Petrogenesis of late stage magmatism at Hold with Hope, East Greenland

The Myggbukta caldera complex and a swarm of basic dykes constitute the latest Tertiary magmatism in the Hold with Hope region, East Greenland. The Sr and Nd isotope ratios of these rocks show coherent variations which extend to high ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd values and require a contribution from continental lithosphere. Broad correlations with major element differentiation indices suggest that the continental component was incorporated during magmatic differentiation thereby favouring a crustal contamination process. Trace element concentrations are strongly correlated with isotopic compositions but display ranges for many incompatible elements which extend beyond likely crustal contaminant compositions. This is readily modelled by AFC processes in which the dominant cause of trace element enrichment is the concentration effect of fractional crystallisation rather than the composition of the contaminant. The simplest such models still require unrealistically high degrees of fractional crystallisation to explain the ten-fold enrichment of some trace elements. This can be overcome if the primary magmas entering the crust already had highly variable trace element compositions. Such variability is readily achieved if melts from different parts of the melting column escape without thorough homogenization. An AFC model which incorporates variability in parental magma composition is then able to simulate the range of compositions observed at Hold with Hope. This carries the implication that the variations observed are more readily attributed to changes in uncontaminated parental magma than to variations in the composition or amount of contaminant. Received: 5 March 1998 / Accepted: 16 June 1998     

A modelling framework for evaluation of the hydrological impacts of nature‐based approaches to flood risk management,with application to in‐channel interventions across a 29‐km2 scale catchment in the United Kingdom

Nature‐based approaches to flood risk management are increasing in popularity. Evidence for the effectiveness at the catchment scale of such spatially distributed upstream measures is inconclusive. However, it also remains an open question whether, under certain conditions, the individual impacts of a collection of flood mitigation interventions could combine to produce a detrimental effect on runoff response. A modelling framework is presented for evaluation of the impacts of hillslope and in‐channel natural flood management interventions. It couples an existing semidistributed hydrological model with a new, spatially explicit, hydraulic channel network routing model. The model is applied to assess a potential flood mitigation scheme in an agricultural catchment in North Yorkshire, United Kingdom, comprising various configurations of a single variety of in‐channel feature. The hydrological model is used to generate subsurface and surface fluxes for a flood event in 2012. The network routing model is then applied to evaluate the response to the addition of up to 59 features. Additional channel and floodplain storage of approximately 70,000 m³ is seen with a reduction of around 11% in peak discharge. Although this might be sufficient to reduce flooding in moderate events, it is inadequate to prevent flooding in the double‐peaked storm of the magnitude that caused damage within the catchment in 2012. Some strategies using features specific to this catchment are suggested in order to improve the attenuation that could be achieved by applying a nature‐based approach.     

Late Pleistocene and Holocene Afromontane vegetation and headwater wetland dynamics within the Eastern Mau Forest,Kenya

The Mau Forest Complex is Kenya's largest fragment of Afromontane forest, providing critical ecosystem services, and has been subject to intense land use changes since colonial times. It forms the upper catchment of rivers that drain into major drainage networks, thus supporting the livelihoods of millions of Kenyans and providing important wildlife areas. We present the results of a sedimentological and palynological analysis of a Late Pleistocene–Holocene sediment record of Afromontane forest change from Nyabuiyabui wetland in the Eastern Mau Forest, a highland region that has received limited geological characterization and palaeoecological study. Sedimentology, pollen, charcoal, X-ray fluorescence and radiocarbon data record environmental and ecosystem change over the last ~16 000 cal a bp. The pollen record suggests Afromontane forests characterized the end of the Late Pleistocene to the Holocene with dominant taxa changing from Apodytes, Celtis, Dracaena, Hagenia and Podocarpus to Cordia, Croton, Ficus, Juniperus and Olea. The Late Holocene is characterized by a more open Afromontane forest with increased grass and herbaceous cover. Continuous Poaceae, Cyperaceae and Juncaceae vegetation currently cover the wetland and the water level has been decreasing over the recent past. Intensive agroforestry since the 1920s has reduced Afromontane forest cover as introduced taxa have increased (Pinus, Cupressus and Eucalyptus).     

The electrical structure of the Slave craton

The Slave craton in northwestern Canada, a relatively small Archean craton (600×400 km), is ideal as a natural laboratory for investigating the formation and evolution of Mesoarchean and Neoarchean sub-continental lithospheric mantle (SCLM). Excellent outcrop and the discovery of economic diamondiferous kimberlite pipes in the centre of the craton during the early 1990s have led to an unparalleled amount of geoscientific information becoming available.

