Global nature of the Paleoproterozoic Lomagundi carbon isotope excursion: A review of occurrences in Brazil,India, and Uruguay

Positive carbon isotope excursion is reported from Paleoproterozoic carbonates of the Aravalli Supergroup (northwestern India), the Minas Supergroup (Brazil), and new sections of the Paso Severino Formation (Uruguay). The 2.42 Ga Gandarela Formation, Minas Gerais, Brazil, contains red carbonate-facies BIF grading into dolostones and limestones and yielding δ¹³C values ranging from −1.6 to +0.4‰ V-PDB. The positive C-isotope excursion (up to + 11‰ V-PDB) in marine shallow-water carbonates in India and Brazil (Jhamarkotra Formation in northwestern India, and Cercadinho and Fecho do Funil formations in Minas Gerais State, Brazil) is comparable to that observed in 2.22–2.1 Ga carbonate successions worldwide that were deposited during the Lomagundi excursion. In Uruguay, δ¹³C values up to +11.6‰ V-PDB in the deep-water Paso Severino Formation of the Piedra Alta Terrane are compatible with deposition at ca. 2.15 Ga, as indicated by the 2146 ± 7 Ma U–Pb age of dacites occurring at the top of the unit. Negative δ¹³C values are also present in carbonates of the Paso Severino Formation, but an origin related to organic-matter remineralization cannot be ruled out. Thin carbonate beds in the Rio Itapicuru greenstone belt, Bahia State, Brazil, are associated, as in the Paso Severino Formation, with deep-water black shales and have carbon isotope values up to +9‰ V-PDB. High metamorphic grade carbonates of the Jacurici terrane in the Medrado-Ipueira area, Bahia, Brazil, have carbon isotope values up to +6.9‰ V-PDB, consistent with their minimum age of 2085 ± 5 Ma inferred from the intrusive contact with and the age of the Medrado norite. No evidence was found in India, Brazil, or Uruguay for Paleoproterozoic glacial events recognized in the 2.45–2.22 Ga sedimentary successions worldwide. Unconformities between the Gandarela and Cercadinho formations in Brazil and the banded gneissic Complex and the Lower Aravalli Supergroup in India might explain the absence of glacial record. Compositional and isotopic data presented here for studied Paleoproterozoic carbonate successions allow their integration into the global record of the Paleoproterozoic evolution as well as correlation with other successions of similar age. The study highlights the global nature of the Lomagundi excursion. Furthermore, it indicates that the Lomagundi excursion is recorded in both shallow-water (Aravalli and Minas supergroups) and deep-water carbonates (Paso Severino Formation and Rio Itapicuru greenstone belt) negating a significant impact of stromatolite productivity and hypersaline conditions on carbon isotope values of carbonates deposited in shallow-water, open-marine and isolated basins.     

Bioaccumulation and biomarker responses of trace metals and micro-organic pollutants in mussels and fish from the Lagoon of Venice, Italy

The aims of this study were to evaluate levels and effects of trace metals (Cd, Cr, Cu, Fe, Mn, Pb, Zn), PAHs and PCBs in mussels and fish native to the Lagoon of Venice. To this end, bioaccumulation and various biomarkers of generic stress and exposure (malondialdehyde, MDA and metallothioneins, MT; ethoxyresorufin O-deethylase activity, EROD; fluorescent bile metabolites and somatic indices in fish; lysosomal membrane stability, LMS; lipofuscins, LF; neutral lipids, NL and survival-in-air, SOS in mussels) were measured in organisms seasonally collected from two differently influenced areas. In mussels, metal bioaccumulation levels at the two sites were low and fluctuated similarly, exhibiting decreasing levels in summer, like MDA and MT. Micro-organic pollutants and the probably related biological response of LMS did not show either significant site differences or seasonal trends. LF and NL revealed inconclusive patterns. The results of the survival-in-air test were quite erratic, showing that they were associated with the high variability of both natural and physiological parameters temperature, food, reproduction, and body reserve cycle. In fish, both inorganic and organic micropollutant levels were low, and differences were detected between sites only for PCBs. The pattern exhibited by micro-organic contaminants was clearly related to the reproductive cycle at both sites; a relationship with PCBs, EROD and MDA was established at the site where their levels were generally higher. Bile metabolites (3-OH benzo(a)pyrene, 1-OH pyrene) were associated with PAH contents.     

