The influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes in pyrolysates of selected terrestrial kerogens

Expulsion of petroleum from source rock is a complex part of the entire migration process. There exist fractional effects on chemical compositions in hydrocarbon expulsion. Does the carbon isotopic fractionation occur during expulsion and to what extent? Here the influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes from pyrolysates of selected terrestrial kerogens from Tuha basin and Fushun, Liaoning Province of China has been experimentally studied. The pyrogeneration-expulsion experiments were carried out under semi-closed system. The carbon isotopic compositions of individual n-alkanes were measured by GC-IRMS. The main conclusions are as follows. First, there is carbon isotopic fractionation associated with hydrocarbon expulsion from Type III kerogens in Tuha Basin. There exist differences of carbon isotopic compositions between the unexpelled n-alkanes and expelled n-alkanes from Tuha desmocollinite and Tuha mudstone. Second, there is almost no carbon isotopic fractionation associated with hydrocarbon expulsion from Type II kerogens in Fushun and Liaohe Basin. Third, carbon isotopic fractionation in hydrocarbon expulsion should be considered in making oil-source correlation of Type III kerogens at least in the Tuha Basin. Further studies need to be carried out to determine whether this is true in other basins. Fourth, oil and source at different maturity levels cannot be correlated directly for Type III kerogens since the carbon isotopic compositions of expelled hydrocarbons at different temperatures are different. The expelled hydrocarbons are usually lighter (depleted in ¹³C) than the hydrocarbons remaining in the source rock at the same maturity.     

关于生命起源研究的问题及其主攻方向的探讨

本文综述和分析了近几十年来国内外关于生命起源的研究的问题及各种假说和见解，提出物质的起源是生命起源问题研究的核心，生命起源问题应是研究原始地球的非生命物质如何演变成为生命物质的，地球上分子手性的起源是生命起源问题研究的主攻方向，有机分子光学活性百发生在由化学进化转入生物进化这一过渡阶段。     

用相关分析法从红外云图上提取云团平均尺度特征量

用相关分析法从红外云图上提取云团平均尺度这一特征量,考察了云团平均尺度与合地面观测资料所估算的云厚以及实测局地降雨之关系。初步分析表明,所得的云团平均尺度具有明显的天气学意义。     

新疆北部主要金矿床的成矿地球化学特征

主要依据成矿作用方式,基本成矿特点及关键控矿标志等,将新疆北部的主要原生金矿新划分为７个矿床类型,分别是浅成低温热液型金矿、韧性剪切带蚀变岩型金矿、微细粒浸染型金矿、浅成岩－构造蚀变岩型金矿、变质热液型金矿、石英脉型金矿及铜、金伴生型矿床。通过分析比较各矿床类型典型金矿的ＲＥＥ分布型式、其矿石的微量元素含量与分布型式、硫与铅同位素组成及流体包裹体成分等资料,探讨了其成矿地球化学特征。     

中国东部新生代玄武岩中单斜辉石巨晶的主要特征及成因信息

作者通过对我国东部新生代玄武岩中巨晶Cpx的109个样品的化学成分的统计、计算及投影,研究了Cpx巨晶的产状、物性及矿物化学的主要特征,并对其成因信息提出了自己的看法。Cpx巨晶的成分以A1_2O_3、A1~(v1)较高而Ti、Mg'中等为特征。但在“反应边”中,A1_2O_3、Na_2O、A1、A1~(v1)则明显降低。我国巨晶以普通辉石为主,而透辉石、次透辉石及顽透辉石少见。国内不同地区的Cpx巨晶成分也略有不同:华南区巨晶的Wo较高而A1_2O_3较低;华北区Fs、A1_2O_3较高;而东北区En较高而A1_2O_3中等。有关Cpx巨晶的成因信息,作者的观点是:(1)巨晶Cpx是寄主玄武岩浆在上地幔中结晶的产物,而不是地幔解体的捕虏晶。(2)我国巨晶Cpx的结晶温度是1021—1209℃,压力为1.4—3.2GPa,所以,Cpx巨晶的结晶深度为48—104Km。(3)我国东部新生代玄武岩均产于大陆板块内部,以碱性玄武岩成分为主,而拉斑玄武岩较少。     

ON THE VERTICAL DISCRETIZATION OF ATMOSPHERIC MODELS-PART Ⅰ:EXISTING PROBLEMS,DATA PROCESSING AND CHOICE OF VERTICAL COORDINATE AND BASIS FUNCTIONS

Discussions are carried out on the vertical discretization of current atmospheric models.It is pointed out that there exist problems in the integration of the hydrostatic equation and the computation of vertical advection,vertical diffusion and so on.Then some possible ways for solving or alleviating them are suggested.Finally,the choice of vertical coordinate and basis functions is discussed.     

影响广播中波转播站防雷系统作用的几个关键技术

电台中波转播站多建于城市近郊区,由于天线高耸落雷几率高,因而易受雷击干扰。针对建站时原已通过防雷验收的转播站设施在投入使用后依然频遭雷击受损的状况,分析了其防雷系统的内在布设技术问题,认为广播中波转播站原有防雷系统的一些关键技术缺漏是遭雷击受损的主要原因,并从转播站的实际情况出发,提出了转播站防雷设计的几个关键技术问题的解决方法：接地网逐级分流、屏蔽馈线再加设外屏蔽环群技术以及不同的线路、不同系统保护的配合方法等,从而形成广播转播站完整的防雷保护系统框架。     

常德地区洪涝灾害加剧原因分析

利用沅水、澧水流域近５０年气象、水文、地理等方面的资料,分析了常德地区洪涝灾害的时空分布,着重探讨了９０年代洪涝灾害加剧的原因。     

一个全球变网格多层原始方程差分模式的设计

文章设计了一个以均匀网格差分模式为基础的全球变网格多层原始方程差分模式。还证明了如果前者满足了一定条件,从而具有质量与能量守恒性质以及与连续情况一致的动能、位能和表面位能之间的转换关系,则变网格模式也同样具有。而且,把前者改变为后者增加的运算量很小,也非常方便。