Progressive metamorphism of the Taitao ophiolite; evidence for axial and off-axis hydrothermal alterations

We estimated metamorphic conditions for the  6 Ma Taitao ophiolite, associated with the Chile triple junction. The metamorphic grade of the ophiolite, estimated from secondary matrix minerals, changes stratigraphically downwards from the zeolite facies, through the prehnite–actinolite facies, greenschist facies and the greenschist–amphibolite transition, to the amphibolite facies. The metamorphic facies series corresponds to the low-pressure type. The metamorphic zone boundaries are subparallel to the internal lithological boundaries of the ophiolite, indicating that the metamorphism was due to axial hydrothermal alteration at a mid-ocean ridge.

Mineral assemblages and the compositions of veins systematically change from quartz-dominated, through epidote-dominated, to prehnite-dominated with increasing depth. Temperatures estimated from the vein assemblages range from  230 °C in the volcanic unit to  380 °C at the bottom of the gabbro unit, systematically  200 °C lower than estimates from the adjoining matrix minerals. The late development of veins and the systematically lower temperatures suggest that the vein-forming alteration was due to off-axis hydrothermal alteration.

Comparison between the Taitao ophiolite with its mid-ocean ridge (MOR) affinity, and other ophiolites and MOR crusts, suggests that the Taitao ophiolite has many hydrothermal alteration features similar to those of MOR crusts. This is consistent with the tectonic history that the Taitao ophiolite was formed at the South Chile ridge system near the South American continent (Anma, R., Armstrong, R., Danhara, T., Orihashi, Y. and Iwano, H., 2006. Zircon sensitive high mass-resolution ion microprobe U–Pb and fission-track ages for gabbros and sheeted dykes of the Taitao ophiolite, Southern Chile, and their tectonic implications. The Island Arc, 15(1): 130–142).     

An organic geochemical study of KP-2 core on the mud volcano at Nankai Trough

Organic geochemical data was collected from a KP-2 piston core sample obtained from a mud volcano in the Nankai Trough, off the southeast coast of Japan. The Nankai Trough was investigated geologically and was found to have a large amount of methane hydrates. Biomarkers indicating anaerobic oxidation of methane (AOM) were expected to be found in the sediment of the mud volcano collected by KP-2 core. But the gas chromatography-mass spectrometry (GC-MS) analysis of the samples showed only one biomarker related to the methane-oxidizing Archaea, namely 2,6,10,15,19-pentamethyleicosane (PME), could be detected throughout the KP-2 core. Phytane was predominant in the upper part of the KP-2 core; however, a series of 2,2-dimethylalkanes (2,2-DMAs) were characterized in the lower part of KP-2 core. The individual δ¹³C values of 2,2-DMAs, which were − 29.1 to − 27.3‰ indicate that the origin of 2,2-DMAs was not related to methane-oxidizing Archaea.     

Subhorizontal boundary between ultrahigh-pressure and low-pressure metamorphic units in the Sulu–Tjube area of the Kokchetav Massif, Kazakhstan

Abstract The Kokchetav Massif of Kazakhstan includes high to ultrahigh-pressure (HP–UHP) metamorphic rocks (some of which were recrystallized at depths in excess of 150 km), juxtaposed against much lower pressure metamorphic components. We investigated the relationship between the HP–UHP metamorphic unit and the low pressure (LP) unit (Daulet Suite) in the Sulu–Tjube area, where the metamorphic rocks have previously been interpreted as constituting a megamelange with subvertical structural attitudes. Analyses of fold structures suggest that the HP–UHP metamorphic unit overlies the LP unit across a west-dipping subhorizontal boundary. In addition, kinematic indicators display top-to-the-north senses of shear along the tectonic contact between the two units, indicating that the HP–UHP unit has been extruded northward onto the LP unit. Following the juxtaposition of the two units, upright folds developed in both units, and these are associated with the previously reported steeply dipping metamorphic foliations. These data have important implications for the mode of exhumation of the UHP rocks from upper mantle to shallow crustal depths.     

