Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

Implementation of a surface runoff model with Horton and Dunne mechanisms into the regional climate model RegCM_NCC

A surface runoff parameterization scheme that dynamically represents both Horton and Dunne runoff generation mechanisms within a model grid cell together with a consideration of the subgrid-scaie soil heterogeneity, is implemented into the National Climate Center regional climate model （RegCM_NCC）. The effects of the modified surface runoff scheme on RegCMANCC performance are tested with an abnormal heavy rainfall process which occurred in summer 1998. Simulated results show that the model with the original surface runoff scheme （noted as CTL） basically captures the spatial pattern of precipitation, circulation and land surface variables, but generally overestimates rainfall compared to observations. The model with the new surface runoff scheme （noted as NRM） reasonably reproduces the distribution pattern of various variables and effectively diminishes the excessive precipitation in the CTL. The processes involved in the improvement of NRM-simulated rainfall may be as follows： with the new surface runoff scheme, simulated surface runoff is larger, soil moisture and evaporation （latent heat flux） are decreased, the available water into the atmosphere is decreased; correspondingly, the atmosphere is drier and rainfall is decreased through various processes. Therefore, the implementation of the new runoff scheme into the RegCMANCC has a significant effect on results at not only the land surface, but also the overlying atmosphere.     

Adaptation of Pressure Based CFD Solvers for Mesoscale Atmospheric Problems

General purpose Computational Fluid Dynamics (CFD) solvers are frequently used in small-scale urban pollution dispersion simulations without a large extent of ver- tical flow. Vertical flow, however, plays an important role in the formation of local breezes, such as urban heat island induced breezes that have great significance in the ventilation of large cities. The effects of atmospheric stratification, anelasticity and Coriolis force must be taken into account in such simulations. We introduce a general method for adapting pressure based CFD solvers to atmospheric flow simulations in order to take advantage of their high flexibility in geometrical modelling and meshing. Compressibility and thermal stratification effects are taken into account by utilizing a novel system of transformations of the field variables and by adding consequential source terms to the model equations of incompressible flow. Phenomena involving mesoscale to microscale coupled effects can be analyzed without model nesting, applying only local grid refinement of an arbitrary level. Elements of the method are validated against an analytical solution, results of a reference calculation, and a laboratory scale urban heat island circulation experiment. The new approach can be applied with benefits to several areas of application. Inclusion of the moisture transport phenomena and the surface energy balance are important further steps towards the practical application of the method.     

Principal Components Analysis of Rainfall and Associated Synoptic Models of the Southwest Monsoon over India

Summary  The summer monsoon circulation shows various spatial and temporal oscillations and often a combination of systems produces an integrated effect. In this study phases of the southwest (SW) monsoon have been identified in an objective manner with the help of T-mode principal component analysis (PCA) of weekly rainfall anomalies. Mean composite charts have been prepared utilising all available upper air data (1977–1986) for each category of the SW monsoon epochs identified by the PCA. These sets of charts have been constructed for both the strong and weak phases associated with the first four significant principal components (PCs). A well defined east-west oriented trough system, extending from about 28° N Latitude/65° E Longitude to 20° N Latitude/90° E Longitude, in the lower levels, has been the main feature associated with the strong phase of the monsoon corresponding to PC I. The trough in the lower levels is more marked in the eastern half compared to the western half in both the sets of charts associated with strong phases of the monsoon related to the PC II and PC III. With PC II, the position of the troughs in the lower levels is further north of its location in PC III. The east-west trough system associated with the strong phase of PC IV has a large southward tilt with height. The charts corresponding to the weak phases of these PCs have synoptic features, such as the position of the trough close to the foothills of the Himalayas, and the shifting of middle and upper tropospheric anticyclones to the south. The study suggests an objective method of interpretation of principal components by utilising synoptic data. In addition, synoptic models and data sets corresponding to different phases of the monsoon can also be prepared in an objective manner by such PCA. Received July 18, 1997 Revised April 30, 1999     

Vertical and Horizontal Transport of Energy and Matter by Coherent Motions in a Tall Spruce Canopy

