Influence of afforestation on water regime in Jizera Catchments,Czech Republic

This paper studies the influence of afforestation on the water regime in two catchments in the Jizera Mountains that are similar in size and altitude but have different afforestation pattern. In this paper a range of different modelling tools is used to establish whether the differences in catchment water regime can be quantified and attributed to differences in catchment characteristics. Frequency analysis of low and high flows and a number and duration of flows over a threshold value are used to look for the differences in flow regime in both catchments. Low flow conditions are modelled using the Wittenberg nonlinear store approach. A rainfall-runoff process is modelled using a Data Based Mechanistic approach. The results indicate that the differences in the catchment response to external climatic factors outweigh the influence of land use apart from the low flows, where the changes in the response might be attributed to afforestation.     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

The crystal structure of bøgvadite (Na2SrBa2Al4F20)

The crystal structure of bøgvadite, Na₂SrBa₂Al₄F₂₀, has been solved and refined to a R₁ factor of 4.4 % from single-crystal data (MoKα X-ray diffraction, CCD area detector) on a sample from the cryolite deposit at Ivittuut, SW Greenland. Bøgvadite is monoclinic, P2₁/n space group, with unit cell parameters a?=?7.134(1), b?=?19.996(3) and c?=?5.3440(8) Å, β?=?90.02(1)^o. A close proximity of the crystal structure to an orthorhombic symmetry and the presence of the two twin components in a nearly 1:1 ratio suggest that the investigated bøgvadite crystal has originally formed as a high-temperature orthorhombic polymorph which on cooling transformed to the stable low temperature monoclinic structure. The bøgvadite crystal structure has groupings of cation-fluoride coordination polyhedra similar to those found in the crystal structures of the genetically closely associated minerals jarlite and jørgensenite. However, its structure type is different from the latter two. The fluoridoaluminate framework of bøgvadite consists of infinite zig-zag chains of cis-connected AlF₆ coordination octahedra. The ¹ _∞[AlF₅] chains are interconnected by infinite chains of Na-F coordination polyhedra which extend in the same direction. Na is coordinated by nine F atoms if its full surrounding is taken in consideration, but makes significant chemical bonds only to closest five. The chains of AlF₆ and NaF₉ coordination polyhedra form double layers. In the centre of layers, relatively large voids in the form of pentagonal antiprisms are occupied by Sr atoms which make chemical bonds with the closest six F atoms. Between the SrF₁₀ coordinations in the centre of layers run empty channels. The double layers are interconnected by Ba atoms which are coordinated by eight F atoms and fill the spaces between the layers. Bøgvadite belongs to the group of fluoridoaluminates with infinite chains of cis-connected AlF₆ coordination octahedra, alike those found in the crystal structures of Ba-fluoridoaluminates.     

Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia

In order to examine the extent of the As enrichment and the factors influencing this enrichment in the groundwater of Eastern Croatia, groundwater samples were collected from 56 production wells in two counties, Osijek-Baranja and Vukovar-Srijem, suspected to be more affected. Hydrochemical analyses were performed at all locations including in situ As speciation at 32 locations. Arsenic was detected in 46 out of 56 groundwater samples with total As concentrations up to 491 μg/L. Thirty-six of the studied wells yielded groundwater with total As concentrations that exceeded the WHO Maximum Contaminant Level for arsenic in drinking water of 10 μg/L. Only inorganic As species were detected with arsenite As(III) as the predominant form. The spatial distribution of As in the groundwater was significantly linked with geological, geomorphological and hydrogeological development of the alluvial basin of the Drava and Sava rivers. The most probable groundwater As sources are deeper sediments from the Middle and Upper Pleistocene. The results obtained suggest that biogeochemical processes controlling As concentration in the groundwater are complex and location-specific. Reductive dissolution of Fe oxides, desorption of As from Fe oxides and/or clay minerals as well as competition for the sorption sites with organic matter and phosphate could be the principal mechanisms that control As mobilization. The extent of those processes vary in the different parts of the Drava and Sava depressions and could be linked to different site related parameters, such as lithology, mineralogy, local hydrology and hydrogeology; thus different processes of As mobilization have been proposed for the different types of water in relation to groundwater evolution.     

