Stable Isotopes Reveal Complex Changes in Trophic Relationships Following Nutrient Addition in a Coastal Marine Ecosystem

Complex links between the top-down and bottom-up forces that structure communities can be disrupted by anthropogenic alterations of natural habitats. We used relative abundance and stable isotopes to examine changes in epifaunal food webs in seagrass (Thalassia testudinum) beds following 6 months of experimental nutrient addition at two sites in Florida Bay (USA) with different ambient fertility. At a eutrophic site, nutrient addition did not strongly affect food web structure, but at a nutrient-poor site, enrichment increased the abundances of crustacean epiphyte grazers, and the diets of these grazers became more varied. Benthic grazers did not change in abundance but shifted their diet away from green macroalgae + associated epiphytes and towards an opportunistic seagrass (Halodule wrightii) that occurred only in nutrient addition treatments. Benthic predators did not change in abundance, but their diets were more varied in enriched plots. Food chain length was short and unaffected by site or nutrient treatment, but increased food web complexity in enriched plots was suggested by increasingly mixed diets. Strong bottom-up modifications of food web structure in the nutrient-limited site and the limited top-down influences of grazers on seagrass epiphyte biomass suggest that, in this system, the bottom-up role of nutrient enrichment can have substantial impacts on community structure, trophic relationships, and, ultimately, the productivity values of the ecosystem.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.     

Orbitolinidae and Alveolinidae (Foraminiferida) from the uppermost Albian-lower Cenomanian of Monti d'Ocre (Abruzzi, Italy)

A biostratigraphic study carried out in the Monti d'Ocre area, Abruzzi, Central Apennines, allowed us to recognize Orbitolina (Conicorbitolina) moulladei ‘Strata 5 (1985) 1’, Praealveolina iberica Reichel and Praealveolina simplex Reichel in uppermost Albian–lower Cenomanian shelf-edge deposits of the Fossato Machè succession. These foraminifers have now been found for the first time in the Apennines of central Italy; their finding is quite important from a palaeobiogeographic viewpoint, as it contributes to the improvement of our knowledge on facies distribution in the circum-Mediterranean regions during the Cretaceous Period. In the study area, the coeval Monte Rotondo and Monte Orsello sections also crop out; these are characterized by bauxite deposits and stratigraphic gaps reflecting episodes of emergence on the carbonate platform. The Monte Rotondo and Monte Orsello sections accumulated in a platform back-reef environment; consequently, in this sector of the Monti d'Ocre area, the depositional environment shifted from a back-reef westward and southward to a shelf-edge northward, during the latest Albian–early Cenomanian. Owing to synsedimentary tectonics, the area investigated underwent differential subsidence: westward and southward, wide areas were uplifted and subjected to emergence, karstification and bauxite accumulation, whereas sedimentation continued in a shelf-edge environment in the north-eastern area.     

Carrier phase bias estimation of geometry-free linear combination of GNSS signals for ionospheric TEC modeling

The ionosphere can be modeled and studied using multi-frequency GNSS signals and their geometry-free linear combination. Therefore, a number of GNSS-derived ionospheric models have been developed and applied in a broad range of applications. However, due to the complexity of estimating the carrier phase ambiguities, most of these models are based on low-accuracy carrier phase smoothed pseudorange data. This, in turn, critically limits their accuracy and applicability. Therefore, we present a new methodology of estimating the phase bias of the scaled L1 and L2 carrier phase difference which is a function of the ambiguities, the ionospheric delay, and hardware delays. This methodology is suitable for ionospheric modeling at regional and continental scales. In addition, we present its evaluation under varying ionospheric conditions. The test results show that the carrier phase bias of geometry-free linear combination can be estimated with a very high accuracy, which consequently allows for calculating ionospheric TEC with the uncertainty lower than 1.0 TECU. This high accuracy makes the resulting ionosphere model suitable for improving GNSS positioning for high-precision applications in geosciences.     