Série du marégraphe de Marseille : mesures de températures de surface de la mer de 1895 à 1956 : une correction

In 2007, a daily temperature series, which has been collected from 1885 to 1967 at the Marseilles tide recorder, was published here. Upon the available information provided by the data managing office, they were considered as sea-surface temperatures. Unfortunately they were not but air temperature inside the building. In the present paper, the authors correct this error by studying the true seawater temperature series which had been dug out after the publication of the precedent paper. The study of this slightly shorter series (1895–1956) leads to close conclusions. Along these 61 years, the warming trend of the surface seawater rises to +1.6 °C, to +1.3 °C if only January to May and December are selected and +2.2 °C during the June to November period. In the first half part of the series (1895–1925), the average value of each month distributions (except January) and annual minimal (except 1956) are significantly lower than along the second (1925–1956).     

Testing the Ep,i–Lp,iso–T0.45 correlation on a BeppoSAX and Swift sample of gamma-ray bursts

Using a sample of 14 BeppoSAX and 74 Swift GRBs with measured redshift we tested the correlation between the intrinsic peak energy of the time-integrated spectrum,   E _{p, i}   , the isotropic-equivalent peak luminosity,   L _p,iso  , and the duration of the most intense parts of the GRB computed as T _0.45 ('Firmani correlation'). For 41 out of 88 GRBs we could estimate all of the three required properties. Apart from 980425, which appears to be a definite outlier and notoriously peculiar in many respects, we used 40 GRBs to fit the correlation with the maximum likelihood method discussed by D'Agostini, suitable to account for the extrinsic scatter in addition to the intrinsic uncertainties affecting every single GRB. We confirm the correlation. However, unlike the results by Firmani et al., we found that the correlation does have a logarithmic scatter comparable with that of the   E _{p, i} – E _iso  ('Amati') correlation. We also find that the slope of the product   L _p,iso  T _0.45  is equal to ∼0.5, which is consistent with the hypothesis that the   E _{p, i} – L _p,iso– T _0.45  correlation is equivalent to the   E _{p, i} – E _iso  correlation (slope ∼0.5). We conclude that, based on presently available data, there is no clear evidence that the   E _{p, i} – L _p,iso– T _0.45  correlation is different (both in terms of slope and dispersion) from the   E _{p, i} – E _iso  correlation.     

Investigation of Shuttle Radar Topography Mission data of the possible impact structure at Serra da Cangalha,Brazil

Abstract— The Serra da Cangalha crater structure in northeast Brazil, ?13 km in diameter, has long been widely considered to be a confirmed impact structure, based on reports of shatter cone findings. Only very limited field work has been carried out at this crater structure. Landsat Thematic Mapper (TM) and Shuttle Radar Topography Mission (SRTM) data sets for the region around this crater structure are compared here with regard to their suitability to determine first‐order structural detail of impact crater structures. The SRTM data provide very detailed information regarding drainage patterns and topography. A pronounced central ring of up to 300 m elevation above the surrounding area, two comparatively subdued intermediate rings of 6 and 10.5 km diameter, respectively, and the broad, complex crater rim of up to >100 m elevation can be distinguished in the Serra da Cangalha data. The maximum cratering‐related regional deformation (radial and concentric features) seems to be limited to a radial distance of 16–18 km from the center of the structure. A first comparison of macrostructural information from several impact structures with that from Serra da Cangalha does not yield firm trends, but the database is still very small at this stage. The varied nature of the target geology strongly influences the development of structural features in any impact event.     

The Sustainable Pumping Rate Concept: Lessons from a Case Study in Central Italy

The term sustainable pumping rate (SPR) is defined as the maximum pumping rate that can be maintained indefinitely without mining an aquifer, and is different from the concept of safe yield (SY), which takes into account also aspects related to the much wider concept of sustainability. The assessment of the SPR for the case study of Petrignano d'Assisi, an alluvial aquifer located in Central Italy, shows the need for a reliable estimate of the global water budget of the aquifer, particularly of the recharge under undisturbed conditions; however, the latter is not sufficient, because the SPR is affected also by the geometry of the aquifer, the hydraulic conductivity pattern, the variation of recharge/discharge ratio induced by the abstractions, and so on. All these aspects are analyzed by means of a numerical flow model calibrated both under undisturbed conditions (1974) and under exploitation conditions (1998 to 2004). The steady-state modeling results show that the relation between recharge and abstractions both at local and global scale is a key point in order to estimate a long-term SPR. Moreover, as it could be necessary to overexploit the aquifer for short periods, e.g., during drought episodes, the estimate of SPR must be performed also in transient conditions, in order to take into account the characteristic time of depletion and the successive recovery.