A study on the preparation of fine and low soda alumina

A simple process to produce fine and low soda α-alumina (α-Al₂O₃) from a commercial grade aluminium trihydroxide (gibbsite, Al(OH)₃) produced by KC Corporation Ltd was developed. There are two options for this process with the first one producing low soda α-alumina (< 0.05% Na₂O) having a mean particle size of 50 μm. The second option yields a fine product with a mean size of less than 10 μm. In the first option, a plant aluminium trihydroxide containing 0.20% Na₂O was first fluidized with nitrogen at 400–600 °C to yield an amorphous activated alumina. This intermediate product was then treated with acetic or oxalic acid, washed with water and heated to 1200 °C to form calcined α-alumina, having a Na₂O content of less than 0.05%. A 20 min leaching using 0.2 M acetic or oxalic acid could yield an alumina product containing 0.04% Na₂O. In the second option, a new technique for the preparation of fine and low soda α-alumina was evaluated using an attrition mill working also as a leaching vessel at 80 °C. Fine (< 10 μm in mean particle size) and low soda (< 0.04% Na₂O) alumina was produced by a 20 min leaching step with 0.2 M acetic acid and concurrent attrition milling.     

Microbial effects on geochemical behavior of arsenic in As-contaminated sediments

The purpose of this study is to investigate the contamination level and chemical speciation of As in sediments from the Hwachon Au mine area, and to study the effects of indigenous bacteria on geochemical behavior of As in As-contaminated sediments from the mine. Concentrations of heavy metal and metalloids in one composite sample of 9 Hwachon sediments were 24.9 As mg/kg, 16.6 Cd mg/kg, 230 Pb mg/kg and 1080 Zn mg/kg. This indicates that this area was seriously contaminated with As, Cd and Zn. From the result of sequential extraction analysis, most of As (87.9%) existed as a phase of As which coprecipitated with Fe oxyhydroxides. Under aerobic condition, As concentration leached from sediments were 4 times higher in non-sterile than in sterile condition. This enrichment of As leaching could be caused by increase of pH and exudation secreted during microbial metabolism. On the other hand, under anaerobic condition, As concentration has dramatically increased in non-sterile solution with time. This As leaching has begun on 4–5th days of incubation and the highest concentration of 511 As μg/l was recorded on about 11th day. Arsenic leaching under anaerobic condition was caused by microbial enhancement of Fe leaching. Total Fe concentration increased from the 4th day, and this Fe leaching might cause lixiviation of As which had been coprecipitated with Fe oxyhydroxide.     

Comparison of satellite measurements of the low-latitude nighttime upper ionosphere with IRI

In this paper, we report the results of our comparison study between satellite measurements and the International Reference Ionosphere (IRI) model on the seasonal and longitudinal changes of the low-latitude nighttime topside ionosphere during the period of solar maximum from June 2000 to July 2001. Satellite measurements were made by KOMPSAT-1 and DMSP F15 at 685 km altitude and 840 km altitude, respectively. The results show that the IRI2001 model gives reasonable density estimations for the summer hemisphere and the March equinox at both altitudes. However, the observed wintertime densities are smaller than the predictions of the IRI2001 model, especially at a higher (840 km) altitude, manifesting strong hemispheric asymmetries. The observed electron temperatures generally reside between the two estimations of IRI2001, one based on the Aeros–ISIS data and the other based on Intercosmos, and the latter estimation better represents the observations. With more or less monotonic increase with latitude, the temperature profiles of the IRI2001 model do not predict the enhancement seen around 15° magnetic latitude of the winter hemisphere. Longitudinal variation, probably caused by the zonal winds, is seen in all seasons at both altitudes, while the IRI2001 model does not show a large variation. The observed density and temperature show significant changes according to the F10.7 values in the whole low-latitude region from 40°S to 40°N geomagnetic latitude. The effect is manifested as increases in the density and temperature, but not in the hemispheric asymmetry or in the longitudinal variation.     

The high-velocity molecular stream in W51B: a ring structure with compact H ii regions

We present ¹³ CO J  = 1 − 0 line observations of the H  ii region complex W51B located in the high-velocity (HV) stream. These observations reveal a filamentary and clumpy structure in the molecular gas. The mean local standard of rest (LSR) velocity ∼ + 65 km s⁻¹ of the molecular gas in this region is greater than the maximum velocities allowed by kinematic Galactic rotation curves. The size and mass of the molecular clouds are ∼ 48 × 17 pc² and ∼ 2.4 × 10⁵ M⊙ respectively. In a position–velocity diagram, molecular gas in the southern part comprises a redshifted ring structure with v _LSR=+ 60 to +73 km s⁻¹. The velocity gradient of this ring is ∼ 0.5 km s⁻¹ pc⁻¹, and the mass is ∼ 6.2 × 10⁴ M⊙. If we assume that the ring is expanding with a uniform velocity, the expansion velocity, radius and kinetic energy are ∼ 7 km s⁻¹, ∼ 13 pc and ∼ 3.0 × 10 ⁴⁹ erg respectively. The kinetic energy and mass spectrum of the ring could be explained by an expanding cylindrical cloud with a centrally condensed mass distribution. The locations of two compact H  ii regions, G49.0−0.3 and G48.9−0.3, coincide with the two molecular clumps in this ring. We discuss star formation, and the mechanism that produced the ring structure.     

