Beyond 'someone else's agenda': An example of indigenous/academic research collaboration

In recent years, Māori and wider indigenous geographies have flourished. These include works by scholars identifying specific Māori or indigenous issues but less attention has been paid to the way such research is conducted. This paper engages with these developments and presents the practices and lessons learnt from one particular research collaboration. Relationship building, multiple methods, flexibility, communication choices and wider support are all noted as key elements in establishing a supportive and fruitful collaboration.     

Evaluation of terrestrial carbonaceous matter aromatization by Raman spectroscopy and its application to C chondrites

A Raman method to estimate the aromatization degree of carbonaceous matter (CM) was established, and calibrated by literature data respecting differences in acquisition procedures. The generated equations allowed a comparison of the G‐band width to vitrinite reflectance, and to additional structural organization parameter extracted from X‐ray powder diffraction. The relations between aromatization degree and peak temperatures from literature were then propagated to G‐band width parameter. The applicability of these geothermometers is demonstrated by the consistency of data obtained for carbonaceous chondrites with previous estimations. Since the CM aromatization is controlled by peak temperature and time span, it is possible to estimate the duration of chondrite’s heating events. The G‐band width relation to elemental ratio trends of organic matter in chondrites, interplanetary dust particles, glucose, and saccharose‐based semi‐coke favors synthesis by formose route. These findings provide new approaches for the future development of chemical kinetic models for organic matter of chondrites. A reliable chemical model may allow the external calibration of numerical models for accurately evaluating the peak temperatures and cooling durations of chondrites.     

Australia House: stones a long way from home

Australia House is a prominent, Grade II listed building located on The Strand in London. It is the home of the High Commission of Australia, the diplomatic mission of Australia in the UK. It opened on 3 August 1918, just over a hundred years ago, and this opportunity is taken to commemorate this building through the remarkable stones used in its construction.     

A ~180,000 years sedimentation history of a perialpine overdeepened glacial trough (Wehntal, N-Switzerland)

A 30 m-deep drill core from a glacially overdeepened trough in Northern Switzerland recovered a ~180 ka old sedimentary succession that provides new insights into the timing and nature of erosion–sedimentation processes in the Swiss lowlands. The luminescence-dated stratigraphic succession starts at the bottom of the core with laminated carbonate-rich lake sediments reflecting deposition in a proglacial lake between ~180 and 130 ka ago (Marine Isotope Stage MIS 6). Anomalies in geotechnical properties and the occurrence of deformation structures suggest temporary ice contact around 140 ka. Up-core, organic content increases in the lake deposits indicating a warming of climate. These sediments are overlain by a peat deposit characterised by pollen assemblages typical of the late Eemian (MIS 5e). An abrupt transition following this interglacial encompasses a likely hiatus and probably marks a sudden lowering of the water level. The peat unit is overlain by deposits of a cold unproductive lake dated to late MIS 5 and MIS 4, which do not show any direct influence from glaciers. An upper peat unit, the so-called «Mammoth peat», previously encountered in construction pits, interrupts this cold lacustrine phase and marks more temperate climatic conditions between 60 and 45 ka (MIS 3). In the upper part of the core, a succession of fluvial and alluvial deposits documents the Late Glacial and Holocene sedimentation in the basin. The sedimentary succession at Wehntal confirms that the glaciation during MIS 6 did not apparently cause the overdeepening of the valley, as the lacustrine basin fill covering most of MIS 6 is still preserved. Consequently, erosion of the basin is most likely linked to an older glaciation. This study shows that new dating techniques combined with palaeoenvironmental interpretations of sediments from such overdeepened troughs provide valuable insights into the past glacial history.     

Promoting a coupled human and natural systems approach to addressing conservation in complex mountainous landscapes of Central Asia

Global climate change, nonpoint source pollution, watershed and wildlife habitat destruction, and unsustainable development are damaging the natural world, threatening the socio-cultural integrity of communities, and jeopardizing the livelihood security of peoples worldwide. Despite the past 50 years of progress in addressing environmental damage in the United States and elsewhere, intractable problems have arisen that to date have eluded successful technological or policy responses. Solutions have been sought by recognizing that these problems are very complex and demand interdisciplinary approaches that require building effective partnerships among relevant academic institutions, governmental agencies, nongovernmental organizations, and private business, as well as levering various disciplines and traditional knowledge systems. Such thinking has evolved to now consider humans to be an integral part of nature, which is captured in the idea of the ‘human ecosystem’, where biophysical, socioeconomic, and cultural systems interact via a complex set of organizational, spatial, and temporal ‘couplings’. Within such a context, environmental problems can be viewed as coupled human and natural systems, which afford unique and novel approaches to their solutions. This paper discusses the development of the coupled systems approach as a scientific methodology, reviews its key characteristics and principles, provides an example of how it has been applied to assess conservation issues in alpine areas of Northwest Yunnan Province, China, and recommends how this scientific approach might be further developed for use in mountainous landscape regions of Central Asia and elsewhere.     

