Seasonal and interannual dynamics of free-living bacterioplankton and microbially labile organic carbon along the salinity gradient of the Potomac River

Samples were collected at stations located in the mesohaline, oligohaline, and tidal fresh regions of the Potomac River, Maryland, between April 1998 and December 1999 to evaluate the seasonal distribution of bacterioplankton and microbially labile organic carbon (MLOC) in relation to hydrodynamic parameters (dissolved oxygen, salinity, and temperature). Bacterioplankton abundance (BA) averaged 13 × 10⁶ cells ml⁻¹ at all stations, a value that is higher than the average observed in many other temperate estuaries around the world, and were almost exclusively free-living. During the summer of 1998, BA often exceeded 30 × 10⁶ cells ml⁻¹ in the mesohaline region during periods of anoxia in subpycnocline waters. Dissolved MLOC typically accounted for 40% of total MLOC and on some occasions during summer and autumn accounted for 80%. A significant positive relationship between dissolved MLOC and BA was evident in the mesohaline Potomac River, the region where anoxia occurs each summer, but the regressions of particulate MLOC and chla on BA were not significant at this location. In the mesohaline Potomac River, BA regressed negatively and significantly on dissolved oxygen (r²=0.50, p<0.001). BA may be an important indicator of ecosystem health in this and other eutrophied estuaries, because of the relationships between BA, dissolved MLOC, and dissolved oxygen in the salinity stratified Potomac River and because free-living BA was elevated along the length of the river.     

九龙江河口区表层水铀同位素的粒级分布

利用微滤和超滤技术研究了九龙江河口区表层水中铀及其同位素组成的粒级分布和地球化学行为.结果表明,溶解态(<0.4μm)中低分子量组分(<10 000 u)占主要份额,胶体态(10 000 u~0.4μm)238U所占比例不足1%,且随盐度的增加其所占份额逐渐降低.溶解态、低分子量组分和胶体态238U的比活度与盐度之间存在良好的线性正相关关系,证实它们在九龙江河口区呈现保守行为.在颗粒态(>0.4μm)中,各粒级组分238U所占份额主要受控于相应颗粒物的浓度,在盐度小于20的区域,各粒级颗粒组分238U占颗粒态的份额有如下变化次序:10~53μm>2~10μm>0.4~2μm>大于53μm,而在盐度大于30的近外海站位,该次序发生一些变化:0.4~2μm>10~53μm>2~10μm>大于53μm,最小粒级颗粒组分238U的贡献有所增加,反映了自生铀贡献的加强.九龙江河口区表层水中溶解态(包括低分子量组分和胶体态)的234U/238U)_A.R.均大于1,显示出234U过剩的特征,而各粒级颗粒组分中的234U/238U)_A.R.则接近于平衡值(1.0).这一现象与陆地岩石风化过程中水体对铀的淋滤释出量及234U的优先浸出有关.对232Th/238U质量比的研究显示,溶解态及其所包括的低分子量组分和胶体态的232Th/238U质量比均小于1,而颗粒态及其所包括的4个粒级组分中的232Th/238U质量比均大于1,反映了向外海输送过程中铀、钍地球化学行为的差异.     

In Situ Observations of Solar Wind Stream Interface Evolution

The heliocentric orbits of the two STEREO satellites are similar in radius and ecliptic latitude, with separation in longitude increasing by about 45° per year. This arrangement provides a unique opportunity to study the evolution of stream interfaces near 1 AU over time scales of hours to a few days, much less than the period of a Carrington rotation. Assuming nonevolving solar wind sources that corotate with the Sun, we calculated the expected time and longitude of arrival of stream interfaces at the Ahead observatory based on the in situ solar wind speeds measured at the Behind observatory. We find agreement to within 5° between the expected and actual arrival longitude until the spacecraft are separated by more than 20° in heliocentric inertial longitude. This corresponds to about one day between the measurement times. Much larger deviations, up to 25° in longitude, are observed after 20° separation. Some of the deviations can be explained by a latitude difference between the spacecraft, but other deviations most likely result from evolution of the source region. Both remote and in situ measurements show that changes at the source boundary can occur on a time scale much shorter than one solar rotation. In 32 of 41 cases, the interface was observed earlier than expected at STEREO/Ahead.     

31P solid-state nuclear magnetic resonance spectroscopy of aluminum phosphate minerals

This study examines the links between ³¹P solidstate NMR studies of aluminum phosphate minerals and their crystallographic structures. We found that ³¹P isotropic chemical shift values, _iso, carry little information about mineral structures. There seems to be no relation between the chemical shift anisotropy, =₃₃–₁₁ (₃₃>₂₂> ₁₁), and indicies of phosphate-tetrahedra distortion. ³¹P¹H heteronuclear magnetic dipole interactions, on the other hand, carry important information about hydrous phosphate mineral structures, information that should prove to be quite valuable in studies of phosphate adsorbed on mineral surfaces. This interaction can be measured through a variety of qualitative and quantitative experiments. It appears that spin diffusion is so rapid that subtle differences in hydrogen-bonding environments cannot be resolved.     