Ammonium regeneration and biomass of macrozooplankton and ctenophores in Great South Bay,New York

The rate of zooplankton ammonium regeneration was measured in Great South Bay, Long Island, New York, between July 1982 and May 1984. Ammonium excretion by macrozooplankton (>200 μm) ranged from 7 μg atoms NH₄ ¹⁺?N m^?3 d^?1 in winter to 156 μg-atoms NH₄ ¹⁺?N m^?3 d^?1 in spring. Ammonium excretion by ctenophores was greater than or equivalent to that of macrozooplankton during the period of ctenophore biomass maximum in summer and fall. The temperature coefficient (Q₁₀) for NH₄ ¹⁺ excretion was 1.74 from 2.2 to 27.5°C for macrozooplankton and 1.63 between 17 and 26°C for the ctenophores. Ammonium nitrogen excretion by macrozooplankton and ctenophores combined, accounted for 1 to 3% of phytoplankton nitrogen requirements in summer when primary productivity was high and 39% in the spring. *** DIRECT SUPPORT *** A01BY040 00005     

Influence of rainfall-induced wetting on the stability of slopes in weathered soils

Shallow failures of slopes in weathered soil are caused by infiltration due to prolonged rainfall. These failures are mainly triggered by the deepening of the wetting band accompanied by a decrease in matric suction induced by the water infiltration. This paper reports trends of rainfall-induced wetting band depth in two types of weathered soils that are commonly found in Korea. Both theoretical and numerical analyses for wetting band depth are presented based on the soil–water characteristic curve obtained using filter paper as well as tensiometer tests. It is found that the magnitude of wetting front suction plays a key role in the stability of slopes in weathered soils. Theoretical analysis based on modified Green and Ampt model tends to underestimate the wetting band depth for typical Korean weathered soils. It was also deduced that for Korean weathered soils, the factor of safety drops rapidly once the wetting band depth of 1.2 m reached.     

Heterogeneous structure of western Nankai seismogenic zone deduced by multichannel reflection data and wide-angle seismic data

The 1946 Nankai earthquake (Ms=8.2) at the forearc region of the western Nankai Trough showed slow slip deformation off Cape Muroto, which did not propagate until the western end of the Nankai seismogenic zone. New seismic investigations show a low-velocity layer (LVL) on the subducting oceanic crust in the coseismic area. Two prestack depth-migrated sections show reflectivity events in the clay-rich boundary layer on the oceanic crust. Narrowly spaced imbricated slices develop in the nonrupture area. The reflective boundary layer indicates probably that underplating develops in the nonrupture area rather than the coseismic area. It is suggested that the friction is larger in the nonrupture area than the coseismic area because of the lack of LVL on the oceanic crust, the well developed underplating and the narrowly spaced imbricated thrusts in the nonrupture area. The topographic high of the oceanic crust with about 50 km width and maximum 3 km height is also revealed and is related to bending and thickening of the oceanic crust, the well developed underplating and the narn spaced imbricated thrusts in the nonrupture area. These structural characters may be the reason why the slow slip deformation did not propagate until the western end of the Nankai seismogenic zone and toward the trough side.     

Deformable backstop as seaward end of coseismic slip in the Nankai Trough seismogenic zone

Wide-angle seismic surveys performed in the last decade have clarified the 3-D crustal structure along the Nankai Trough. The geometry and velocity structure of the southwestern Japan subduction zone are now well constrained. Comparing these observations with the rupture distribution of historic great thrust earthquakes, it appears that the coseismic rupture occurred along plate boundaries deeper than the wedge/backstop boundary (the boundary between the Neogene-Quaternary accretionary wedge and the crust forming the backstop). From the view of spatial relationship, both rupture distributions of the last two large events and the crust forming the backstop are considerably retreated from the trough axis in the west and east off the Kii Peninsula. In both areas, seamount or ridge subduction is apparent in seismic results, geomorphological data and geomagnetic data. The landward indentation of the deformable backstop, which corresponds to the crustal block of old accreted sediments, may be formed by seamount subduction according to published results of sandbox modeling. In particular, the subducted seamount may be a structural factor affecting the recession of the crustal block forming the backstop.     

Estimating Ore Production in Open-pit Mines Using Various Machine Learning Algorithms Based on a Truck-Haulage System and Support of Internet of Things

Natural Resources Research - This study aimed to develop and assess the feasibility of different machine learning algorithms for predicting ore production in open-pit mines based on a truck-haulage...