华北东部地幔改造作用和置换作用:单斜辉石激光探针研究

对山东蒙阴古生代金伯利岩中石榴石方辉橄榄岩、河南鹤壁新生代玄武岩中 铬尖晶石方辉橄榄岩、山东栖霞新生代玄武岩中央晶石二辉橄榄岩和山东山旺新生代 玄武岩中尖晶石（富ＣｐＸ）二辉橄榄岩单斜辉石的常量、微量元素的研究和对比表明：华 北地块古生代稳定存在的克拉通岩石圈地幔在中、新生代其东部被具大洋地幔性质的 显生宙地幔不均匀地发生了置换作用,残存于南北重力梯度带（岩石圈减薄过渡带）上 的鹤壁浅部克拉通地幔除保存有置换作用前改造作用的丰富信息外,也包含有其深部 被置换后的地幔改造作用信息;郯庐断裂带东部栖霞的新生地幔仍保留有较多的大洋 地幔成分特征,而郯庐断裂带内山旺的新生地幔受后续地幔改造作用的影响有向大陆 地幔演化的趋向．发生于华北地块东部中、新生代的岩石圈巨厚减薄作用与地幔的置换 作用有关,由渐进的富ＣＯ_２流体或碳酸岩熔体对岩石圈地幔的交代改造作用以及由此 所引起的熔体抽取作用是完成新生地幔对古老地幔置换作用的关键．郯庐断裂带等岩 石圈深大断裂为地幔改造作用和地幔置换作用提供了良好的通道作用．     

Past,present and future vegetation-cloud feedbacks in the Amazon Basin

To begin exploring the underlying mechanisms that couple vegetation to cloud formation processes, we derive the lifting condensation level (LCL) to estimate cumulus cloud base height. Using a fully coupled land–ocean–atmosphere general circulation model (HadCM3LC), we investigate Amazonian forest feedbacks on cloud formation over three geological periods; modern-day (a.d. 1970–1990), the last glacial maximum (LGM; 21 kya), and under a future climate scenario (IS92a; a.d. 2070–2090). Results indicate that for both past and future climate scenarios, LCL is higher relative to modern-day. Statistical analyses indicate that the 800 m increase in LCL during the LGM is related primarily to the drier atmosphere promoted by lower tropical sea surface temperatures. In contrast, the predicted 1,000 m increase in LCL in the future scenario is the result of a large increase in surface temperature and reduced vegetation cover.     

Degradation of native wheat straw lignin by Streptomyces viridosporus T7A

Lignin is one of the major contributing factors toward the recalcitrance of lignocellulosic biomass. Understanding the process of lignin degradation in natural biological processes will provide useful information to develop novel biomass conversion technologies. Functional group changes in the lignin entities during the process may contribute to the cellulose degradation (utilization) by the microorganisms. In this study, compositional and advanced Fourier transform infrared, pyrolysis gas chromatography/mass spectrometry and ¹³C cross polarization/magic angle spinning nuclear magnetic resonance analysis were performed to explore the mechanism of biodegradation of wheat straw by Streptomyces viridosporus T7A. The results indicated that S. viridosporus T7A removed lignin and hemicelluloses as indicated by the increased carbohydrate/lignin ratio. Significant modification of carbonyl and methoxyl groups in the complex lignin structure was also evident. Most importantly, the quantitative results showed that lignin degradation was featured by deduction of guaiacyl unit. The results provide new insight for understanding lignin degradation by bacteria.     

Urban seismic stations: soil–structure interaction assessment by spectral ratio analyses

In this work we present and discuss the results of ambient seismic noise analyses computed at four sites where seismic stations, managed by the INGV (Italian Institute for Geophysics and Vulcanology) and the DPC (Italian Department of Civil Protection), are installed inside buildings. The experiments were performed considering different types of installation: sensor located at the bottom of a school, directly installed on rock (case 1); sensor located at the bottom of a medieval fortress, built on an isolate hill, directly installed on rock (case 2); sensor installed on the foundations of a medieval fortress, built on an isolate hill (case 3); sensor installed on the foundations of a school, built on alluvial deposits (case 4). Since recent works proposed the use of spectral ratio techniques to study the dynamic characterization of buildings, ambient seismic-noise measurements were performed for each site close to the stations (at the base of the structures), at the top of the structures and outside the buildings. In order to check the source of vibrations both horizontal to vertical spectral ratio (HVNR) and standard spectral ratio (SSR) techniques were applied. For all stations the results from ambient seismic noise were compared to those obtained from earthquakes (HVSR). In order to detect preferential directions of amplification, for each site average HVNRs and HVSRs were computed considering one azimuth for each set of 5°. We obtain different results for different types of installation: in cases 1 and 2, where the sensors are directly installed on rock, the vibrations of the structure do not affect the noise measures performed close to the stations, which show flat HVNR in the whole frequency range: in both cases the eigenfrequency of the building is given by the HVNR calculated from the measures performed at the top of the structure. In cases 3 and 4, where the sensors are installed on the foundations of the considered structures, both the amplification peaks between 5 and 9 Hz (case 3) and between 5.5 and 7 Hz (case 4) include the contribution of the free oscillations of the buildings. In particular, in case 4, HVNRs performed outside building highlight possible soil–structure resonance effects in case of an earthquake.     

