Byproduct Formation During the Reduction of TCE by Zero-Valence Iron and Palladized Iron

Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gas chromatography and a flame ionization detector. When a 5 ppm initial concentration of TCF. reacts with zero-valence iron, approximately 140 ppb of vinyl chloride persists for as long as 73 days. The concentration of vinyl chloride (approximately If) ppb) remaining with palladized iron is approximately an order of magnitude less than when zero-valence iron is the reductant. These data suggest that volatile byproducts may be under-represented in oilier published data regarding reduction with zero-valence metals. These results also demonstrate that the reduction of TCE with palladized iron (0.05 percent palladium) is more than an order of magnitude faster than with zero-valence iron. Wilh a 5:1 solution-to-solid ratio the TCE half-life with zero-valence iron is 7.41 hours. but is only 0.59 hours with the palladized iron.     

网络环境下地震科技信息工作的思考

进入21世纪以来,信息技术得到飞速发展,使得信息获取途径日益呈现出多元化特性,强烈地冲击了传统的地震科技信息工作依赖馆藏文献提供为主的信息管理和服务模式.同时也更凸显了地震科技信息工作在信息开发利用与服务上的种种缺陷.变革中的社会信息环境,迫使我们重新审视和思考网络环境下地震科技信息管理与服务等诸多问题,加强地震科技信息工作创新的研究与思考.     

联合办刊是科技期刊走出困境的重要途径--以《灾害学》杂志为例

以《灾害学》杂志为例，论述了联合办刊的问题。实践证明，联合办刊是解决科技期刊办刊经费不足、发行量有限、稿源短缺等问题并使其走出困境、寻求发展的重要途径。     

未定名矿物(Bi38CrO60)的矿物学研究

人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致.     

21世纪中国地质灾害防治形势与减灾战略思考

文章论述了21世纪中国地质灾害减灾面临的形势是既存在许多有利条件又存在多方面困难而面临严重挑战。提出21世纪地质灾害减灾战略：1．建立地质灾害防治安全维护体系；2．优先安排西部地区地质灾害防治工程，实施地质灾害风险管理；3．建立矿山地质灾害防治监督管理体系；4．城市地质灾害防治与土地利用相结合；5．加强我国地质环境监测与网站建设；6．针对地质灾害区域分布规律，采取分区减灾对策；7．加大地质灾害防治投入力度。     

An experimental study on seismic responses of multifunctional vibration‐absorption reinforced concrete megaframe structures

Two models are tested on a shake‐table. One of the models is a normal reinforced concrete megaframe structure and the other is a multifunctional vibration‐absorption reinforced concrete megaframe structure in which the laminated rubber bearings are placed between the major frame and the minor frames. Two earthquake motions (the El Centro wave and the Taft wave) are used during the test. This paper presents the dynamic characteristic, the seismic responses and the failure mechanism of these two models under varying peak acceleration levels for each of the earthquake motions. The test results demonstrate that the aseismic behavior of a multifunctional vibration‐absorption reinforced concrete megaframe structure is much better than that of a normal reinforced concrete megaframe structure. Copyright © 2003 John Wiley & Sons, Ltd.     

Seismic structural control using an electric servomotor active mass driver system

This study investigates an electric‐type active mass driver (AMD) system for structural vibration control. Composed primarily of an electric servomotor and a ball screw, the electrical AMD system is free from noise problems, oil leakage, and labor‐intensive maintenance that commonly are associated with hydraulic AMD systems. The desired stroke amplification of the mass and the power demand of the servomotor can be adjusted via the ball screw pitch, which in turn affects the effectiveness and efficiency of the system. Meanwhile, an instantaneous optimal direct output feedback control algorithm is adopted. Numerical simulation is performed using a five‐story steel frame as the object structure under the conditions of the 1940 El Centro earthquake. The AMD system proves to be effective and efficient within a certain range of the ball screw pitch. The reductions of the peak responses can reach as high as 70% if properly designed. Requiring only the velocity measurement of the top floor for on‐line feedback control, the proposed control algorithm is recommended for practical implementation. Copyright © 2004 John Wiley & Sons, Ltd.     

贵东岩体地质地球化学特征及其形成的构造环境识别

本文在研究贵东花岗岩岩体岩石矿物组合、结构构造等地质特征的基础上 ,运用花岗岩的岩石化学、微量元素和同位素等分析数据 ,采用目前广泛应用的几种岩石化学图解、微量元素和同位素图解等方法 ,判别了贵东岩体形成的构造环境为造山带后碰撞型     

黄河水下三角洲沉积物强度变化原位测试研究

研究区位于1964～1976年黄河由刁口入海时形成的水下三角洲叶瓣上。1995年为石油开采在潮坪上构筑的交通设施对波浪形成良好的屏障。在屏障两侧各选一典型研究区，于1999年和2002年进行了大量对比性现场原位土工测试，探讨了波浪对黄河口沉积物的次生改造作用，结果表明：(1)较强的波浪荷载作用，不会提高海底沉积物的表层强度，只是导致不均匀程度随水动力作用的时间增长有所加大：(2)较强的波浪荷载作用，使得海底表层沉积物之下一定深度范围内土体强度提高，形成强度硬层：(3)海底沉积物强度沿着剖面线在平面上呈现周期性或间隔性变化。     

许昌麦岭水源地可开采量的水均衡法计算

根据许昌麦岭镇多年地下水动态观测资料,利用水均衡法原理,对水源地边界地质条件、补给与排泄的关系进行研究,对地下水允许开采量进行综合评价,提出水源地水量开采的建议。