Particle Image Velocimetry Measurements of Turbulent Flow Within Outdoor and Indoor Urban Scale Models and Flushing Motions in Urban Canopy Layers

We investigate the spatial characteristics of urban-like canopy flow by applying particle image velocimetry (PIV) to atmospheric turbulence. The study site was a Comprehensive Outdoor Scale MOdel (COSMO) experiment for urban climate in Japan. The PIV system captured the two-dimensional flow field within the canopy layer continuously for an hour with a sampling frequency of 30 Hz, thereby providing reliable outdoor turbulence statistics. PIV measurements in a wind-tunnel facility using similar roughness geometry, but with a lower sampling frequency of 4 Hz, were also done for comparison. The turbulent momentum flux from COSMO, and the wind tunnel showed similar values and distributions when scaled using friction velocity. Some different characteristics between outdoor and indoor flow fields were mainly caused by the larger fluctuations in wind direction for the atmospheric turbulence. The focus of the analysis is on a variety of instantaneous turbulent flow structures. One remarkable flow structure is termed ‘flushing’, that is, a large-scale upward motion prevailing across the whole vertical cross-section of a building gap. This is observed intermittently, whereby tracer particles are flushed vertically out from the canopy layer. Flushing phenomena are also observed in the wind tunnel where there is neither thermal stratification nor outer-layer turbulence. It is suggested that flushing phenomena are correlated with the passing of large-scale low-momentum regions above the canopy.     

Correlating biostratigraphy and palaeoceanographic changes during late Quaternary at cold seeps with gas hydrate‐free areas of the Japan Sea using foraminifera paleoecology

Late Quaternary foraminifera assemblages have been examined in two sediment cores (MD179‐3296 and MD179‐3317) from cold seep areas in the eastern margin of the Japan Sea, off Joetsu, Niigata Prefecture. Foraminifera assemblages in core MD179‐3296, which was located at the center of a pockmark on the Umitake Spur, show no evidence of methane flux and, especially in its upper portion, share the same paleo‐environmental history as other free gas hydrate areas of the Japan Sea. In comparison, in the core MD179‐3317 at the center of a pockmark at Joetsu Knoll, foraminiferal distributions were strongly affected by methane activities and, in the main part of the core, were deposited under local conditions. Three horizons were identified in this core, which are characterized by the high abundance value of Thalmannammina parkerae and might be related to methane flux due to sea level fall especially through late marine isotope stage (MIS) 3 and MIS 2.     

Spatial Variability of Both Turbulent Fluxes and Temperature Profiles in an Urban Roughness Layer

The spatial variability of both turbulent flow statistics in the roughness sublayer (RSL) and temperature profiles within and above the canopy layer (CL) were investigated experimentally in a densely built-up residential area in Tokyo, Japan. Using five towers with measuring devices, each tower isolated from the others by at least 200 m, we collected high-frequency measurements of velocity and temperature at a height z=1.8 z _H, where z _H, the mean building height in the area, is 7.3 m. Also, temperature profiles were measured from z=0.4 to 1.8 z _H. The ‘areal mean’ geometric parameters that were obtained for the areas within 200 m of each tower were fairly homogeneous among the tower sites. The main results are as follows: (1) The spatial variability of all RSL turbulent statistics, except the sensible heat flux, was comparable to that reported in a pine forest. Also, the variability decreased with increasing friction velocity. (2) The spatial variability of the RSL sensible heat flux was larger than that reported in a pine forest. Also, the variability depended on the time of the day and became larger in the morning. The difference among the sites was well related to the areal fraction of vegetation. (3) The spatial variability of the CL temperature profile depended on the time of the day and became larger in the morning. Nevertheless, the spatial standard deviation of CL temperature was always below 0.7 K. (4) It is suggested that the “warming-up” process in the morning when heat storage is dominant increases the spatial variation of RSL sensible heat flux and CL temperature according to the local properties around each tower and the variation decreases once there is further convective mixing in the midday     

High-pressure phase transition and behavior of protons in brucite Mg(OH)2: a high-pressure–temperature study using IR synchrotron radiation

 Infrared absorption spectra of brucite Mg (OH)₂ were measured under high pressure and high temperature from 0.1 MPa 25 °C to 16 GPa 360 °C using infrared synchrotron radiation at BL43IR of Spring-8 and a high-temperature diamond-anvil cell. Brucite originally has an absorption peak at 3700 cm⁻¹, which is due to the OH dipole at ambient pressure. Over 3 GPa, brucite shows a pressure-induced absorption peak at 3650 cm⁻¹. The pressure-induced peak can be assigned to a new OH dipole under pressure. The new peak indicates that brucite has a new proton site under pressure and undergoes a high-pressure phase transition. From observations of the pressure-induced peak under various P–T condition, a stable region of the high-pressure phase was determined. The original peak shifts to lower wavenumber at −0.25 cm⁻¹ GPa⁻¹, while the pressure-induced peak shifts at −5.1 cm⁻¹ GPa⁻¹. These negative dependences of original and pressure-induced peak shifts against pressure result from enhanced hydrogen bond by shortened O–H···O distance, and the two dependences must result from the differences of hydrogen bond types of the original and pressure-induced peaks, most likely from trifurcated and bent types, respectively. Under high pressure and high temperature, the pressure-induced peak disappears, but a broad absorption band between 3300 and 3500 cm⁻¹ was observed. The broad absorption band may suggest free proton, and the possibility of proton conduction in brucite under high pressure and temperature. Received: 16 July 2001 / Accepted: 25 December 2001     