In the framework of the EGER (ExchanGE processes in mountainous Regions) project, the contribution of coherent structures to vertical and horizontal transports in a tall spruce canopy is investigated. The combination of measurements done in both the vertical and horizontal directions allows us to investigate coherent structures, their temporal scales, their role in flux transport, vertical coupling between the sub-canopy, canopy and air above the canopy, and horizontal coupling in the sub-canopy layer. The temporal scales of coherent structures detected with the horizontally distributed systems in the sub-canopy layer are larger than the temporal scales of coherent structures detected with the vertically distributed systems. The flux contribution of coherent structures to the momentum and sensible heat transport is found to be dominant in the canopy layer. Carbon dioxide and latent heat transport by coherent structures increase with height and reach a maximum at the canopy height. The flux contribution of the ejection decreases with increasing height and becomes dominant above the canopy level. The flux fraction transported during the sweep increases with height and becomes the dominant exchange process at the upper canopy level. The determined exchange regimes indicate consistent decoupling between the sub-canopy, canopy and air above the canopy during evening, nighttime and morning hours, whereas the coupled states and coupled by sweep states between layers are observed mostly during the daytime. Furthermore, the horizontal transport of sensible heat by coherent structures is investigated, and the heterogeneity of the contribution of coherent events to the flux transport is demonstrated. A scheme to determine the horizontal coupling by coherent structures in the sub-canopy layer is proposed, and it is shown that the sub-canopy layer is horizontally coupled mainly in the wind direction. The vertical coupling in most cases is observed together with streamwise horizontal coupling, whereas the cross-stream direction is decoupled.     

The Space and Time Variations of Water Quality and Water Pollution Dynamics in the Oka Basin

Water Resources - The space–time variations in the Oka basin water chemistry have been considered. The specific features in the river water and groundwater pollution along the Oka channel and...     

Artificial Neural Network as a Tool for Backbreak Prediction

Backbreak is one of the destructive side effects of the blasting operation. Reducing of this event is very important for economic of a mining project. Involvement of various parameters has made the backbreak analyzing difficult. Currently there is no any specific method to predict or control the phenomenon considering all the effective parameters. In this paper, artificial neural network (ANN) as a powerful tool for solving such complicated problems is used to predict backbreak in blasting operation of the Sangan iron mine, Iran. Network training was fulfilled using a collected database of the practiced operation including blast design details and rock condition. Trying various types of the networks, a network with two hidden layers was found to be optimum. Performance of the ANN model was compared with statistical analysis using datasets which were kept apart from the original database. According to the obtained results, for the ANN model there existed a higher correlation (R² = 0.868) and lesser error (RMSE = 0.495) between the predicted and measured backbreak as compared to the regression model. Also, sensitivity analysis revealed that the inputs rock factor and number of rows are the most and the least sensitive parameters on the output backbreak, respectively.     

Oxygen and nutrient dynamics within mats of the filamentous macroalga Chaetomorpha linum

Concentration profiles of O₂, NH₄ ⁺, NO₃ ⁻, and PO₄ ³⁻ were measured at high spatial resolution in a 12-cm thick benthic mat of the filamentous macroalga Chaetomorpha linum. Oxygen and nutrient concentration profiles varied depending on algal activity and water turbulence. High surface irradiance stimulated O₂ production in the surface layers and introduced O₂ to deeper parts of the mat while the bottom layers of the mat and the underlying sediment were anoxic. Nutrient concentrations were highest in the bottom layers of the mat directly above the sediment nutrient source and decreased towards the surface layers due to algal assimilation and enhanced mixing with the overlying water column. Increased turbulence during windy periods resulted in more homogeneous oxygen and nutrient concentration profiles and shifted the oxic-anoxic interface downward. Denitrification within the mat, as measured by the isotope pairing technique on addition of ¹⁵NO₃ ⁻, was found to take place directly below the oxic-anoxic interface. Denitrification activity was always due to coupled nitrification-denitrification, whereby nitrifiers in the mat utilize NH₄ ⁺ diffusing from below and O₂ diffusing from above. The denitrification rate in the mat ranged from 22 μmol m⁻² h⁻¹ to 28 μmol m⁻² h⁻¹, approximately equivalent to that measured in the surrounding nonvegetated sediment. Although sediment denitrification is suppressed when the sediment surface is covered by a dense macroalgal mat, the denitrification zone may migrate up into the mat. In eutrophic estuaries with a large area of macroalgal cover, the physical structure and growth stage of algal mats may thus play an important role in the regulation of nitrogen removal by denitrification.     

Evolution of Ore-Forming Fluids and Ag-Cu Polymetal Mineralization in the Lanping Basin, Yunnan

EVOLUTION OF ORE-FORMING FLUIDS AND Ag-Cu POLYMETAL MINERALIZATION IN THE LANPING BASIN, YUNNAN“KeyProjectforResourcesandEconomics” (95 0 2 0 0 1 0 1)oftheMinistryofLandResources     

Structural improvement of age-hardened gypsum-treated bauxite red mud waste using readily decomposable phyto-organics

Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely, it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and ineffective.