Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Remarks on dynamical ellipticity at the Earth's

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.     

STUDY ON BEIJING''''S EMERGING MOBILE COMMUNICATION INDUSTRIAL CLUSTER AND ITS POLICY IMPLICATIONS

1INTRODUCTIONClusters,definedasgeographicallyproximategroupsofinterconnectedcompaniesandassociatedinstitutionsinparticularfields,linkedbycommonalitiesandcomple-mentarities(PORTER,2000),havearousedanintenseinterestofurbanandregionalplanningresearchersandpolicymakersoverthepastdecades.Itiswidelyrecog-nizedthatclusterscanpromoteproductivityandinno-vation,developlocalcompetitiveadvantages.Popular-izedbyMichaelPORTERinhisbook“TheCompetitiveAdvantageofNationsin1990,theclusterisnotanewcon…     

Study on application of polyenzyme method to offal of Harengula zunasi

The new polyenzyme method for making gravy fromHarengula zunasi offal involves protein enzymolysis with flavorase after proper alkaline and neutral protease levels were established by orthogonal trials to select the best hydrolytic conditions for processing offal with alkaline and neutral protease. The conditions for the polyenzyme method were pH of 7.0, temperature of 50°C, alkaline and neutral protease concentration of 1.5% respectively, hydrolysis time of 120 min, and flavorase concentration of 2.0%, for 60 min. The new gravy-making technology yields a nutritious and delicious gravy containing 40.3% of total essential amino acids, with delicious amino acids Glu, Asp, Gly, Ala, Pro and Ser comprising 49.5%, total and amino nitrogen being respectively 1.9 and 1.1 g/100 g (amino acid nitrogen being 61.0% of total nitrogen), The polyenzyme method was used to make 14.8% protein gravy fromHarengula zunasi offal. In addition, inorganic elements, the phosphorus content is the highest. This project was aided financially by the Guangdong Science and Technology Office (No. 2KM06002S).     

NEMERTEANS OF ZHOUSHAN ISLANDS, EAST CHINA SEA COAST,CHINA Ⅰ.ENOPLA: DISTROMATOPHYNCHOCOELA: MONOSTILIFERA: EMPLECTONEMERTIDAE

Two nemerteans of the Zhoushan Islands, Paranemertes sinensis sp. nov. and P. peregrina, are reportedin this paper. P. sinensis sp. nov. has the body wall longitudinal musculature anteriorly divided,numerous eyes grouped into four clusters, two pairs of cephalic furrows, rhynchocoel 1/3 to 1/2 of fullbody length, cephalic glands well developed and posteriorly extending beyond the cerebral ganglia.precerebral septum absent, cerebral sense organs situated in front of brain, three pairs of nephridiopores,and 17-18 proboscis nerves.     

对松辽盆地钱家店凹陷铀成矿作用的重新认认识

钱家店凹陷中的含矿层位主要为上白垩统姚家组,前人认为其中的红色砂岩为原生成因,但大量的证据证实砂岩原生应以灰色为主,红色砂岩为后生氧化蚀变造成,并控制着钱家店铀矿床铀矿化的产出.在此基础上建立该矿床的后生蚀变分带,依次为红色蚀变带、黄色蚀变带、灰白色蚀变带、过渡带、原生带,红色蚀变带为主要的氧化带,铀矿化主要集中在过渡带.平面上铀矿化主要分布于层间氧化带前锋线附近的位置,并在氧化舌状体的前端和两个氧化舌状体之间存在铀的富集.文章最后还建立了该矿床的成矿模式,并对区域上层间氧化带的展布进行了讨论.     

冀北万全寺银金矿床地质地球化学特征

万全寺银金矿床位于张宣幔枝构造东侧的侏罗纪断陷盆地中,成矿时限晚于133.33Ma～101.82 Ma.通过硫、铅、氢、氧、碳及稀有气体同位素研究认为,成矿物质应源自地球深部,在中生代冀西北幔枝构造演化过程中集中成矿.成矿热液以岩浆水为主并加入了部分天水.     

青藏高原中、东部局地因素对地温的双重影响(Ⅰ): 植被和雪盖

青藏高原冻土区地温既受海拔、纬度和经度(干燥度)区域地带性规律控制, 同时它又受植被、雪盖、砂层、 水被和地质构造等局地因素的显著影响. 局地因素对地温的影响具有双重性: 在不同域值条件下, 它可增高或降低地温. 地温随植被覆盖度减小而逐渐增高, 但覆盖度减到0～20%时, 地温反而降低. 在青藏高原东部、南部和腹部的高山区, 冷季降雪多, 很多地段为稳定积雪区, 雪盖厚, 持续时间长, 对浅层地温起保温作用;而高原腹部的高平原、河谷和盆地冷季降雪较少, 雪盖薄, 持续时间较短, 一般保温作用微弱. 当雪盖厚度超过20 cm以后, 保温作用即开始增强;在暖季因积雪存在时间短, 雪盖薄, 短期内对浅层地温起冷却作用. 总之, 每种局地因素迫使地温向相反方向转化阶段是一个区间值, 为渐变过程. 随时空尺度变化, 局地因素的影响变化很大. 有些地段, 几种局地因素共同作用, 加上活动构造和地形、地貌等的影响, 使地温的时空分布和局地因素对其影响或控制变得错综复杂. 因此, 研究和预测地温特征和变化趋势, 需要在监测植被和积雪作用的基础上进行参数选择、 验证和优化.     

真空堆载联合预压加固软基中孔隙水压力消散规律研究

通过实测资料分析了真空堆载联合预压中不同深度的孔隙水压力、超孔隙水压力、相对超孔隙水压力随时间的变化规律,并对孔压变化的原因进行了微观解释。结果表明:(1)处理区外侧,孔压变化主要由地下水位下降引起,受真空影响较小;(2)在处理区内,孔压变化受真空负压、土体渗透性和堆载荷载的影响。真空作用下的渗流是孔压消散的主要方式,土体渗透性的强弱影响着孔压消散的速度,消散的孔压转化成有效应力,促使土颗粒移动,对孔隙水产生挤压,这使孔压消散呈脉动性特征。