Hydrogeochemical modelling of an active system of uranium fixation by organic soils and sediments (Needle's Eye,Scotland)

Uranium accumulation in organic-rich sediments can be closely modelled by assuming that the dominant effect of the uranium-organic matter interaction is the direct or indirect reduction of uranyl compounds to form U(IV) minerals, especially uraninite-pitchblende. Application of this model to the Needle's Eye (Scotland) site where uranium is actively accumulating in Quaternary sediments demonstrates that uranium accumulation is both effective and rapid in environments involving shallow, organic-rich, reducing horizons. The period of uranium deposit formation at Needle's Eye is estimated to be as short as 5000 years. The transport of uranium to the site of deposition by oxidizing groundwaters and the channelling of these oxidizing uraniferous groundwaters are identified as important factors involved in the rapid accumulation of uranium. The regional hydrogeological model indicates that a fault in the area appears to act as a hydraulic screen for the uraniferous groundwaters. On one side of the fault the Quaternary sediments are well drained whilst on the other the flow of groundwater seeps out creating a major flux just at the bottom of the organic-rich layers. The local hydrogeological model shows that the groundwater flow is vertical in this area. A third significant factor in the development of these uranium accumulations is the presence of a significant nearby source of leachable primary uranium. In the case of the Needle's Eye site this is in the form of some thirty 185 ±20 Ma, pitchblende-bearing veins.     

Development of main structures of the siberian platform: history and dynamics

The location of the regions with maximum subsidence within the Siberian platform and the age volumes of the structural stages have been determined in relation to the location and periods of development of the adjacent geosynclines. The western and eastern parts of the platform differ in the character of the structures and magmatism, in the volume and age of the structural stages, as well as in the asynchronism of the main tectonic stages, which is connected with the boundary location of the platform between the Atlantic and Pacific Ocean segments of the earth's crust. The Siberian platform sharply differs from other ancient platforms of the northern hemisphere by the intensity of magmatism and style of tectonic deformation in the Meso-Cenozoic, and it is similar in this respect to the southern ancient platforms. The subcrustal processes in the adjacent geosynclines have played a leading role in the development of the platform structure; but the release of the stresses during the epochs of the magmatism and rift formation took place directly on the platform itself.     

东南极达尔克冰川表面运动速度特征研究

2007-2012年,在东南极达尔克冰川实施了18期空间方向交会观测,解算得到了冰川的运动规律:其整体平均运动速度为0.41 m·d^-1,平均流向的方位角为7.01°;总的来说,其冬季和夏季的流速基本相当,但冰川前缘附近的运动在冬季显得更为活跃;冰川横截面上从边缘到中心,流速逐渐增大,流速最大的点出现在冰川中轴线上,流速最小的点则出现在边界附近;沿冰川流动方向,从上游至入海口,流速亦逐渐增大,冰川前缘流速最大,此处有较多的冰裂缝发育.与之前的遥感研究结果相比较,冰川运动比较稳定,流速未发现显著变化.     

Comparison between geodetic and oceanographic approaches to estimate mean dynamic topography for vertical datum unification: evaluation at Australian tide gauges

The direct method of vertical datum unification requires estimates of the ocean’s mean dynamic topography (MDT) at tide gauges, which can be sourced from either geodetic or oceanographic approaches. To assess the suitability of different types of MDT for this purpose, we evaluate 13 physics-based numerical ocean models and six MDTs computed from observed geodetic and/or ocean data at 32 tide gauges around the Australian coast. We focus on the viability of numerical ocean models for vertical datum unification, classifying the 13 ocean models used as either independent (do not contain assimilated geodetic data) or non-independent (do contain assimilated geodetic data). We find that the independent and non-independent ocean models deliver similar results. Maximum differences among ocean models and geodetic MDTs reach >150 mm at several Australian tide gauges and are considered anomalous at the 99% confidence level. These differences appear to be of geodetic origin, but without additional independent information, or formal error estimates for each model, some of these errors remain inseparable. Our results imply that some ocean models have standard deviations of differences with other MDTs (using geodetic and/or ocean observations) at Australian tide gauges, and with levelling between some Australian tide gauges, of \({\sim }\pm 50\,\hbox {mm}\). This indicates that they should be considered as an alternative to geodetic MDTs for the direct unification of vertical datums. They can also be used as diagnostics for errors in geodetic MDT in coastal zones, but the inseparability problem remains, where the error cannot be discriminated between the geoid model or altimeter-derived mean sea surface.