Over the last 5 years deep-probing electromagnetic surveys were conducted on the Slave, using the natural-source magnetotelluric (MT) technique, as part of a variety of programs to study the craton and determine its regional-scale electrical structure. Two of the four types of surveys involved novel MT data acquisition; one through frozen lakes along ice roads during winter, and the second using ocean-bottom MT instrumentation deployed from float planes.

The primary initial objective of the MT surveys was to determine the geometry of the topography of the lithosphere–asthenosphere boundary (LAB) across the Slave craton. However, the MT responses revealed, completely serendipitously, a remarkable anomaly in electrical conductivity in the SCLM of the central Slave craton. This Central Slave Mantle Conductor (CSMC) anomaly is modelled as a localized region of low resistivity (10–15 Ω m) beginning at depths of 80–120 km and striking NE–SW. Where precisely located, it is spatially coincident with the Eocene-aged kimberlite field in the central part of the craton (the so-called “Corridor of Hope”), and also with a geochemically defined ultra-depleted harzburgitic layer interpreted as oceanic or arc-related lithosphere emplaced during early tectonism. The CSMC lies wholly within the NE–SW striking central zone defined by Grütter et al. [Grütter, H.S., Apter, D.B., Kong, J., 1999. Crust–mantle coupling; evidence from mantle-derived xenocrystic garnets. Contributed paper at: The 7th International Kimberlite Conference Proceeding, J.B. Dawson Volume, 1, 307–313] on the basis of garnet geochemistry (G10 vs. G9) populations.

Deep-probing MT data from the lake bottom instruments infer that the conductor has a total depth-integrated conductivity (conductance) of the order of 2000 Siemens, which, given an internal resistivity of 10–15 Ω m, implies a thickness of 20–30 km. Below the CSMC the electrical resistivity of the lithosphere increases by a factor of 3–5 to values of around 50 Ω m. This change occurs at depths consistent with the graphite–diamond transition, which is taken as consistent with a carbon interpretation for the CSMC.

Preliminary three-dimensional MT modelling supports the NE–SW striking geometry for the conductor, and also suggests a NW dip. This geometry is taken as implying that the tectonic processes that emplaced this geophysical–geochemical body are likely related to the subduction of a craton of unknown provenance from the SE (present-day coordinates) during 2630–2620 Ma. It suggests that the lithospheric stacking model of Helmstaedt and Schulze [Helmstaedt, H.H., Schulze, D.J., 1989. Southern African kimberlites and their mantle sample: implications for Archean tectonics and lithosphere evolution. In Ross, J. (Ed.), Kimberlites and Related Rocks, Vol. 1: Their Composition, Occurrence, Origin, and Emplacement. Geological Society of Australia Special Publication, vol. 14, 358–368] is likely correct for the formation of the Slave's current SCLM.     

Middle Paleozoic paleomagnetism of east Kazakhstan: post-Middle Devonian rotations in a large-scale orocline in the central Ural–Mongol belt

In order to test different hypotheses concerning the Paleozoic evolution of the Ural–Mongol belt (UMB) and the amalgamation of Eurasia, we studied Middle Devonian basalts from two localities (11 sites) and Lower Silurian volcanics, redbeds, and intra-formational conglomerates from three localities (20 sites) in the Chingiz Range of East Kazakhstan. The Devonian rocks prove to be heavily overprinted in the late Paleozoic, and a high-temperature, presumably primary, southerly, and down component is isolated at only four sites from a homoclinal section. Most Silurian redbeds are found to be remagnetized in the late Paleozoic; in contrast, a bipolar near-horizontal remanence, isolated from Silurian volcanics, is most probably primary as indicated by positive tilt and conglomerate tests. Analysis of paleomagnetic data from the Chingiz Range shows that southward-pointing directions in Ordovician, Silurian, and Devonian rocks are of normal polarity and hence indicate large-scale rotations after the Middle Devonian. The Chingiz paleomagnetic directions can be compared with Paleozoic data from the North Tien Shan and with the horseshoe-shaped distribution of subduction-related volcanic complexes in Kazakhstan. Both paleomagnetic and geological data support the idea that today's strongly curved volcanic belts of Kazakhstan are an orocline, deformed mostly before mid-Permian time. Despite the determination of nearly a dozen new Paleozoic paleopoles in this study and other recent publications by our team, significant temporal and spatial gaps remain in our knowledge of the paleomagnetic directions during the middle and late Paleozoic. However, the paleomagnetic results from the Chingiz Range and the North Tien Shan indicate that these areas show generally coherent motions with Siberia and Baltica, respectively.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.     