Problems of ratifying international environmental agreements: Overcoming initial obstacles in the post-agreement negotiation process

The post-agreement period typically is characterized by negotiations between various stakeholders to reach mutually beneficial and acceptable means to achieve national implementation of, and compliance with, treaty provisions. National ratification of international environmental agreements is often the first subprocess of these ‘postagreement negotiations’. This article places ratification negotiations within the larger conceptual context of postagreement negotiations, with the goal of understanding and explaining problems of treaty Implementation. An empirical analysis reveals that delay in national ratification of environmental agreements is a chronic problem, but is worse for complex, multi-issue treaties. Strong public concern over local environmental issues, low quality of life, low national wealth, and low public research and development expenditures for environmental protection contribute to ratification delay. Ultimately, the authors are interested in identifying ways of improving the international negotiation process that initiated these later problems in implementation. Recommendations are offered in this regard.     

Correction to: Spatio-temporal variability of atmospheric rivers and associated atmospheric parameters in the Euro-Atlantic region

Theoretical and Applied Climatology -     

Cleantech clusters: Transformational assemblages for a just,green economy or just business as usual?

The rhetorical zeal for green enterprise as a global fix for the tripartite challenges of economic recession, environmental degradation and social inequality is increasingly visible in state and non-state pronouncements around the globe under the banner of ‘The Green Economy’. In particular, many policy-facing statements call for transitions leading to a transformation in development practices. Yet there is little detail either in policy or research regarding the types of transitions needed and how they are to be initiated, nor agreement about what a transformed economy might look like. Despite this, there are emergent activities within the cleantech arena which are being heralded as actually existing examples of green economy activities. One means through which these activities are seeking to exert influence over development trajectories is by clustering both at the subnational and transnational level. While diverse in formation, many of these clusters are hybridised, involving actors from public, private and civil society sectors. Critiquing the efficacy of mainstream industrial cluster theory to analyse hybridised cleantech clustering, this paper presents a unique synthesis of current thought on multiscalar environmental governance and socio-spatial formations to explore the practices and potentialities of these hybridised cleantech clusters. Surveying the landscape of cleantech clustering and meta-clustering, before focusing in depth on one case study, the contribution of clustering to transitioning towards a transformed green economy is considered. Despite strong forces, both within and beyond cleantech clusters, for maintaining neoliberalised approaches to cleantech activity, it is concluded that for as long as cleantech clusters remain open and inclusive of actors proposing alternative pathways they do represent potential, albeit provisional, assemblages for transformation.     

Consistent global responses of marine ecosystems to future climate change across the IPCC AR5 earth system models

Climate Dynamics - We analyze for the first time all 16 Coupled Model Intercomparison Project Phase 5 models with explicit marine ecological modules to identify the common mechanisms involved in...     

Benthic respiration and stoichiometry of regenerated nutrients in lake sediments with Dreissena polymorpha

The effect of patchy colonies of the invasive zebra mussel (Dreissena polymorpha) on sedimentary processes was investigated in a mesotrophic lake (Plateliai Lake, Lithuania). Benthic fluxes of O₂, TCO₂, CH₄, Mn²⁺, Fe²⁺, N₂, the inorganic forms of N, Si and P and dissolved organic C and N were quantified by dark incubations of sediments cores, with and without D. polymorpha. Individual mussels also were incubated for metabolic measurements. Sediments with D. polymorpha had significantly higher O₂ and TCO₂ fluxes and displayed higher rates of denitrification. The presence of mussels also resulted in higher regeneration of P and N (mostly as ammonium) while the effect on Si was not significant. However, likely due to the low zebra mussel biomass (57.2 ± 25.3 g_SFDW m^?2), biodeposition has not changed the ratio between anaerobic and total respiration. Methane and reduced metals fluxes were in fact similar in the presence and absence of D. polymorpha. Incubations of mussels without sediments confirmed that bivalve metabolism was the main driver of benthic respiration and nutrient recycling. Nitrate production suggested the presence of nitrifiers associated with the molluscs. The main outcome of this study was that zebra mussels alter the quantity and the stoichiometry of nutrients regenerated by the benthic compartment. The enhancement of nitrogen loss via denitrification, by a factor of 1.5, was much less pronounced than the increase in ammonium recycling rate, stimulated by a factor of 33. Negligible PO₄ ^3? fluxes in bare sediments (?3.4 ± 6.8 μmol m^?2 h^?1) increased in the presence of mussels and considerable amounts of this nutrient (69.6 ± 29.4 μmol m^?2 h^?1) were mobilized to the water column. Further research should address other nutrient sources to the lake to verify whether altered rates and stoichiometry of benthic regeneration can affect primary producer community composition and activity.