Duration and extent of lunar volcanism: Comparison of 3D convection models to mare basalt ages

It is widely accepted that lunar volcanism started before the emplacement of the mare fills ( b.p.) and lasted for probably more than 3.0 Ga. While the early volcanic activity is relatively easy to understand from a thermal point of view, the late stages of volcanism are harder to explain, because a relatively small body like the Earth's Moon is expected to cool rapidly and any molten layer in the interior should solidify rather quickly. We present several thermal evolution models, in which we varied the boundary conditions at the model surface in order to evaluate the influence on the extent and lifetime of a molten layer in the lunar interior. To investigate the influence of a top insulating layer we used a fully three-dimensional spherical shell convection code for the modelling of the lunar thermal history. In all our models, a partial melt zone formed nearly immediately after the simulation started (early in lunar history), consistent with the identification of lunar cryptomare and early mare basalt volcanism on the Moon. Due to the characteristic thickening of the Moon's lithosphere the melt zone solidified from above. This suggests that the source regions of volcanic rock material proceeded to increasing depth with time. The rapid growth of a massive lithosphere kept the Moon's interior warm and prevented the melt zone from fast freezing. The lifetimes of the melt zones derived from our models are consistent with basalt ages obtained from crater chronology. We conclude that an insulating megaregolith layer is sufficient to prevent the interior from fast cooling, allowing for the thermal regime necessary for the production and eruption of young lava flows in Oceanus Procellarum.     

Fractionation of oxygen isotopes in phosphate during its interactions with iron oxides

Iron (III) oxides are ubiquitous in near-surface soils and sediments and interact strongly with dissolved phosphates via sorption, co-precipitation, mineral transformation and redox-cycling reactions. Iron oxide phases are thus, an important reservoir for dissolved phosphate, and phosphate bound to iron oxides may reflect dissolved phosphate sources as well as carry a history of the biogeochemical cycling of phosphorus (P). It has recently been demonstrated that dissolved inorganic phosphate (DIP) in rivers, lakes, estuaries and the open ocean can be used to distinguish different P sources and biological reaction pathways in the ratio of ¹⁸O/¹⁶O (δ¹⁸O_P) in PO₄³⁻. Here we present results of experimental studies aimed at determining whether non-biological interactions between dissolved inorganic phosphate and solid iron oxides involve fractionation of oxygen isotopes in PO₄. Determination of such fractionations is critical to any interpretation of δ¹⁸O_P values of modern (e.g., hydrothermal iron oxide deposits, marine sediments, soils, groundwater systems) to ancient and extraterrestrial samples (e.g., BIF’s, Martian soils). Batch sorption experiments were performed using varied concentrations of synthetic ferrihydrite and isotopically-labeled dissolved ortho-phosphate at temperatures ranging from 4 to 95 °C. Mineral transformations and morphological changes were determined by X-Ray, Mössbauer spectroscopy and SEM image analyses.Our results show that isotopic fractionation between sorbed and aqueous phosphate occurs during the early phase of sorption with isotopically-light phosphate (P¹⁶O₄) preferentially incorporated into sorbed/solid phases. This fractionation showed negligible temperature-dependence and gradually decreased as a result of O-isotope exchange between sorbed and aqueous-phase phosphate, to become insignificant at greater than ∼100 h of reaction. In high-temperature experiments, this exchange was very rapid resulting in negligible fractionation between sorbed and aqueous-phase phosphate at much shorter reaction times. Mineral transformation resulted in initial preferential desorption/loss of light phosphate (P¹⁶O₄) to solution. However, the continual exchange between sorbed and aqueous PO₄, concomitant with this mineralogical transformation resulted again in negligible fractionation between aqueous and sorbed PO₄ at long reaction times (>2000 h). This finding is consistent with results obtained from natural marine samples. Therefore, ¹⁸O values of dissolved phosphate (DIP) in sea water may be preserved during its sorption to iron-oxide minerals such as hydrothermal plume particles, making marine iron oxides a potential new proxy for dissolved phosphate in the oceans.     