The Kuroshio Current System as a jet and twin “relative” recirculation gyres embedded in the Sverdrup circulation

By analyzing the results of a realistic ocean general circulation model (OGCM) and conducting a series of idealized OGCM experiments, the dynamics of the Kuroshio Current System is examined. In the realistic configuration, the Kuroshio Current System is successfully simulated when the horizontal resolution of OGCMs is increased from 1/2° to 1/10°. The difference between the two experiments shows a jet, the model’s Kuroshio Extension, and a pair of cyclonic and anticyclonic, “relative,” recirculation gyres (RRGs) on the northern and southern flanks of the jet. We call them recirculation gyres because they share some features with ordinary recirculation gyres in previous studies, and we add the adjective “relative” to emphasize that they may not be apparent in the total field. Similar zonal jet and RRGs are obtained also in the idealized model with a rectangular basin and a flat bottom with a horizontal resolution of 1/6°. The northern RRG is generated by the injection of high potential vorticity (PV) created in the viscous sublayer of the western boundary current, indicating the importance of a no-slip boundary condition. Since there is no streamline with such high PV in the Sverdrup interior, the eastward current in the northern RRG region has to lose its PV anomaly by viscosity before connecting to the interior. In the setup stage this injection of high PV is carried out by many eddies generated from the instability of the western boundary current. This high PV generates the northern RRG, which induces the separation of the western boundary current and the formation of the zonal jet. In the equilibrium state, the anomalous high PV values created in the viscous sublayer are carried eastward in the northern flank of the zonal jet. The southern RRG is due to the classical Rhines–Young mechanism, where low PV values are advected northward within the western boundary inertial sublayer, and closed, PV-conserving streamlines form to the south of the Kuroshio Extension, allowing slow homogenization of the low PV anomalies. The westward-flowing southern branch of this southern RRG stabilizes the inertial western boundary current and prevents its separation in the northern half of the Sverdrup subtropical gyre, where the western boundary current is unstable without the stabilizing effect of the southern RRG. Therefore, in the equilibrium state, the southern RRG should be located just to the north of the center of the Sverdrup subtropical gyre, which is defined as the latitude of the Sverdrup streamfunction maximum. The zonal jet (the Kuroshio Extension) and the northern RRG gyre are formed to the north of the southern RRG. This is our central result. This hypothesis is confirmed by a series of sensitivity experiments where the location of the center of the Sverdrup subtropical gyre is changed without changing the boundaries of the subtropical gyre. The locations of the zonal jets in the observed Kuroshio Current System and Gulf Stream are consistent as well. Sensitivities of the model Kuroshio Current System are also discussed with regard to the horizontal viscosity, strength of the wind stress, and coastline.     

Alkalinization and acidification of stream water with changes in atmospheric deposition in a tropical dry evergreen forest of northeastern Thailand

Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO₄^2? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO₄^2? concentration (13.5–60.6 μmol_c/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 mol_c/ha). Release of SO₄^2? with H⁺, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO₄^2? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO₄^2? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO₄^2? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO₄^2? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.     

Impact of mesoscale eddies on particulate organic carbon flux in the western subarctic North Pacific

The mechanism that controls particulate organic carbon (POC) flux in the deep sea differs depending on the season and sea. The POC produced in the western subarctic North Pacific are known to be transported to the deep sea efficiently, but the direct relationship between the POC flux and physical processes is still unclear. In this study, we evaluated the effect of mesoscale eddies on POC flux in the western subarctic North Pacific. The seasonal and interannual variabilities of POC flux were investigated using data from a time-series sediment trap deployed at 4810 m at station K2 (47°N, 160°E) from 2005 to 2018. POC flux was high during May–November, appearing to reflect spring and fall blooms at the ocean surface. POC flux also showed interannual variability, with twelve peaks that were mostly affected by enhanced bloom just before the peak. Nine peaks of the twelve peaks were affected by mesoscale eddies, which enhanced bloom around K2 by extending the area with a high chlorophyll-a concentration along the coastal region into the offshore region, suggesting that mesoscale eddies strongly impact the interannual variability of POC flux at K2.