黄河水下三角洲沉积物强度变化原位测试研究

研究区位于1964～1976年黄河由刁口入海时形成的水下三角洲叶瓣上。1995年为石油开采在潮坪上构筑的交通设施对波浪形成良好的屏障。在屏障两侧各选一典型研究区，于1999年和2002年进行了大量对比性现场原位土工测试，探讨了波浪对黄河口沉积物的次生改造作用，结果表明：(1)较强的波浪荷载作用，不会提高海底沉积物的表层强度，只是导致不均匀程度随水动力作用的时间增长有所加大：(2)较强的波浪荷载作用，使得海底表层沉积物之下一定深度范围内土体强度提高，形成强度硬层：(3)海底沉积物强度沿着剖面线在平面上呈现周期性或间隔性变化。     

Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.     

The influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes in pyrolysates of selected terrestrial kerogens

Expulsion of petroleum from source rock is a complex part of the entire migration process. There exist fractional effects on chemical compositions in hydrocarbon expulsion. Does the carbon isotopic fractionation occur during expulsion and to what extent? Here the influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes from pyrolysates of selected terrestrial kerogens from Tuha basin and Fushun, Liaoning Province of China has been experimentally studied. The pyrogeneration-expulsion experiments were carried out under semi-closed system. The carbon isotopic compositions of individual n-alkanes were measured by GC-IRMS. The main conclusions are as follows. First, there is carbon isotopic fractionation associated with hydrocarbon expulsion from Type III kerogens in Tuha Basin. There exist differences of carbon isotopic compositions between the unexpelled n-alkanes and expelled n-alkanes from Tuha desmocollinite and Tuha mudstone. Second, there is almost no carbon isotopic fractionation associated with hydrocarbon expulsion from Type II kerogens in Fushun and Liaohe Basin. Third, carbon isotopic fractionation in hydrocarbon expulsion should be considered in making oil-source correlation of Type III kerogens at least in the Tuha Basin. Further studies need to be carried out to determine whether this is true in other basins. Fourth, oil and source at different maturity levels cannot be correlated directly for Type III kerogens since the carbon isotopic compositions of expelled hydrocarbons at different temperatures are different. The expelled hydrocarbons are usually lighter (depleted in ¹³C) than the hydrocarbons remaining in the source rock at the same maturity.     

基于面向对象的空间目标3维交互式建模的设计

3维数据模型的建立是实现真3维GIS的一个核心问题。在充分分析现有3维数据模型的基础上，比较了传统模型的优缺点。针对空间目标建模的特点，设计了一种面向对象的3维数据模型。考虑到软件的实用性和可扩展性，着重论述了3维交互式设计及数据管理。     

辽宁省鞍本地区铁尾矿资源现状及其开发利用

辽宁省的鞍山、本溪两市为我国重要的钢铁基地，各矿山长期生产遗留的铁尾矿问题越来越引起人们的重视，如污染环境、诱发地质灾害等，如何解决已成为地质、环保、水工界的关注。     

近年我国十大重要金属矿种找矿重大进展与成果

近年我国重要矿产资源勘查成果不断快速涌现。为服务矿产勘查进展长期动态跟踪与成果集成研究,2010~2014年,笔者依托原中国地质调查局发展研究中心承担的《重点成矿区带矿产勘查跟踪与成果集成》、《全国地质勘查进展分析》等项目,以铁、铜、铝、铅锌、金、钨、锡、钼、镍、锰等十大重要金属矿产勘查进展为主要研究对象,研究分析了勘查成果特征。     

Petrogenesis of Two Types of Archean TTGs in the North China Craton: A Case Study of Intercalated TTGs in Lushan and Non-intercalated TTGs in Hengshan

