Low pressure mineral-melt equilibria in natural anhydrous mafic systems

Contributions to Mineralogy and Petrology - Low pressure phase equilibria for natural mafic systems may be calculated utilizing empirically derived single component distribution coefficients and...     

Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps

High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist. Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore, the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle.     

Miocene shallow-water limestones from São Nicolau (Cabo Verde): Caribbean-type benthic fauna and time constraints for volcanism

Shallow-water limestones of presumed Late Cretaceous and Eocene age, interbedded with basaltic lavas, were described by earlier authors from São Nicolau in the northwestern part of the Cabo Verde archipelago. If confirmed, these ages would imply late Mesozoic shallow-marine and subaerial volcanic activity in the Cabo Verde archipelago, and document a geological history very different from that known so far from other Cabo Verde Islands, from which no subaerial volcanic activity before the mid-Cenozoic is known. Our re-investigation of the foraminiferal fauna indicates a Late Miocene age for the presumed Late Cretaceous and Eocene limestones. The hypothesis of a long-lived hot spot, active by the Early Cretaceous, and of a major island-building stage in the Cabo Verde Islands during this period, is therefore not supported by the present bio- or chronostratigraphic data.     

Potential impacts of aerosol–land–atmosphere interactions on the Indian monsoonal rainfall characteristics

Aerosols can affect the cloud-radiation feedback and the precipitation over the Indian monsoon region. In this paper, we propose that another pathway by which aerosols can modulate the multi-scale aspect of Indian monsoons is by altering the land–atmosphere interactions. The nonlinear feedbacks due to aerosol/diffuse radiation on coupled interactions over the Indian monsoon region are studied by: (1) reviewing recent field measurements and modeling studies, (2) analyzing the MODIS and AERONET aerosol optical depth datasets, and (3) diagnosing the results from sensitivity experiments using a mesoscale modeling system. The results of this study suggest that the large magnitude of aerosol loading and its impact on land–atmosphere interactions can significantly influence the mesoscale monsoonal characteristics in the Indo-Ganges Basin.     

Uranium depositional controls at the Prairie Flats surficial uranium deposit, Summerland, British Columbia

A hydrological and geochemical investigation of the Prairie Flats surficial uranium deposit in Summerland, BC was undertaken to identify the principal controls on uranium deposition. A network of piezometers was installed and used to measure the hydraulic conductivities of the host sediments as well as the general flow direction and aqueous geochemistry of the resident groundwaters. Two hydrostratigraphic units were identified: a peat and clay unit overlying a sand and gravel unit. Measured hydraulic conductivities were on the order of 10^-7 and 10^-5 m/s, respectively, and the vertical hydraulic gradients indicate significant groundwater discharge upward into the peat and clay unit. Prairie Flats groundwaters are neutral to alkaline in pH, enriched in Ca²⁺ and HCO₃^-, and have dissolved uranium concentrations ranging from 10 to nearly 1,000 µg/l. Groundwater flow and geochemistry data were used to estimate the flux of uranium in groundwater at the site. A major fraction of the uranium is taken up by adsorption to organics. There is also evidence for subsequent desorption by the formation of soluble complexes with bicarbonate. Uranium that is not held by adsorption is most likely precipitated as uraninite, UO_2(c). Reducing conditions in the peat and clay unit (Eh<0.1 V) relative to the underlying sand and gravel unit (Eh>0.2 V) may explain the high concentrations of uranium nearer ground surface. The current flux of uranium into the flats is significantly smaller than that calculated from the size and age of the deposit, which may be an indication of changing rates of deposition in response to varying climatic and hydrogeologic conditions over time.     

