A model for adjustment of differential gravity measurements with simultaneous gravimeter calibration

 A mathematical model is proposed for adjustment of differential or relative gravity measurements, involving simultaneously instrumental readings, coefficients of the calibration function, and gravity values of selected base stations. Tests were performed with LaCoste and Romberg model G gravimeter measurements for a set of base stations located along a north–south line with 1750 mGal gravity range. This line was linked to nine control stations, where absolute gravity values had been determined by the free-fall method, with an accuracy better than 10 μGal. The model shows good consistence and stability. Results show the possibility of improving the calibration functions of gravimeters, as well as a better estimation of the gravity values, due to the flexibility admitted to the values of the calibration coefficients. Received: 15 November 1999 / Accepted: 31 October 2000     

Local geoid determination combining gravity disturbances and GPS/levelling: a case study in the Lake Nasser area, Aswan, Egypt

 The use of GPS for height control in an area with existing levelling data requires the determination of a local geoid and the bias between the local levelling datum and the one implicitly defined when computing the local geoid. If only scarse gravity data are available, the heights of new data may be collected rapidly by determining the ellipsoidal height by GPS and not using orthometric heights. Hence the geoid determination has to be based on gravity disturbances contingently combined with gravity anomalies. Furthermore, existing GPS/levelling data may also be used in the geoid determination if a suitable general gravity field modelling method (such as least-squares collocation, LSC) is applied. A comparison has been made in the Aswan Dam area between geoids determined using fast Fourier transform (FFT) with gravity disturbances exclusively and LSC using only the gravity disturbances and the disturbances combined with GPS/levelling data. The EGM96 spherical harmonic model was in all cases used in a remove–restore mode. A total of 198 gravity disturbances spaced approximately 3 km apart were used, as well as 35 GPS/levelling points in the vicinity and on the Aswan Dam. No data on the Nasser Lake were available. This gave difficulties when using FFT, which requires the use of gridded data. When using exclusively the gravity disturbances, the agreement between the GPS/levelling data were 0.71 ± 0.17 m for FFT and 0.63 ± 0.15 for LSC. When combining gravity disturbances and GPS/levelling, the LSC error estimate was ±0.10 m. In the latter case two bias parameters had to be introduced to account for a possible levelling datum difference between the levelling on the dam and that on the adjacent roads. Received: 14 August 2000 / Accepted: 28 February 2001     

New analytical and numerical approaches for geopotential modeling

 The standard analytical approach which is applied for constructing geopotential models OSU86 and earlier ones, is based on reducing the boundary value equation to a sphere enveloping the Earth and then solving it directly with respect to the potential coefficients _n,m . In an alternative procedure, developed by Jekeli and used for constructing the models OSU91 and EGM96, at first an ellipsoidal harmonic series is developed for the geopotential and then its coefficients _n,m ^e are transformed to the unknown _n,m . The second solution is more exact, but much more complicated. The standard procedure is modified and a new simple integral formula is derived for evaluating the potential coefficients. The efficiency of the standard and new procedures is studied numerically. In these solutions the same input data are used as for constructing high-degree parts of the EGM96 models. From two sets of _n,m (n≤360,|m|≤n), derived by the standard and new approaches, different spectral characteristics of the gravity anomaly and the geoid undulation are estimated and then compared with similar characteristics evaluated by Jekeli's approach (`etalon' solution). The new solution appears to be very close to Jekeli's, as opposed to the standard solution. The discrepancies between all the characteristics of the new and `etalon' solutions are smaller than the corresponding discrepancies between two versions of the final geopotential model EGM96, one of them (HDM190) constructed by the block-diagonal least squares (LS) adjustment and the other one (V068) by using Jekeli's approach. On the basis of the derived analytical solution a new simple mathematical model is developed to apply the LS technique for evaluating geopotential coefficients. Received: 12 December 2000 / Accepted: 21 June 2001     

Degradation of native wheat straw lignin by Streptomyces viridosporus T7A

Lignin is one of the major contributing factors toward the recalcitrance of lignocellulosic biomass. Understanding the process of lignin degradation in natural biological processes will provide useful information to develop novel biomass conversion technologies. Functional group changes in the lignin entities during the process may contribute to the cellulose degradation (utilization) by the microorganisms. In this study, compositional and advanced Fourier transform infrared, pyrolysis gas chromatography/mass spectrometry and ¹³C cross polarization/magic angle spinning nuclear magnetic resonance analysis were performed to explore the mechanism of biodegradation of wheat straw by Streptomyces viridosporus T7A. The results indicated that S. viridosporus T7A removed lignin and hemicelluloses as indicated by the increased carbohydrate/lignin ratio. Significant modification of carbonyl and methoxyl groups in the complex lignin structure was also evident. Most importantly, the quantitative results showed that lignin degradation was featured by deduction of guaiacyl unit. The results provide new insight for understanding lignin degradation by bacteria.     

Past,present and future vegetation-cloud feedbacks in the Amazon Basin

To begin exploring the underlying mechanisms that couple vegetation to cloud formation processes, we derive the lifting condensation level (LCL) to estimate cumulus cloud base height. Using a fully coupled land–ocean–atmosphere general circulation model (HadCM3LC), we investigate Amazonian forest feedbacks on cloud formation over three geological periods; modern-day (a.d. 1970–1990), the last glacial maximum (LGM; 21 kya), and under a future climate scenario (IS92a; a.d. 2070–2090). Results indicate that for both past and future climate scenarios, LCL is higher relative to modern-day. Statistical analyses indicate that the 800 m increase in LCL during the LGM is related primarily to the drier atmosphere promoted by lower tropical sea surface temperatures. In contrast, the predicted 1,000 m increase in LCL in the future scenario is the result of a large increase in surface temperature and reduced vegetation cover.     

