Reaction mechanism for the replacement of calcite by dolomite and siderite: implications for geochemistry, microstructure and porosity evolution during hydrothermal mineralisation

Carbonate reactions are common in mineral deposits due to CO₂-rich mineralising fluids. This study presents the first in-depth, integrated analysis of microstructure and microchemistry of fluid-mediated carbonate reaction textures at hydrothermal conditions. In doing so, we describe the mechanisms by which carbonate phases replace one another, and the implications for the evolution of geochemistry, rock microstructures and porosity. The sample from the 1.95 Moz Junction gold deposit, Western Australia, contains calcite derived from carbonation of a metamorphic amphibole—plagioclase assemblage that has further altered to siderite and dolomite. The calcite is porous and contains iron-rich calcite blebs interpreted to have resulted from fluid-mediated replacement of compositionally heterogeneous amphiboles. The siderite is polycrystalline but nucleates topotactically on the calcite. As a result, the boundaries between adjacent grains are low-angle boundaries (<10°), which are geometrically similar to those formed by crystal–plastic deformation and recovery. Growth zoning within individual siderite grains shows that the low-angle boundaries are growth features and not due to deformation. Low-angle boundaries develop due to the propagation of defects at grain faces and zone boundaries and by impingement of grains that nucleated with small misorientations relative to each other during grain growth. The cores of siderite grains are aligned with the twin planes in the parent calcite crystal showing that the reactant Fe entered the crystal along the twin boundaries. Dolomite grains, many of which appear to in-fill space generated by the siderite replacement, also show alignment of cores along the calcite twin planes, suggesting that they did not grow into space but replaced the calcite. Where dolomite is seen directly replacing calcite, it nucleates on the Fe-rich calcite due to the increased compatibility of the Fe-bearing calcite lattice relative to the pure calcite. Both reactions are interpreted as fluid-mediated replacement reactions which use the crystallography and elemental chemistry of the calcite. Experiments of fluid-mediated replacement reactions show that they proceed much faster than diffusion-based reactions. This is important when considering the rates of reactions relative to fluid flow in mineralising systems.     

A digitized global flood inventory (1998–2008): compilation and preliminary results

Floods have profound impacts on populations worldwide in terms of both loss of life and property. A global inventory of floods is an important tool for quantifying the spatial and temporal distribution of floods and for evaluating global flood prediction models. Several global hazard inventories currently exist; however, their utility for spatiotemporal analysis of global floods is limited. The existing flood catalogs either fail to record the geospatial area over which the flood impacted or restrict the types of flood events included in the database according to a set of criteria, limiting the scope of the inventory. To improve upon existing databases, and make it more comprehensive, we have compiled a digitized Global Flood Inventory (GFI) for the period 1998–2008 which also geo-references each flood event by latitude and longitude. This technical report presents the methodology used to compile the GFI and preliminary findings on the spatial and temporal distributions of the flooding events that are contained in the inventory.     

Lu–Hf geochronology and trace element distribution in garnet: Implications for uplift and exhumation of ultra-high pressure granulites in the Sudetes, SW Poland

Combining Lu–Hf garnet geochronology with in situ trace element analyses in garnet allowed us to gain new insight into the metamorphic evolution of UHP–UHT rocks in the Stary Gierałtów region, in the Polish Sudetes. Prograde garnet growth recorded by Rayleigh-type heavy REE (HREE) zoning in the felsic granulites indicates that the obtained 386.6 ± 4.9 Ma Lu–Hf age represents the time of garnet crystallization on a prograde UHP metamorphic path. The surrounding rocks were metamorphosed at the same time as indicated by 381.2 ± 6.7 Ma Sm–Nd garnet age obtained for the mid-crustal metapelites. The second metamorphic episode, which affected most of the lower crust in the Orlica–Śnieżnik Massif (OSM) occurred at ca. 340 Ma as determined by U–Pb zircon and Sm–Nd garnet dating of granulites in this and previous studies is interpreted as a high temperature event, which took place on a retrograde path.

Trace element distribution in garnets from the layered granulites showed significant differences in distribution of medium and HREE in garnets from mafic and felsic protoliths over the course of the metamorphic evolution. This had strong impact on the isotopic dating results and led to “decoupling” of the Sm–Nd and Lu–Hf clocks, which recorded timing of the two different metamorphic episodes separated by as much as 40 Ma. Moreover, the preservation of the HREE growth zonation profile in garnets from the felsic granulites whose minimum metamorphic temperature was established at 900 °C implies that the Lu–Hf system under relatively dry conditions does not undergo significant diffusional re-equilibration even at such extreme temperatures and therefore it sill provides the age of prograde garnet growth. Under hydrous conditions, at least some resetting will take place, as documented by the partially relaxed HREE zonation profile in the amphibolitised mafic granulite, which yielded a 10 Ma younger age. The HREE distribution study appeared to be a particularly valuable and essential tool, which allowed us to distinguish garnet growth from post-growth complexities and hence, provide improved age interpretation. Medium REE, on the other hand, did not show any obvious correlation with the isotopic signature of garnet.

Two distinct metamorphic episodes recorded in the Stary Gierałtów region show that buoyancy-driven uplift of UHP rocks can be arrested at the base of a continental crust if not supported by any additional force. In our case study, the UHP rocks would have never reached the surface if their uplift had not been resumed after a long pause under a different tectonic regime. The multistage, discontinuous uplift revealed by the UHP rocks of the OSM provides a new scenario for the exhumation of continental crust from mantle depths distinct from the fast-track exhumation histories recognized in UHP terranes elsewhere.     

