Deltaic sedimentation in the Devonian of Western Libya

Middle and Upper Devonian deposits from the Aouinet Ouenine Formation in the southern Ghadames Basin of western Libya provide a well exposed example of a deltaic complex containing both progradational and transgressive facies. Progradational facies comprise both laterally accreting and incised distributary channels overlying prodelta deposits. Also present is a progradational beach environment showing build-up from an offshore shelf through nearshore shelf to shoreface and foreshore sub-environments. Over-lying these progradational facies are transgressive tidal-flat, washover-fan, foreshore and nearshore deposits.The characteristics and interrelationships of the different facies are explained by two sedimentation models: progradational facies existed contemporaneously during phases of active sediment supply whereas the transgressive facies existed contemporaneously during periods of diminished or absent detrital influx.     

Quantitative taxonomy and biostratigraphy of Middle Cambrian trilobites from Montana and Wyoming

This study was made to revise the taxonomy and biostratigraphy of Middle Cambrian trilobites from Montana and Wyoming. Both numerical and conventional analyses were made of the taxonomic and biostratigraphic data. Numerical taxonomy was performed on a sample of 210 OTU's (Operational Taxonomic Units) using 66 characters which were determined on cranidia of Middle Cambrian ptychopariid trilobites. These characters consisted of linear measurements which were transformed to indices proportional to glabellar length, quantitative-qualitative shape or angle measurements, and multistate attributes. The similarity coefficients calculated were average taxonomic distances and Pearson's product-moment correlation coefficient. The matrices of similarity coefficients were clustered by single-linkage and unweighted pair-group algorithms. The coordinates of OTU's in a three-dimensional A-space defined by the first three principal axes also were calculated. A phenogram of the distance matrix clustered by UPGMA (which yielded the highest cophenetic correlation coefficient) and a three-dimensional pin-and-ball model were used to interpret the trilobite taxonomy. Insufficiently clear clustering in both representations of taxonomic structure necessitated also a conventional taxonomic study guided by the numerical phenetics. Numerical biostratigraphy was performed with 79 collections as OTU's and 43 trilobite genera as characters. Jaccard coefficients were used as similarity coefficients, and the results were clustered by UPGMA. The resultant phenogram was readily interpretable, and seven faunal assemblage zones (Albertella, Glossopleura, Ehmaniella, Bolaspis-Glyphaspis, Ehmania, Parehmania, and Bolaspidella)are defined for the Middle Cambrian in the study area. Two of the zones (Ehmaniellaand Parehmania)are new and replace part of the previously defined “Bathyuriscus-Elrathina”zone. Bolaspis-Glyphaspis, Ehmania,and Parehmaniazones may have only regional validity.     

The northern limits of glacial lake Algonquin in upper Michigan

A number of ancient shorelines formed by late-Pleistocene proglacial lakes have been found in eastern upper Michigan. These shorelines delimit several water planes, the uppermost of which is correlated with the Main Lake Algonquin stage. This correlation is based on the continuity of the highest water plane with Main Algonquin shorelines in Wisconsin and Ontario, the strength of the shoreline features, its altitudinal relationship with lower water planes, and a reinterpretation of radiocarbon dates from the Sault Ste. Maria area. The isobases of this water plane have a bearing of S75°E. At the time of the maximum extent of Lake Algonquin, ca. 10,600 yr B.P., its northern, ice-limited border lay along the Munising moraine, the northernmost of the two main morainic systems of eastern upper Michigan. This interpretation lends support to the idea of a period of slow deglaciation from ca. 11,000 to 10,000 yr B.P. An ice lobe occupied the central Lake Superior basin until early Holocene time. Radiocarbon dates on wood found beneath till or outwash at several sites indicate a minor ice readvance from the central Lake Superior basin ca. 10,000 yr B.P. If true, this would have prevented the development of the post-Duluth series of glacial lakes in the western Lake Superior basin until ca. 9900 yr B.P., well after the end of the main Lake Algonquin stage.     

