Development of secondary porosity in the Fairholme carbonate complex (southwest Alberta, Canada)

Because of their economic importance as hydrocarbon reservoirs, the Upper Devonian dolomitized carbonate reefs in southwest Alberta have been the subject of several studies. Still, there is no consensus on the process of matrix dolomitization and furthermore, the process of vug development is not often addressed. The studied outcrops show features of an early diagenetic matrix-selective dolomitization by a Late Devonian seawater-derived fluid. Seepage reflux dolomitization combined with latent reflux is proposed, which best explains most chemical characteristics. The cements in the vugs are precipitated from warm saline, ⁸⁷Sr-enriched fluids and testify to thermogenic sulphate reduction based on the presence of sulphur, CO₂ and H₂S in inclusions, relatively high homogenization temperatures and depleted δ¹³C values, which sets constraints on the timing of vug formation. Secondary porosity may be created by the mixing of formation water with a tectonically and topographically driven fluid and by the dissolution of anhydrite nodules.     

An obliquity-controlled Early Pleistocene river terrace record from Western Turkey?

Investigation of the Pleistocene sequence of the Gediz River, Western Turkey, has revealed a record of Early Pleistocene river terraces. Eleven terraces spanning the interval from 1.67 to 1.245 million years ago (MIS 59–37) are preserved beneath basaltic lava flows. The high number of terraces over this short time period reflects high-frequency sedimentation/incision cycles preserved due to the fortuitous combination of relatively high uplift rates (0.16 mm yr⁻¹) and progressive southwards valley migration. Comparison of this record with ODP967 from the Eastern Mediterranean Basin suggests a link between the production of terraces and obliquity-driven 41,000 year climate cycles in the Early Pleistocene.     

Research, Extension and Industry – Working Together Can Achieve Results

Over recent decades, research has been directed to assessing the impacts of land uses on valuable natural assets, such as the Great Barrier Reef. Land managers in adjacent areas are expected to adopt practices to minimize any adverse affects on downstream environments. Conversely, researchers are being pressed to provide answers to the problems. In response, researchers and environmental managers are bombarding land managers with information regarding the potential environmental implications of their practices. Is this an effective mode to achieve on-ground change?

Collaboration between all groups – research, industry and extension – may be more effective in developing and implementing practical solutions to these more complex issues. A change from the research and extension models currently used may be needed to achieve positive resource management outcomes.

Research, development and extension initiatives underway in the Australian sugar industry to improve farm practice and reduce the potential for adverse impacts on downstream environments are discussed. Case studies provide some insights into how science and extension skills work best together and how an industry group can respond to a community concern.     

The competing impacts of geology and groundwater on electrical resistivity around Wrightsville Beach,NC

Measurements of electrical resistivity have long been used to find freshwater resources below the earth's surface. Recently, offshore resistivity and electromagnetic techniques have been used to map occurrences of submarine groundwater originating from the offshore extension of terrestrial aquifers. In many cases, observations of a high resistivity (low conductivity) anomaly in the seafloor are sufficient to suggest the presence of fresh (and less conductive) pore waters. Data from offshore Wrightsville Beach, NC show highly variable resistivity structure, with moderately high resistivity at depths of ～20 m subsurface that is at least in part caused by lithologic complexity in an underlying limestone unit, the Castle Hayne. These offshore results suggest caution in the interpretation of resistivity anomalies simply in terms of groundwater volumes. In contrast, low onshore resistivities show evidence for intrusion of saltwater into the subsurface beneath the beach, adjacent to areas of pumping for water supply.     

Continuous field estimation of dissolved organic carbon concentration and biochemical oxygen demand using dual‐wavelength fluorescence,turbidity and temperature

Dissolved organic matter (DOM) quality and quantity is not measured routinely in‐situ limiting our ability to quantify DOM process dynamics. This is problematic given legislative obligations to determine event based variability; however, recent advances in field deployable optical sensing technology provide the opportunity to address this problem. In this paper, we outline a new approach for in‐situ quantification of DOM quantity (Dissolved Organic Carbon: DOC) and a component of quality (Biochemical Oxygen Demand: BOD) using a multi‐wavelength, through‐flow fluorescence sensor. The sensor measured tryptophan‐like (Peak T) and humic‐like (Peak C) fluorescence, alongside water temperature and turbidity. Laboratory derived coefficients were developed to compensate for thermal quenching and turbidity interference (i.e., light attenuation and scattering). Field tests were undertaken on an urban river with ageing wastewater and stormwater infrastructure (Bourn Brook; Birmingham, UK). Sensor output was validated against laboratory determinations of DOC and BOD collected by discrete grab sampling during baseflow and stormflow conditions. Data driven regression models were then compared to laboratory correction methods. A combination of temperature and turbidity compensated Peak T and Peak C was found to be a good predictor of DOC concentration (R² = 0.92). Conversely, using temperature and turbidity correction coefficients provided low predictive power for BOD (R² = 0.46 and R² = 0.51, for Peak C and T, respectively). For this study system, turbidity appeared to be a reasonable proxy for BOD, R² = 0.86. However, a linear mixed effect model with temperature compensated Peak T and turbidity provided a robust BOD prediction (R² = 0.95). These findings indicate that with careful initial calibration, multi‐wavelength fluorescence, coupled with turbidity, and temperature provides a feasible proxy for continuous, in‐situ measurement of DOC concentration and BOD. This approach represents a cost effective monitoring solution, particularly when compared to UV – absorbance sensors and DOC analysers, and could be readily adopted for research and industrial applications.