Improved age constraint for pre‐ and post‐Anglian temperate‐stage deposits in north Norfolk,UK, from analysis of serine decomposition in Bithynia opercula

The ‘new glacial stratigraphy’ (NGS) of Britain postulates that deposits hitherto assigned to the Anglian glaciation in Marine Isotope Stage (MIS) 12 represent MIS 16, 12, 10 and 6. This controversial idea can be tested at Sidestrand in north Norfolk, where fossiliferous temperate‐stage deposits underlie the oldest and overlie the youngest of the glacial deposits. Previous work has considered biostratigraphy and amino acid dating of these temperate‐stage deposits, but did not achieve tight age constraint using the amino acid evidence alone. The total hydrolysable amino acid fraction in intra‐crystalline protein from Bithynia tentaculata opercula has previously been analysed for concentrations of serine and alanine. Statistical screening of these data gives alanine/serine ratios of 4.572 ± 0.114 for the Sidestrand Hall Member (beneath the glacial deposits) and 3.564 ± 0.091 for the Sidestrand Cliff Formation (overlying the glacial deposits). These ratios imply ages of MIS 13a and 11c, respectively, indicating the latest Cromerian and early Hoxnian interglacials and invalidating the NGS. Copyright © 2009 John Wiley & Sons, Ltd.     

Europe adapts to climate change: Comparing National Adaptation Strategies

For the last two decades, European climate policy has focused almost exclusively on mitigation of climate change. It was only well after the turn of the century, with impacts of climate change increasingly being observed, that adaptation was added to the policy agenda and EU Member States started to develop National Adaptation Strategies (NASs). This paper reviews seven National Adaptation Strategies that were either formally adopted or under development by Member States at the end of 2008. The strategies are analysed under the following six themes. Firstly, the factors motivating and facilitating the development of a national adaptation strategy. Secondly, the scientific and technical support needed for the development and implementation of such a strategy. Thirdly, the role of the strategy in information, communication and awareness-raising of the adaptation issue. Fourthly, new or existing forms of multi-level governance to implement the proposed actions. Fifthly, how the strategy addresses integration and coordination with other policy domains. Finally, how the strategy suggests the implementation and how the strategy is evaluated. The paper notes that the role of National Adaptation Strategies in the wider governance of adaptation differs between countries but clearly benchmarks a new political commitment to adaptation at national policy levels. However, we also find that in most cases approaches for implementing and evaluating the strategies are yet to be defined. The paper concludes that even though the strategies show great resemblance in terms of topics, methods and approaches, there are many institutional challenges, including multi-level governance and policy integration issues, which can act as considerable barriers in future policy implementation.     

Quantitative multi-risk analysis for natural hazards: a framework for multi-risk modelling

This paper introduces a generic framework for multi-risk modelling developed in the project ‘Regional RiskScape’ by the Research Organizations GNS Science and the National Institute of Water and Atmospheric Research Ltd. (NIWA) in New Zealand. Our goal was to develop a generic technology for modelling risks from different natural hazards and for various elements at risk. The technical framework is not dependent on the specific nature of the individual hazard nor the vulnerability and the type of the individual assets. Based on this generic framework, a software prototype has been developed, which is capable of ‘plugging in’ various natural hazards and assets without reconfiguring or adapting the generic software framework. To achieve that, we developed a set of standards for treating the fundamental components of a risk model: hazards, assets (elements at risk) and vulnerability models (or fragility functions). Thus, the developed prototype system is able to accommodate any hazard, asset or fragility model, which is provided to the system according to that standard. The software prototype was tested by modelling earthquake, volcanic ashfall, flood, wind, and tsunami risks for several urban centres and small communities in New Zealand.     

Geochemical studies in the drainage basin of the Rio Vouga,Portugal. IV. Impact of land use on the hydrogeochemistry of natural waters in the Vouzela region

A hydrogeochemical study of the impact of land use on the composition of natural waters in the Vouzela region in northern Portugal was carried out during the summer of 1983. Water samples were collected from spring and major streams in the area and analyzed for major constituents and some trace elements. Analysis of variance and subsequent pairwise contrast tests demonstrated that waters from agricultural areas are significantly enriched in constiluents such as Na, K, Ca, Mg, Sr, Cl, SO₄, and NO₃. High concentrations of these ions in agricultural areas are the result of both the application of fertilizers and enhanced evaporation by the intensive irrigation of agricultural lands. Constitutents such as H₄SiO₄, HCO₃, F, and probably Li, which are typically related to mineral weathering, were not affected by land use. In waters from forested areas the concentration of most constituents was about 20% higher than in waters from uncultivated areas with mainly a grass cover. This reflects the difference in the evapotranspiration of these two vegetation types. The chemistry of the Rio Zela clearly reflects differences in land use in the Rio Zela valley.