The contribution of sulphur dioxide from ablating micrometeorites to the atmospheres of Earth and Mars

Atmospheric composition is a key control on climate and the habitability of planetary surfaces. Ablation of infalling micrometeorites has been recognised as one way in which atmospheric chemistry can be changed, especially at times in solar system history when the infall rates of exogenous material were high. Despite its potential to influence climate and habitability, extraterrestrial sulphur dioxide is currently an unquantified contribution to the atmospheres of the terrestrial planets. We have used flash pyrolysis to simulate the atmospheric entry of micrometeorites and Fourier-transform infrared spectroscopy to identify and quantify the sulphur dioxide produced from the carbonaceous meteorites Orgueil (CI1), ALH 88045 (CM1), Cold Bokkeveld (CM2), Murchison (CM2) and Mokoia (CV3). We have used this approach to understand the introduction of sulphur dioxide to the atmospheres of Earth and Mars from infalling micrometeorites. Sulphates, present in carbonaceous chondrites at a few wt.%, are resistant to thermal decomposition, limiting the yields of sulphur dioxide from unmelted micrometeorites. Infalling micrometeorites are a minor source of present-day sulphur dioxide on Earth and Mars, calculated to be up to around 2400 tonnes and about 350 tonnes, respectively. During the Late Heavy Bombardment (LHB), the much greater infall rates of micrometeoritic dust are calculated to be associated with average production rates of sulphur dioxide of around 20 Mt yr⁻¹ for the early Earth and 0.5 Mt yr⁻¹ for early Mars, for a LHB of 100 Myr. These rates of delivery of sulphur dioxide at high altitudes would have reduced the solar energy reaching the surfaces of these planets, via scattering of sunlight by stratospheric sulphate aerosols, and may have had detrimental effects on developing biospheres by promoting cooler climates and reducing the probability of liquid water on planetary surfaces.     

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).     

Effect of suction on the mechanical behaviour of iron ore rock

The effect of suction on the behaviour of iron ore has been studied from both physical and mechanical points of view. The porosity and the suction phenomena have been analysed using different experimental techniques. Uniaxial compressive tests on partially saturated samples have shown that the suction is responsible for strength and cohesion improvement. Considering the theory of partially saturated porous soils of Coussy and Dangla (Mécanique des sols non saturés (2002 edn). Hermès Science: 2002; 390), we have proposed a constitutive law for partially saturated iron ore. The real increase in the apparent cohesion due to the capillary attraction forces is overestimated if the yield function is written in terms of effective stresses. The effect of the capillary cohesion has been modelled with a function in the expression of the apparent cohesion of the yield function. The effect of suction on the mechanical behaviour has been represented in the effective stresses space and in the total stresses space like the Alonso model (Géotechnique 1990; 40 :405–430). Copyright © 2005 John Wiley & Sons, Ltd.     

Cu(II) adsorption at the calcite-water interface in the presence of natural organic matter: Kinetic studies and molecular-scale characterization

We have characterized the adsorption of Suwannee River humic acid (SRHA) and Cu(II) on calcite from preequilibrated solutions at pH 8.25. Sorption isotherms of SRHA on calcite follow Langmuir-type behavior at SRHA concentrations less than 15 mg C L⁻¹, whereas non-Langmuirian uptake becomes evident at concentrations greater than 15 mg C L⁻¹. The adsorption of SRHA on calcite is rapid and mostly irreversible, with corresponding changes in electrostatic properties. At pH 8.25, Cu(II) uptake by calcite in the presence of dissolved SRHA decreases with increasing dissolved SRHA concentration, suggesting that formation of Cu-SRHA aqueous complexes is the primary factor controlling Cu(II) sorption at the calcite surface under the conditions of our experiments. We also observed that surface-bound SRHA has little influence on Cu(II) uptake by calcite, suggesting that Cu(II) coordinates to calcite surface sites rather than to surface-bound SRHA.Cu K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine-structure (EXAFS) spectroscopic results show that the local coordination of Cu adsorbed at the calcite surface is very similar in the presence and absence of SRHA. Ca backscatterers at ∼3.90 Å indicate that Cu(II) forms tetragonally distorted inner-sphere adsorption complexes in both binary and ternary systems. Subtle differences in the XANES and EXAFS between binary sorption samples and ternary sorption samples, however, prevent us from ruling out the formation of ternary Cu-SRHA surface complexes. Our findings demonstrate that SRHA plays an important role in controlling the fate and transport of Cu(II) in calcite-bearing systems.     