Acid mine drainage at Cerro Rico de Potosí I: unabated high-strength discharges reflect a five century legacy of mining

Intensive mining and processing of Ag, Sn, Pb and Zn ores have occurred in various locations within and around the city of Potosí, Bolivia since 1545. Surface and subsurface waters, stream sediments and soils are contaminated with various ecotoxic metals in the headwaters of the economically vital, yet highly impacted, upper Rio Pilcomayo watershed. Previous studies have documented downstream trace metal contamination, however, not addressed specific sources. The AMD discharges identified in this study help link downstream pollution to primary origins. The majority of AMD would be considered high-strength due to metal concentrations and acidity orders of magnitude greater than typical AMD. Discharges from both operating and abandoned portals as well as tailings-related deposits displayed a high degree of heterogeneity with total metal concentrations ranging from 0.11 to 7480, <0.022 to 889, <0.0006 to 65.3, <0.001 to 310, 0.12 to 72,100, 0.3 to 402, <0.012 to 34.8, and 0.24 to 19,600 mg/L of Al, As, Cd, Cu, Fe, Mn, Pb and Zn, respectively. Net acidity and pH ranged from −10 to 246,000 mg/L as CaCO₃ equivalent and 0.90–6.94 standard units, respectively. Data were gathered during two sampling events centered around the most extreme periods of the dry and wet seasons of one water-year. Loadings to local streams were marginally greater for most metals in the wet season. If observed loadings are historically representative, Cerro Rico AMD has contributed thousands of tonnes of ecotoxic metals to the upper Rio Pilcomayo over the last five centuries. Metal and hydrogen ion concentrations in the majority of AMD sampled were several orders of magnitude above discharge limits set by the Bolivian government, yet no action has historically or contemporarily been taken.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.     

Distribution of Indus born mica along Gulf of Kachchh coast: Implications in understanding current dynamics

Indus is one of the major sources of sediments to the Gulf of Kachchh. Yet only its <63 micron fraction is studied in detail with regards to the offshore current dynamics. Hence here we present our study on characteristic signature of the Indus sediment load (i.e. mica minerals) in >63 micron size fraction along the coast of Gulf of Kachchh. The spatial distribution of mica minerals along the Gulf of Kachchh coast was studied which showed in general decreasing trend as we move along the northern and southern coast of the Gulf of Kachchh but, an increase in amount near the southern mouth at Okha. The study shows that the earlier proposed tidal barrier is ineffective in restricting movement of mica across the mouth of the gulf due to its characteristic transport mechanism. Also the presence of mudflats along the gulf of Kachchh coast plays a vital role as sediment receptors in the active sediment transport processes and mica minerals prove to be a promising simple tracer in studying the Indus born sediments in the region.     

Equatorial Indian Ocean evaporation estimates from operational meteorological satellites and some inferences in the context of monsoon onset and activity

The estimation of evaporation from the sea surface is not yet achieved adequately by remote sensing techniques, in general. However, for approximate averaged estimates over moderate space and time scales over a specific tropical region, e.g., weekly values over the Indian Ocean as needed in monsoon moisture diagnosis, it may be possible to extrapolate satellite wind and humidity data to the ocean surface and then use bulk aerodynamic parameterization for estimating evaporation. In the present investigation, GOES low-level cloud winds and TIROS-N moisture profiles over the Indian Ocean are extrapolated to the ocean surface. The planetary boundary layer (PBL) wind shear is obtained over different sub-regions and periods during the monsoon season, by reference to objectively analysed fields. These shear values are applied to GOES satellite winds to obtain sea-surface winds. The humidity extrapolation was based on (i) an exponential fit for water vapour density and (ii) a vertical distribution of relative humidity approximately proportional to atmospheric pressure. The exchange coefficient is varied slightly depending on wind speed and boundary-layer stability inferred approximately from TIROS-N sea surface temperatures and temperature profiles. The evaporation estimate as based on these satellite parameters is assessed by comparison with ships' surface observations. Sensible heat exchange is also estimated and assessed. Some inferences based on these estimates are also presented, in relation to monsoon onset and activity.