TTG(Tonalite-Trondhjemite-Granodiorite) gneisses,a major component of Precambrian continental crust,play a significant role in understanding the process and mechanism of the crustal evolution in the early periods of the Earth. In terms of field occurrence,there are two kinds of Archean TTGs in the NCC(North China Craton): intercalated and non-intercalated TTGs. In this contribution,we make a comprehensive comparison of these two types of TTGs from the typical areas(Lushan and Hengshan) in the NCC with an aim to constrain their petrogenesis. The results suggest that they have similar mineral assemblages of Pl + Qtz + Bt ± Amp ± Kfs but different field appearances and geochemical compositions,thus probably reflecting different source materials and tectonic settings. Differences in the contents of characteristic elements,such as Sr,REE and HFSE,suggest that the nonintercalated TTGs in Hengshan were generated at deeper levels than those of intercalated TTGs in Lushan. Constraints from element contents and geochemical modeling results are consistent with derivation from dual sources involving both garnet amphibolite and rutile-bearing eclogite residues for the non-intercalated TTGs in Hengshan,whereas the compositions of intercalated TTGs in Lushan indicate that they were formed by partial melting with amphibolite to garnet-amphibolite residues. Moreover,accumulation of plagioclase is also required in the petrogenesis of intercalated TTGs in Lushan,at least for part of them. In addition,the non-intercalated TTGs in Hengshan display distinctly higher Mg O,Mg#,Cr and Ni values and lower SiO_2 average contents compared to the intercalated TTGs in Lushan. These features suggest that the former magma,at least a part,might have interacted with the mantle wedge during ascent. Considering all the above factors and in combination with the whole-rock Nd and zircon Hf isotopic data,it is suggested that the non-intercalated TTGs in Hengshan were produced by partial melting of subducted slab contaminated by the overlying mantle wedge at deeper levels and high pressures,whereas the intercalated TTGs in Lushan were generated by melting of the thickened lower crust at lower pressures and shallower depths. The tectonic settings of the two types of TTGs shed new light on the growth of the NCC.     

Study on biogenic amines in various dry salted fish consumed in China

This study was carried out to investigate the biogenic amines（BAs）, physicochemical property and microorganisms in dry salted fish, a traditional aquatic food consumed in China. Forty three samples of dry salted fish were gathered from retail and wholesale markets and manufacturers, which had been produced in various regions in China. Cadaverine（CAD） and putrescine（PUT） were quantitatively the most common biogenic amines. About 14% of the samples exceeded the histamine content standards established by the FDA and/or EU. The highest histamine content was found in Silver pomfret（Pampus argenteus）(347.79 mg kg^-1). Five of forty three samples exceeded the acceptable content of TYR(100 mg kg^-1), and 23.26% of dried-salted fish contained high contents of biogenic amines(above 600 mg kg^-1). In addition, species, regions, pickling processes and drying methods made the physicochemical property, microorganisms and biogenic amines in dry salted fish to be different to some extents. The total plate count（TPC） was much higher than that of total halophilic bacteria in all samples. The biogenic amines, physicochemical property and microbiological counts exhibited large variations among samples. Furthermore, no significant correlation between biogenic amines and physicochemical property and TPC was observed. This study indicated that dry salted fish may still present healthy risk for BAs, depending on the processing methods, storage conditions among others.     

Data integration in characterizing a fracture-cavity reservoir,Tahe oilfield,Tarim basin,China

Fracture-cavity reservoirs can be described in terms of storage space, filling materials and distribution, however, characterizing these variables remains a challenge. In this study, a method was developed to characterize complex reservoirs by integrating outcrop, core, well log, and seismic data from the Tahe oilfield. Outcrop analogs were used to identify and qualitatively analyze the genesis of different reservoir spaces. Cores, well logs, and seismic data were used to identify different types of reservoir space in the subsurface, to describe the spatial distribution, and to establish the distribution pattern of fracture-cavity reservoirs. Clastic sediments, collapse breccia, and chemical fillings were described from the cores and used to assess porosity and permeability. On the basis of the results, a three-dimensional geological model was constructed incorporating a structural model, a reservoir space model, and a property model. Caves and fractures were the main storage spaces and seepage passages. The cave model was built using multi-point geostatistical simulation, while the fracture model was established using deterministic modeling combined with manual interpretations and ant-tracking technology.