Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

A deep-sea in-situ suspended sediment sampling system: Comment

A recent article by Beer et al. (1974) in Marine Geology describes an in-situ suspended sediment sampling system which utilizes a pump/motor unit, filter holders, and a lead-acid battery power source. Two aspects of their article may be misleading: the use of certain filter material as X-ray diffraction mounts, and the technique by which an oil-filled battery case may be operated.     

Snow measurement techniques for land-surface-atmosphere exchange studies in boreal landscapes

Summary  Snow has been studied widely in hydrology for many decades whereas recent meteorological interest in snow is caused by increased emphasis on high latitudes and wintertime in climate-change research as well as by the need to improve weather-forecast models during these conditions. Ground-based measurements of snow properties are needed both to improve understanding of surface-atmosphere exchange processes and to provide ground truth to new remote-sensing algorithms. This justifies a review of techniques to measure snow in combination with establishment of criteria for the suitability of the methods for process studies. This review assesses the state-of-art in ground-based snow-measurement techniques in the end of the 1990s in view of their accuracy, time resolution, possibility to automate, practicality and suitability in different terrain. Methods for snow-pack water equivalent, depth, density, growth, quality, liquid-water content and water leaving the snow pack are reviewed. Synoptic snow measurements in Fennoscandian countries are widely varying and there is no single standard on which process-related studies can build. A long-term, continuous monitoring of mass and energy properties of a snow cover requires a combination of point-measurement techniques. Areally representative values of snow properties can be achieved through a combination of automatically collected point data with repeated manual, areally covering measurements, remote-sensing data and digital elevation models, preferably in a GIS framework. Received August 27, 1999     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

A case study of warm air advection over a melting snow surface

When relatively warm, moist air moves over a snow surface, sensible heat and moisture are extracted from its lower layers and used to melt the snow. The depth of the cooled layer depends on horizontal wind speeds and the presence of high vertical wind shear. The mechanism for air mass modification appears to be turbulent mixing.