Size scales over which ordinary chondrites and their parent asteroids are homogeneous in oxidation state and oxygen-isotopic composition

Literature data demonstrate that on a global, asteroid-wide scale (plausibly on the order of 100 km), ordinary chondrites (OC) have heterogeneous oxidation states and O-isotopic compositions (represented, respectively, by the mean olivine Fa and bulk Δ¹⁷O compositions of equilibrated samples). Samples analyzed here include: (a) two H5 chondrite Antarctic finds (ALHA79046 and TIL 82415) that have the same cosmic-ray exposure age (7.6 Ma) and were probably within ∼1 km of each other when they were excavated from the H-chondrite parent body, (b) different individual stones from the Holbrook L/LL6 fall that were probably within ∼1 m of each other when their parent meteoroid penetrated the Earth’s atmosphere, and (c) drill cores from a large slab of the Estacado H6 find located within a few tens of centimeters of each other. Our results indicate that OC are heterogeneous in their bulk oxidation state and O-isotopic composition on 100-km-size scales, but homogeneous on meter-, decimeter- and centimeter-size scales. (On kilometer size scales, oxidation state is heterogeneous, but O isotopes appear to be homogeneous.) The asteroid-wide heterogeneity in oxidation state and O-isotopic composition was inherited from the solar nebula. The homogeneity on small size scales was probably caused in part by fluid-assisted metamorphism and mainly by impact-gardening processes (which are most effective at mixing target materials on scales of ?1 m).     

Fast kimberlite ascent rates estimated from hydrogen diffusion profiles in xenolithic mantle olivines from southern Africa

Fourier transform infrared spectrometry (FTIR) analyses of olivines from peridotite xenoliths found in southern African kimberlites indicate 0 to 80 ppm H₂O concentrations. OH absorbance profiles across olivine grains show homogeneous H contents from core to edge for most samples. In one sample the olivines are H-free, while another has olivines characterized by lower H contents at the grain edges compared to the cores, indicating H loss during transport of the xenolith to the surface. Flat or near-flat H profiles place severe constraints on the duration of H loss from olivine grains, with implications for kimberlite magma ascent rates. Diffusion equations were used to estimate times of H loss of about 4 h for the sample with heterogeneous olivine H contents. Resulting kimberlite ascent rates are calculated to be 5-37 m s⁻¹ minimum, although these estimates are highly dependent on volatile contents and degassing behavior of the host kimberlite magma. Xenolithic olivines from alkali basalts generally have lower H contents and more pronounced H diffusion profiles than do those from kimberlites. This difference is likely caused by higher magma temperatures and lower ascent rates of alkali basalts compared to kimberlites.     

Growing up green on serpentine soils: Biogeochemistry of serpentine vegetation in the Central Coast Range of California

Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg⁻¹. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils.     

The presence of anomalous trace element levels in present day Jamaican soils and the geochemistry of Late-Miocene or Pliocene phosphorites

High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene.     

The hydrochemistry of a semi-arid pan basin case study: Sua Pan,Makgadikgadi, Botswana

This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m³ of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (⁸⁷Sr/⁸⁶Sr average 0.722087) and S (δ³⁴S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.     

Pole-to-pole moisture conditions for the IGY

Summary A study of the mean atmospheric humidity conditions on a planetary scale during the IGY covering the calendar year 1958 is presented. The fields of mean precipitable water content and of the zonal and meridional transports of water vapor are analyzed for the entire globe. Zonally averaged values of the various quantities at several levels are presented in tabular form and compared whenever possible with previous results or indirectly are analyzed on the basis of information obtained from different sources. The structure of these fields is studied and the corresponding implications for the general circulations of the atmosphere are discussed. Finally the zonal water balance for all the globe is discussed and its implications analyzed.     

Heat exchange between water and ice in the Arctic Ocean

Summary The heat balance equation for the bottom surface of floating sea ice is evaluated on the basis of observations of ice temperature, water temperature, current velocity, and ablation or accretion of ice. Assuming equality of the eddy diffusivities for momentum, heat, and salt (average 24 cm² sec^–1) it is shown that the temperature gradient in the oceanic boundary layer is extremely small (averages between 2.10^–5 and 4.10^–4°C/meter) and difficult to measure directly. It is suggested that a large part of the heat transfer from the relatively warm Atlantic water to the arctic atmosphere may occur through open leads in the ice cover.

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Zusammenfassung Die Wärmebilanzgleichung für die Unterseite von schwimmendem Meereis wird an Hand von Beobachtungen der Eistemperatur, der Wassertemperatur, der Strömungsgeschwindigkeit und der Eisdickenänderung ausgewertet. Unter der Annahme gleicher Austauschkoeffizienten für Bewegungsgröße, Wärme und Salzgehalt (im Mittel 24 cm² sec^–1) ergibt sich für die ozeanische Grenzschicht ein außerordentlich kleiner Gradient der Wassertemperatur (durchschnittlich zwischen 2.10^–5 und 4.10^–4°C/Meter), der durch direkte Beobachtungen schwer nachzuweisen ist. Es ist zu vermuten, daß ein beträchtlicher Teil der Wärmeabgabe von der relativ warmen atlantischen Wassermasse an die arktische Atmosphäre durch Öffnungen in der Meereisdecke erfolgt.

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Résumé On établit l'équation du bilan thermique valable pour la surface inférieure de la glace marine dérivante. Pour ce faire, on se sert d'observations de la température de la glace, de celle de l'eau, de la vitesse du courant et des variations de l'épaisseur de la glace. En admettant que les coefficients d'échange sont les mêmes pour la quantité de mouvement, la chaleur et le taux de salinité (en moyenne 24 cm² sec^–1), il résulte pour la couche limite un gradient extrêmement faible de la température de l'eau (situé en moyenne entre 2·10^–5 et 4·10^–4°C/m); un tel gradient est difficile à prouver au moyen d'observations directes. On peut supposer qu'une partie importante de la chaleur transmise par l'eau relativement chaude de l'Atlantique à l'atmosphère arctique passe au travers des lacunes de la couche de glace recouvrant l'océan.

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With 4 Figures

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Contribution 141, Department of Atmospheric Sciences, University of Washington, Seattle. This is a thesis submitted by the author in partial fulfillment of the requirements for the degree of Master of Science.