Urban seismic stations: soil–structure interaction assessment by spectral ratio analyses

In this work we present and discuss the results of ambient seismic noise analyses computed at four sites where seismic stations, managed by the INGV (Italian Institute for Geophysics and Vulcanology) and the DPC (Italian Department of Civil Protection), are installed inside buildings. The experiments were performed considering different types of installation: sensor located at the bottom of a school, directly installed on rock (case 1); sensor located at the bottom of a medieval fortress, built on an isolate hill, directly installed on rock (case 2); sensor installed on the foundations of a medieval fortress, built on an isolate hill (case 3); sensor installed on the foundations of a school, built on alluvial deposits (case 4). Since recent works proposed the use of spectral ratio techniques to study the dynamic characterization of buildings, ambient seismic-noise measurements were performed for each site close to the stations (at the base of the structures), at the top of the structures and outside the buildings. In order to check the source of vibrations both horizontal to vertical spectral ratio (HVNR) and standard spectral ratio (SSR) techniques were applied. For all stations the results from ambient seismic noise were compared to those obtained from earthquakes (HVSR). In order to detect preferential directions of amplification, for each site average HVNRs and HVSRs were computed considering one azimuth for each set of 5°. We obtain different results for different types of installation: in cases 1 and 2, where the sensors are directly installed on rock, the vibrations of the structure do not affect the noise measures performed close to the stations, which show flat HVNR in the whole frequency range: in both cases the eigenfrequency of the building is given by the HVNR calculated from the measures performed at the top of the structure. In cases 3 and 4, where the sensors are installed on the foundations of the considered structures, both the amplification peaks between 5 and 9 Hz (case 3) and between 5.5 and 7 Hz (case 4) include the contribution of the free oscillations of the buildings. In particular, in case 4, HVNRs performed outside building highlight possible soil–structure resonance effects in case of an earthquake.     

Study of a high SO2 event observed over an urban site in western India

Continuous measurements of SO₂, NO_x and O₃ along with sampling based measurements of CO, CH₄, NMHCs and CO₂ were carried out during May, 2010 at Ahmedabad. The diurnal variations of SO₂ in ambient air exhibited elevated values during the night and lower levels during the sunlit hours. The mean concentration of SO₂ during the study period was 0.95 ± 0.88 ppbv. However, the ambient SO₂ exceeded 17 ppbv in the night of 20 May, 2010. On the same day, tropospheric columnar SO₂ from OMI showed almost 350% increase corroborating the surface observations over an extended height regime. This was also the highest columnar value of SO₂ during the summer of 2010. Columnar loadings were also found to be high for formaldehyde, precipitable water vapor and aerosol optical depth on 20 May. Elevated concentrations were also recorded for other trace gases like NO₂ and O₃. Analysis of related data of trace gases indicated characteristics of fresh emissions with dominant contributions from mobile sources during the study period. However, SO₂/NO₂ ratio of 0.36 during the event period on 20th May connotes non-local influences. Analyses of meteorological parameters suggest combined impacts of transport and inversion causing higher levels of SO₂ and other pollutants during 20?C21 May. Episodes of such enhancements may perturb chemical and radiative balance of the atmosphere.     

Acid mine drainage at Cerro Rico de Potosí I: unabated high-strength discharges reflect a five century legacy of mining

Intensive mining and processing of Ag, Sn, Pb and Zn ores have occurred in various locations within and around the city of Potosí, Bolivia since 1545. Surface and subsurface waters, stream sediments and soils are contaminated with various ecotoxic metals in the headwaters of the economically vital, yet highly impacted, upper Rio Pilcomayo watershed. Previous studies have documented downstream trace metal contamination, however, not addressed specific sources. The AMD discharges identified in this study help link downstream pollution to primary origins. The majority of AMD would be considered high-strength due to metal concentrations and acidity orders of magnitude greater than typical AMD. Discharges from both operating and abandoned portals as well as tailings-related deposits displayed a high degree of heterogeneity with total metal concentrations ranging from 0.11 to 7480, <0.022 to 889, <0.0006 to 65.3, <0.001 to 310, 0.12 to 72,100, 0.3 to 402, <0.012 to 34.8, and 0.24 to 19,600 mg/L of Al, As, Cd, Cu, Fe, Mn, Pb and Zn, respectively. Net acidity and pH ranged from −10 to 246,000 mg/L as CaCO₃ equivalent and 0.90–6.94 standard units, respectively. Data were gathered during two sampling events centered around the most extreme periods of the dry and wet seasons of one water-year. Loadings to local streams were marginally greater for most metals in the wet season. If observed loadings are historically representative, Cerro Rico AMD has contributed thousands of tonnes of ecotoxic metals to the upper Rio Pilcomayo over the last five centuries. Metal and hydrogen ion concentrations in the majority of AMD sampled were several orders of magnitude above discharge limits set by the Bolivian government, yet no action has historically or contemporarily been taken.