The initial cooling of pahoehoe flow lobes

 In this paper we describe a new thermal model for the initial cooling of pahoehoe lava flows. The accurate modeling of this initial cooling is important for understanding the formation of the distinctive surface textures on pahoehoe lava flows as well as being the first step in modeling such key pahoehoe emplacement processes as lava flow inflation and lava tube formation. This model is constructed from the physical phenomena observed to control the initial cooling of pahoehoe flows and is not an empirical fit to field data. We find that the only significant processes are (a) heat loss by thermal radiation, (b) heat loss by atmospheric convection, (c) heat transport within the flow by conduction with temperature and porosity-dependent thermal properties, and (d) the release of latent heat during crystallization. The numerical model is better able to reproduce field measurements made in Hawai'i between 1989 and 1993 than other published thermal models. By adjusting one parameter at a time, the effect of each of the input parameters on the cooling rate was determined. We show that: (a) the surfaces of porous flows cool more quickly than the surfaces of dense flows, (b) the surface cooling is very sensitive to the efficiency of atmospheric convective cooling, and (c) changes in the glass forming tendency of the lava may have observable petrographic and thermal signatures. These model results provide a quantitative explanation for the recently observed relationship between the surface cooling rate of pahoehoe lobes and the porosity of those lobes (Jones 1992, 1993). The predicted sensitivity of cooling to atmospheric convection suggests a simple field experiment for verification, and the model provides a tool to begin studies of the dynamic crystallization of real lavas. Future versions of the model can also be made applicable to extraterrestrial, submarine, silicic, and pyroclastic flows. Received: 26 November 1994 / Accepted: 1 December 1995     

Subsurface DC resistivity mapping: approximate 1-D interpretation

Resistivity prospecting is the main tool used to investigate the shallow structure of the ground. A series of new techniques for determining the 2-D and 3-D geometry of the ground is now finding increasing use, but the light and simple Wenner prospecting technique remains a practical and efficient tool for rapidly mapping lateral variations in resistivity. When the resistivity changes are smooth, 1-D modelling can be used to interpret the data, and the criteria governing this approximation can be defined from synthetic data generated by a 3-D slab-model. For a Wenner array, two quadripole configurations can be used, Normal and Dipole-Dipole. For these two configurations the width of the transition zone, the apparent anisotropy effect and the precision of the resistivity values recovered from 1-D inversion differ. However the simultaneous inversion of both sets of data gives better results than for either configuration by itself. Two examples illustrate that in geological contexts where the thickness of the weathered zone causes the changes in the apparent resistivity value, this parameter can be recovered from 1-D inversion.     

Bed load transport during rising and falling stages on two small streams

Bed load transport rates were measured with continuously recording pit samplers on two small gravel-bed streams in the Goodwin Creek Research Watershed, northern Mississippi, U.S.A. When transport samples were grouped according to whether the stage was rising or falling, significant differences in mean bed load transport rates were found at nearly all flow strengths. At higher flow strengths, mean bed load transport rates were greater during rising stages than during falling stages. The greater transport rates measured during rising stages may be caused by a lag in the formation and destruction of bed roughness elements. One of the streams also showed evidence for greater transport rates for low flows as the stage declined. This may be caused by differences in the stability of the bed material at the beginning and at the end of a transport event.     

Experimentally determined mineral-melt partition coefficients for Sc,Y and REE for olivine,orthopyroxene, pigeonite,magnetite and ilmenite

Our current lack of understanding of the partitioning behavior of Sc, Y and the REE (rare-earth elements) can be attributed directly to the lack of a sufficiently large or chemically diverse experimental data set. To address this problem, we conducted a series of experiments using several different natural composition lavas, doped with the elements of interest, as starting compositions. Microprobe analyses of orthopyroxene, pigeonite, olivine, magnetite, ilmenite and co-existing glasses in the experimental charges were used to calculate expressions that describe REE partitioning as a function of a variety of system parameters. Using expressions that represent mineral-melt reactions (versus element ratio distribution coefficients) it is possible to calculate terms that express low-Ca pyroxene-melt partitioning behavior and are independent of both pyroxene and melt composition. Compositional variations suggest that Sc substitution in olivine involves either a paired substitution with Al or, more commonly, with vacancies. The partitioning of Sc is dependent both on melt composition and temperature. Our experimentally determined olivine-melt REE Ds (partition coefficients) are similar to, but slightly higher than those reported by McKay (1986) and support their conclusions that olivines are strongly LREE depleted. Y and REE mineral/melt partition coefficients for magnetite range from 0.003 for La to 0.02 for Lu. Ilmenite partition coefficients range from 0.007 for La to 0.029 for Lu. These experimental values are two orders of magnitude lower than many of the published values determined by phenocryst/matrix separation techniques.