWMF) along the hake food web were higher for Hg and CB-153 than for BDE-47 and (137)Cs, and increase in contaminant concentration with trophic level occurred at different rates depending on contaminants. Such differences of biomagnification patterns can be related to physico-chemical properties of the different contaminants.     

Characterization of complex fluvial systems using remote sensing of spatial and temporal water level variations in the Amazon,Congo, and Brahmaputra Rivers

The Surface Water and Ocean Topography (SWOT) satellite mission will provide global, space‐based estimates of water elevation, its temporal change, and its spatial slope in fluvial environments, as well as across lakes, reservoirs, wetlands, and floodplains. This paper illustrates the utility of existing remote sensing measurements of water temporal changes and spatial slope to characterize two complex fluvial environments. First, repeat‐pass interferometric SAR measurements from the Japanese Earth Resources Satellite are used to compare and contrast floodplain processes in the Amazon and Congo River basins. Measurements of temporal water level changes over the two areas reveal clearly different hydraulic processes at work. The Amazon is highly interconnected by floodplain channels, resulting in complex flow patterns. In contrast, the Congo does not show similar floodplain channels and the flow patterns are not well defined and have diffuse boundaries. During inundation, the Amazon floodplain often shows sharp hydraulic changes across floodplain channels. The Congo, however, does not show similar sharp changes during either infilling or evacuation. Second, Shuttle Radar Topography Mission measurements of water elevation are used to derive water slope over the braided Brahmaputra river system. In combination with in situ bathymetry measurements, water elevation and slope allow one to calculate discharge estimates within 2.3% accuracy. These two studies illustrate the utility of satellite‐based measurements of water elevation for characterizing complex fluvial environments, and highlight the potential of SWOT measurements for fluvial hydrology. Copyright © 2010 John Wiley & Sons, Ltd.     

Brominated flame retardants and organochlorine contaminants in winter flounder, harp and hooded seals, and North Atlantic right whales from the Northwest Atlantic Ocean

Various brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) and current-use, non-PBDE BFRs, as well as organochlorine (OC) pesticides and polychlorinated biphenyls (PCBs), were measured in winter flounder, harp and hooded seals, and North Atlantic right whales from the Eastern United States and Canada. The concentrations of PBDEs in winter flounder and right whales were similar in magnitude to the levels of PCBs, which was unlike the pattern observed in seals. In these marine mammals, the levels of PBDEs were orders of magnitude lower than the levels of OCs and PCBs detected. Evidence existed for the accumulation of methoxylated (MeO)-PBDEs of natural origin in seals and right whales. Current-use, non-PBDE BFRs (including hexabromocyclododecane, pentabromoethylbenzene, hexabromobenzene, and pentabromotoluene) were detected in winter flounder and marine mammals. Future research should focus on monitoring PBDEs, current-use, non-PBDE BFRs, and MeO-BDEs of natural origin in marine organisms from Massachusetts and Cape Cod Bays.     

Complex resistivity and radar investigation of building material: First results of field scale measurements

Moisture ingress is one of major damaging factors for masonry buildings. As the complex resistivity (CR) is sensitive to textural properties as well as to the pore fluid chemistry of wet porous media, its non-destructive application can provide helpful information for conservators. In a comprehensive laboratory study it has been shown that CR might even be able to distinguish between salt content and saturation degree in only one measurement. The combined use of electrical and electromagnetic measurement techniques in two field-scale flooding experiments has shown some unexpected differences. Possible reasons are discussed and it is shown that bringing together the information of both methods leads to a clearer picture.     

Evaluating ice‐rafted debris as a proxy for glacier calving in Upernavik Isfjord,NW Greenland

Records of ice‐rafted debris (IRD) in sediments are commonly used as a proxy for iceberg production and to reconstruct past changes of glacier stability. However, the interpretation of IRD is complex as multiple processes modulate its variability. This study investigates the relationship between IRD variability and glaciological change by measuring IRD records from Upernavik Fjord and comparing these to frontal positions of Upernavik Isstrøm during the past century. Results show that the spatial variability of IRD deposition throughout the fjord is high, indicating that randomness inherent to IRD distorts the calving signal. However, we investigate whether IRD records can be combined to improve the reconstruction, as previously suggested, and show the importance of core site selection and number of cores on this approach. The outer‐fjord core compares relatively well to the observed front positions and this is reflected in the composite record: increased IRD deposition in 1937–1946, 1968–1980, and 1996–1999 occurred during periods of faster retreat. Comparison with climatic records shows that the calving episodes in the late ‘30 s/early ‘40 s and late ‘90 s are related to warm ocean and air temperatures, whereas intensified retreat and calving during the ‘70 s reflects partly an internal glacier response to the fjord geometry.