Intrusion–Related Vein Gold Deposits: Types, Tectono-Magmatic Settings and Difficulties of Distinction from Orogenic Gold Deposits

Abstract: A spectrum of intrusion-related vein gold deposits is recognized. Representative examples are described of the following geochemical associations: Au-Fe oxide–Cu, Au–Cu–Mo–Zn, Au–As–Pb–Zn–Cu, Au–Te–Pb–Zn–Cu and Au–As–Bi–Sb. The associated intrusions range from small outcropping stocks to complex batholiths. The different vein associations are believed to reflect the compositions of related intrusions, which themselves characterize distinct tectonic settings. The Au-Fe oxide–Cu and Au–Cu–Mo–Zn associations belong to two broad groups of deposits, Fe oxide–Cu–Au and porphyry Cu–Au, both of which are related to highly oxidized calc-alkaline intrusions emplaced in sub–duction–related arcs. The Au–As–Pb–Zn–Cu association seems to be linked to somewhat less oxidized intrusions emplaced in a similar setting. The Au–Te–Pb–Zn–Cu association, which possesses well-known epithermal counterparts, is also found with highly oxidized intrusions, but of alkaline composition and back-arc location. In contrast, the Au–As–Bi–Sb association, part of a newly recognized class of intrusion-hosted Au–Bi–W–As deposits, is related to relatively reduced intrusions, spanning the boundary between the magnetite– and ilmenite–series. Such intrusions, which may host major bulk-mineable gold deposits, were emplaced along the landward sides of arcs, possibly during lulls in subduction, as well as in continental collision settings. Therefore, a variety of geological environments is prospective for vein and, by extrapolation, other styles of gold mineralization, not all of them fully appreciated in the past. Several features of vein gold deposits, including imprecise relationships to individual intrusive phases, poorly developed mineral and metal zoning, apparent time gaps between intrusion and mineralization and presence of low–salinity, CO₂–rich fluid inclusions, are commonly taken to indicate a non-igneous origin and to be more typical of orogenic (mesothermal) gold deposits generated during accretionary tectonic events. However, several or all of these features apply equally to some intrusion– related vein gold deposits and, therefore, do not constitute distinguishing criteria. The currently popular assignment of most gold-rich veins to the orogenic category requires caution, because of the geological convergence that they show with some intrusion-related deposits. A proper distinction between intrusion-related and orogenic gold deposits is crucial for exploration planning.     

Dynamic simulation of littoral zone habitats in low Chesapeake Bay. II. Seagrass habitat primary production and water quality relationships

Seagrasses are indicators of ecosystem state because they are sensitive to variations in water composition and clarity resulting from watershed-level impacts. A simulation model designed to studyZostera marina (eelgrass) habitat dynamics in a variable littoral zone environment was used to address the potential ecological responses to eutrophication in lower Chesapeake Bay. The adjacent channel boundary environment is a source of dissolved and particulate materials to the littoral zone. In the simulations, concentrations of key water quality variables in the adjacent estuarine channel boundary were either halved or doubled relative to the base case to investigate light versus nitrogen effects. The role of the seagrass meadow in littoral zone carbon and nitrogen dynamics was evaluated when meadow size was changed in the model. Particulate and dissolved organic carbon accounted for 83% of the submarine light attenuation in the seagrass meadow. In all model runs, the water column concentrations of chlorophylla and dissolved inorganic nitrogen (DIN) were below the habitat criteria proposed as critical to seagrass survival. Eelgrass community production was carefully regulated by the interactive effects of light, nitrogen, and grazing on epiphyte growth. Increased eelgrass coverage in the littoral zone led to a simulated doubling of ecosystem primary production but reduced the fraction of production by planktonic and sediment microalgae. The simulation model presented here demonstrated the importance of material input from the channel in littoral zone biogeochemical dynamics. Submarine ligh regulated primary production more strongly than inorganic nitrogen concentrations in the model. External DIN concentrations influenced seagrass survival indirectly: enrichment stimulated growth of epiphytes and phytoplankton and promoted shading of the seagras leaf. The model was based upon a unimpacted ecosystem and deteriorated water quality negatively influenced primary production greater than the increases triggered by improved condition. Increased material loading to the littoral zone reduced submarine light availability, increased phytoplankton production, lowered ecosystem production, and reduced subtidal vegetated habitat. This simulation model of the estuarine littoral zone model combines hydrodynamics, biogeochemical sources and sinks, and living resources in order to better understand structure, function, and change in aquatic ecosystems.