Calorimetric study of the coesite-stishovite transformation and calculation of the phase boundary

High temperature drop-solution calorimetry in molten 2 PbO · B₂O₃ at 1044 K for coesite and stishovite polymorphs of silica was carried out to determine the enthalpy of the coesite-stishovite transition. These experiments were performed on high-purity, single-phase samples of coesite and stishovite. Our new value for the enthalpy of the coesitestishovite transition (ΔH ₂₉₈ ⁰ ) is 29.85 ± 0.78 kJ/mol, which is about 35% lower than previously reported by Akaogi and Navrotsky (1984) and Holm et al. (1967), but which compares well with new measurements by Akaogi et al. (1994b). Using these new data, we have calculated the equilibrium phase boundary between coesite and stishovite and obtained a slope, dP/dT=0.0031 (2) GPa/K. This calculated slope is in good agreement with that determined [0.0026 (2) GPa/K] from the in-situ X-ray diffraction study of Zhang et al. (1996).     

全球灾害系统(GHS)在地质灾害预测预报中的简介

洪水和滑坡是两种典型的地质灾害。针对这两种地质灾害的预报预测,本文简介了全球灾害系统(GHS)及一些应用。基于遥感和预测模型集成的全球洪水和滑坡灾害的解决思路,笔者采用美国宇航局(NASA)集成的准实时卫星降雨的洪水模型和滑坡模型,初步开发成全球灾害系统(GHS)对相关地区进行研究。通过在洪都拉斯、印度尼西亚、中国汶川等实例研究,表明GHS在在大型洪水的时间和强度上具有较好的预测能力,同时,能较精确地预报出滑坡发生的时间和范围。最后本文提出该系统在福建省应用的展望。     

MIL 03443, a dunite from asteroid 4 Vesta: Evidence for its classification and cumulate origin

Abstract– The absence of dunite (>90 vol% olivine) in the howardite, eucrite, and diogenite (HED) meteorite suite, when viewed with respect to spectroscopic and petrologic evidence for olivine on Vesta, is problematic. Herein, we present petrologic, geochemical, and isotopic evidence confirming that Miller Range (MIL) 03443, containing 91 vol% olivine, should be classified with the HED clan rather than with mesosiderites. Similarities in olivine and pyroxene FeO/MnO ratios, mineral compositions, and unusual mineral inclusions between MIL 03443 and the diogenites support their formation on a common parent body. This hypothesis is bolstered by oxygen isotopic and bulk geochemical data. Beyond evidence for its reclassification, we present observations and interpretations that MIL 03443 is probably a crustal cumulate rock like the diogenites, rather than a sample of the Vestan mantle.     

Temporal Pointing Variations of the Solar Dynamics Observatory’s HMI and AIA Instruments on Subweekly Time Scales

Achieving subarcsecond co-registration across varying time-lines of multi-wavelength and instrument images is difficult and requires an accurate characterization of the instrument pointing jitter. We investigated the internal pointing errors on daily and yearly time-scales that occur across the Solar Dynamics Observatory’s (SDO) Atmospheric Imaging Assembly (AIA) and Helioseismic Magnetic Imager (HMI). Using cross-correlation techniques on the AIA 1700 Å passband and the HMI line-of-sight magnetograms from three years of observational image pairs at approximately three-day intervals, internal pointing errors were quantified. Pointing variations of ±?0.26″ (jitter-limited) and ±?0.50″ in the solar East–West (x) and North–South (y) directions, respectively, were measured. AIA observations of the Venus transit in June 2012 were used to measure existing coalignment offsets in all passbands. We found that the AIA passband pointing variations are 〈ΔX _CO〉=1.10″±1.41″ and 〈ΔY _CO〉=1.25″±1.24″ when aligned to the HMI nominal image center, referred to here as the CutOut technique. Minimal long-term pointing variations found between limb and correlation derived pointings provide evidence that the image-center positions provided by the instrument teams achieve single-pixel accuracy on time scales shorter than their characterization. However, daily AIA passband pointing variations of ??1.18″ indicate that autonomous subarcsecond co-registration is not fully achieved yet.     

Heat and mass transfer effects during displacement of deepwater methane hydrate to the surface of Lake Baikal

The present paper focuses on heat and mass exchange processes in methane hydrate fragments during in situ displacement from the gas hydrate stability zone (GHSZ) to the water surface of Lake Baikal. After being extracted from the methane hydrate deposit at the lakebed, hydrate fragments were placed into a container with transparent walls and a bottom grid. There were no changes in the hydrate fragments during ascent within the GHSZ. The water temperature in the container remained the same as that of the ambient water (~3.5 °С). However, as soon as the container crossed the upper border of the GHSZ, first signs of hydrate decomposition and transformation into free methane gas were observed. The gas filled the container and displaced water from it. At 300 m depth, the upper and lower thermometers in the container simultaneously recorded noticeable decreases of temperature. The temperature in the upper part of the container decreased to –0.25 °С at about 200 m depth, after which the temperature remained constant until the water surface was reached. The temperature at the bottom of the container reached –0.25 °С at about 100 m depth, after which it did not vary during further ascent. These observed effects could be explained by the formation of a gas phase in the container and an ice layer on the hydrate surface caused by heat consumption during hydrate decomposition (self-preservation effect). However, steady-state simulations suggest that the forming ice layer is too thin to sustain the hydrate internal pressure required to protect the hydrate from decomposition. Thus, the mechanism of self-preservation remains unclear.     

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.