Response of the coccolithophores Emiliania huxleyi and Coccolithus braarudii to changing seawater Mg and Ca concentrations: Mg/Ca, Sr/Ca ratios and δCa, δMg of coccolith calcite

Calcium and magnesium concentrations in seawater have varied over geological time scales. On short time scales, variations in the major ion composition of seawater influences coccolithophorid physiology and the chemistry of biogenically produced coccoliths. Validation of those changes via controlled laboratory experiments is a crucial step in applying coccolithophorid based paleoproxies for the reconstruction of past environmental conditions. Therefore, we examined the response of two species of coccolithophores, Emiliania huxleyi and Coccolithus braarudii, to changes in the seawater Mg/Ca ratio (≈0.5 to 10 mol/mol) by either manipulating the magnesium or calcium concentration under controlled laboratory conditions. Concurrently, seawater Sr/Ca ratios were also modified (≈2 to 40 mmol/mol), while keeping salinity constant at 35. The physiological response was monitored by measurements of the cell growth rate as well as the production rates of particulate inorganic and organic carbon, and chlorophyll a. Additionally, coccolithophorid calcite was analyzed for its elemental composition (Sr/Ca and Mg/Ca) as well as isotope fractionation of calcium and magnesium (Δ^44/40Ca and Δ^26/24Mg). Our results reveal that physiological rates were substantially influenced by changes in seawater calcium rather than magnesium concentration within the range estimated to have occurred over the past 250 million years when coccolithophores appear in the fossil record. All physiological rates of E. huxleyi decreased at a calcium concentration above 25 mmol L⁻¹, whereas C. braarudii displayed a higher tolerance to increased seawater calcium concentrations. Partition coefficient of Sr was calculated as 0.36 ± 0.04 (±2σ) independent of species. Partition coefficient of Mg²⁺ increased with increasing seawater Ca²⁺ concentrations in both coccolithophore species. Calcium isotope fractionation was constant at 1.1 ± 0.1‰ (±2σ) and not altered by changes in seawater Mg/Ca ratio. There is a well-defined inverse linear relationship between calcium isotope fractionation and partition coefficient of Sr²⁺ in all experiments, suggesting similar controls on both proxies in the investigated species. Magnesium isotope ratios were relatively stable for seawater Mg/Ca ratios ranging from 1 to 5, with a higher degree of fractionation in Emiliania huxleyi (by ≈0.2‰ in Δ^26/24Mg). Although Mg/Ca ratios in the calcite of coccolithophores and foraminifera are similar, the former have considerably higher Δ^26/24Mg (by >+3‰), presumably due to differences in calcification mechanisms between the two taxa. These observations suggest, a physiological control over magnesium elemental and isotopic fractionation during the process of calcification in coccolithophores.     

Contemporary Rates of Carbon Sequestration Through Vertical Accretion of Sediments in Mangrove Forests and Saltmarshes of South East Queensland,Australia

Mangrove forests and saltmarshes are important habitats for carbon (C) sequestration in the coastal zone but variation in rates of C sequestration and the factors controlling sequestration are poorly understood. We assessed C sequestration in Moreton Bay, South East Queensland in mangrove forests and tidal marshes that span a range of environmental settings and plant communities, including mangrove forests and tidal marshes on the oligotrophic sand islands of the eastern side of Moreton Bay and on the nutrient enriched, western side of the bay adjacent to the city of Brisbane. We found that rates of C sequestration in sediments were similar among mangrove forests over the bay, despite large differences in the C density of sediments, because of different rates of vertical accretion of sediments. The C sequestration on the oligotrophic sand island tidal marshes, dominated by Juncus kraussii, had the highest rate of C sequestration in the bay while the western saltmarshes, which were dominated by Sarcocornia quinqueflora, had the lowest rate of C sequestration. Our data indicate C sequestration varies among different tidal wetland plant community types, due to variation in sediment characteristics and rates of sediment accretion over time.     

Holocene Paleo‐Geographic Reconstructions of the Ramore Head Area,Northern Ireland,Using Geophysical and Geotechnical Data: Paleo‐Landscape Mapping and Archaeological Implications

We present early to Mid‐Holocene paleo‐geographic reconstructions for the Ramore Head area (Northern Ireland). This coastal area is characterized by Mesolithic occupation (c. 10–6 ka) and preserved early–Mid‐Holocene peats both on‐ and offshore. This paper improves on previous reconstructions by employing a backstripping methodology, which removes accumulated recent deposits from identified buried paleo‐landsurfaces instead of using modern topography as an analogue to the past landscape. Paleo‐landsurfaces are identified offshore from seismic profiles supplemented by cores, and onshore through legacy borehole records. The paleo‐landsurface can be traced offshore to depths of −2 to −19 m and is buried by <5 m of modern sediment. It extends onshore under the coastal town of Portrush and is buried <2.5–10 m below modern ground level. The identified paleo‐landsurface is combined with sea‐level curves from recent Glacio‐Isostatic‐Adjustment models to reconstruct marine transgression during the early–Mid‐Holocene. Comparison is also made with reconstructions based on modern topography. Together, the identified paleo‐landsurfaces and revised reconstructions can assist future site prospection on‐ and offshore and delimit high‐potential areas for heritage management. Revised reconstructions also allow placement of extant archaeology into a more accurate context of landscape change and help develop insights into local‐scale site location patterns.