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81.
Several stratigraphic sequences in the Upper Carboniferous (Pennsylvanian) in Kansas (Midcontinent, USA) were analyzed quantitatively for periodic repetitions. The sequences were coded by lithologic type into strings of datasets. The strings then were analyzed by an adaptation of a one-dimensional Fourier transform analysis and examined for evidence of periodicity. The method was tested using different states in coding to determine the robustness of the method and data. The most persistent response is in multiples of 8–10 ft (2.5–3.0 m) and probably is dependent on the depositional thickness of the original lithologic units. Other cyclicities occurred in multiples of the basic frequency of 8–10 with persistent ones at 22 and 30 feet (6.5–9.0 m) and large ones at 80 and 160 feet (25–50 m). These levels of thickness relate well to the basic cyclothem and megacyclothem as measured on outcrop. We propose that this approach is a suitable one for analyzing cyclic events in the stratigraphic record. 相似文献
82.
In situ flow-through attenuated total reflectance (ATR) Fourier transform infrared (FTIR) spectroscopy has been used to investigate the formation, and step-wise oxidation, of sulfoxyanions at the pyrite surface during oxidation by molecular oxygen. The surface was studied under two different pH regimes (pH 2.5 and pH 5.6) and under two light conditions (dark and ultraviolet light). It was experimentally observed that multiple sulfoxyanions were present at the pyrite surface during oxidation by molecular oxygen, spectroscopically illustrating the concept of sulfur step-wise oxidation. The results from photochemical experiments were complex and suggest a dependence on both pH and surface speciation. 相似文献
83.
Particles in shear enclose important information about a rock's past and can potentially be used to decipher the kinematic history and mechanical behavior of a certain outcrop or region. Isolated rigid clasts in shear zones often exhibit systematic inclinations with respect to the shear-plane at small angles, tending towards the instantaneous stretching direction of the shear zone. This shape preferred orientation cannot be easily explained by any of the analytical theories used in geology. It was recently recognized that a weak mantle surrounding the clast or a slipping clast–matrix interface might be responsible for the development of the observed inclinations. Physical considerations lead us to conjecture that such mantled, rigid clasts can be effectively treated as voids that are not allowed to change their shape. The resulting equivalent void conjecture agrees well with numerical and field data and has the following important geological implications. (i) Clasts in shear zones can have stable positions in simple shear without the requirement of an additional pure shear component. (ii) The stable orientation can be approached either syn- or antithetically; hence, the clast can rotate against the applied shear sense. (iii) The strain needed to develop a strong shape preferred orientation is small (γ≈1) and therefore evaluations based on other theories may overestimate strain by orders of magnitude. (iv) The reconstruction of far-field shear flow conditions and kinematic vorticity analysis must be modified to incorporate these new findings. 相似文献
84.
85.
Atika Karim Mostafa Berkhli Daniel Vachard Nicolas Tribovillard Beate Orberger 《Comptes Rendus Geoscience》2005,337(5):525-532
The unexplored area of Azarhare in central Morocco is studied thanks to three sections composed of five lithological facies Main biostratigraphical and sedimentological results concern (1) the identification of Late Visean biozones, with important presence of problematic algae Ungdarella, (2) the regional extension of deposit sequences SD5, SD6 and SD7 previously defined, (3) and an analysis of the diagenetic kaolinite. To cite this article: A. Karim et al., C. R. Geoscience 337 (2005). 相似文献
86.
87.
Daniel J. Sinclair 《Geochimica et cosmochimica acta》2005,69(13):3265-3284
Micron-scale variations in the trace-element (TE) composition of tropical coral skeletons were measured using laser-ablation ICP-MS (LA-ICP-MS) as part of an investigation into the chemical processes underlying paleoenvrionmental proxy reconstructions. Fluctuations in B, Mg, Sr, Ba and U were measured at high spatial resolution in two Porites corals from the Great Barrier Reef (Australia), and the fine-scale fluctuations (< ∼1.0 mm) were compared with seasonal TE cycles in a third coral. Fine-scale TE variations were found to have a large amplitude over distances corresponding to less than 1 month growth. Variations were quasi-periodic and appeared to have characteristic wavelengths on weekly (6-7 d) and monthly (28 d) scales, although periodicity was not continuous and variations could not be matched either within or between individual corallites. Fine-scale variations between Mg, Sr and U were significantly correlated with each other (Sr and U are positively correlated, but negatively correlated with Mg). This 3D correlation “vector” has the same slope as the seasonal-scale Mg, Sr and U correlations, suggesting that the same chemical/biologic biomineralization process mediates trace element variations at both timescales. Importantly, the fine-scale variations are too large to be caused directly by daily to monthly fluctuations in sea-surface temperature. This means that seasonal variations in these elements cannot reflect purely inorganic temperature-dependent coprecipitation. Models of physicochemical calcification were developed to test whether changes in calcification rate could explain the trace-element correlations. The calculations show that increases in calcification rate will result in correlated decreases in all TE/Ca ratios. The models reproduce the Sr partition coefficient, trace-element correlation slopes, and amplitude of fine-scale variations for an average calcifying pH of 8.5, varying by ±0.2 pH units. The models, however, predict U partition coefficients which are too low, and cannot reproduce the negative correlation between Mg and the other trace elements, which may be caused by crystallographic factors. 相似文献
88.
89.
The Sheep Mountain‐Little Sheep Mountain Anticlines, Bighorn Basin (USA) formed as basement‐cored Laramide structures in the formerly undeformed foreland of the thin‐skinned Sevier orogen. We take advantage of the well‐constrained microstructural network there to reconstruct differential stress magnitudes that prevailed during both Sevier and Laramide layer‐parallel shortening (LPS), before the onset of large‐scale folding. Differential stress magnitudes determined from tectonic stylolites are compared and combined to previous stress estimates from calcite twinning paleopiezometry in the same formations. During stress loading related to LPS, differential stress magnitudes transmitted from the distant Sevier thin‐skinned orogen into the sedimentary cover of the Bighorn basin (11–43 MPa) are higher than the differential stress magnitudes accompanying the early stage of LPS related to the thick‐skinned Laramide deformation (2–19 MPa). This study illustrates that the tectonic style of an orogen affects the transmission of early orogenic stress into the stable continental interior. 相似文献
90.
Mohammad M. Sohrabi Rohan Benjankar Daniele Tonina Seth J. Wenger Daniel J. Isaak 《水文研究》2017,31(9):1719-1733
Stream water temperature plays a significant role in aquatic ecosystems where it controls many important biological and physical processes. Reliable estimates of water temperature at the daily time step are critical in managing water resources. We developed a parsimonious piecewise Bayesian model for estimating daily stream water temperatures that account for temporal autocorrelation and both linear and nonlinear relationships with air temperature and discharge. The model was tested at 8 climatically different basins of the USA and at 34 sites within the mountainous Boise River Basin (Idaho, USA). The results show that the proposed model is robust with an average root mean square error of 1.25 °C and Nash–Sutcliffe coefficient of 0.92 over a 2‐year period. Our approach can be used to predict historic daily stream water temperatures in any location using observed daily stream temperature and regional air temperature data. 相似文献