Dynamical portrait of the Lixiaohua asteroid family

In this paper we present a comprehensive analysis of the dynamics in the region of the (3556) Lixiaohua asteroid family. The family lies in a particularly interesting region of the phase space, crossed by several two-body and three-body mean motion resonances. Also, members of this family can have close encounters with large asteroids, such as Ceres. We have identified the mean motion resonances which contribute to the long-term dynamical evolution of the family and our results confirm that the members of this family can be classified into a number of groups, exhibiting different dynamical behavior. We show for the first time that in the Lixiaohua region, apart from the chaotic diffusion in proper eccentricity and inclination (e _p and I _p ), there is at least one extended chaotic zone where several resonances overlap, thus giving rise to chaotic diffusion in proper semi-major axis (a _p ) as well. Using a code of Monte Carlo type, we simulate the evolution of the family, according to the model which combines the chaotic diffusion (in a _p , e _p and I _p ), Yarkovsky/YORP thermal effect and random walk in a _p due to the close encounters with massive asteroids. These simulations show that all these effects should be taken into account in order to accurately explain the observed distribution of family members in the space of proper elements, although a “minimal” model that accounts for chaotic diffusion in (e _p , I _p ), Yarkovsky-induced drift in a _p and random walk in a _p due to the close encounters with the most massive asteroids is enough to grossly characterize the shape of the family.     

Development of the mixed conifer forest in northern New Mexico and its relationship to Holocene environmental change

Chihuahueños Bog (2925 m) in the Jemez Mountains of northern New Mexico contains one of the few records of late-glacial and postglacial development of the mixed conifer forest in southwestern North America. The Chihuahueños Bog record extends to over 15,000 cal yr BP. An Artemisia steppe, then an open Picea woodland grew around a small pond until ca. 11,700 cal yr BP when Pinus ponderosa became established. C/N ratios, δ¹³C and δ¹⁵N values indicate both terrestrial and aquatic organic matter was incorporated into the sediment. Higher percentages of aquatic algae and elevated C/N ratios indicate higher lake levels at the opening of the Holocene, but a wetland developed subsequently as climate warmed. From ca. 8500 to 6400 cal yr BP the pond desiccated in what must have been the driest period of the Holocene there. C/N ratios declined to their lowest Holocene levels, indicating intense decomposition in the sediment. Wetter conditions returned after 6400 cal yr BP, with conversion of the site to a sedge bog as groundwater levels rose. Higher charcoal influx rates after 6400 cal yr BP probably result from greater biomass production rates. Only minor shifts in the overstory species occurred during the Holocene, suggesting that mixed conifer forest dominated throughout the record.     

Meridional Motion and Reynolds Stress from Debrecen Photoheliographic Data

The Debrecen Photoheliographic Data catalogue is a continuation of the Greenwich Photoheliographic Results providing daily positions of sunspots and sunspot groups. We analyse the data for sunspot groups focussing on meridional motions and transfer of angular momentum towards the solar equator. Velocities are calculated with a daily shift method including an automatic iterative process of removing the outliers. Apart from the standard differential rotation profile, we find meridional motion directed towards the zone of solar activity. The difference in measured meridional flow in comparison to Doppler measurements and some other tracer measurements is interpreted as a consequence of different flow patterns inside and outside of active regions. We also find a statistically significant dependence of meridional motion on rotation velocity residuals confirming the transfer of angular momentum towards the equator. Analysis of horizontal Reynolds stress reveals that the transfer of angular momentum is stronger with increasing latitude up to about \(40^{\circ}\), where there is a possible maximum in absolute value.     

Geomagnetic Effects of Corotating Interaction Regions

We present an analysis of the geoeffectiveness of corotating interaction regions (CIRs), employing the data recorded from 25 January to 5 May 2005 and throughout 2008. These two intervals in the declining phase of Solar Cycle 23 are characterised by a particularly low number of interplanetary coronal mass ejections (ICMEs). We study in detail how four geomagnetic-activity parameters (the Dst, Ap, and AE indices, as well as the Dst time derivative, \(\mathrm{dDst}/\mathrm{d}t\)) are related to three CIR-related solar wind parameters (flow speed, \(V\), magnetic field, \(B\), and the convective electric field based on the southward Geocentric solar magnetospheric (GSM) magnetic field component, \(\mathit{VB}_{s}\)) on a three-hour time resolution. In addition, we quantify statistical relationships between the mentioned geomagnetic indices. It is found that Dst is correlated best to \(V\), with a correlation coefficient of \(\mathrm{cc}\approx0.6\), whereas there is no correlation between \(\mathrm{dDst}/\mathrm{d}t\) and \(V\). The Ap and AE indices attain peaks about half a day before the maximum of \(V\), with correlation coefficients ranging from \(\mathrm{cc}\approx0.6\) to \(\mathrm{cc}\approx0.7\), depending on the sample used. The best correlations of Ap and AE are found with \(\mathit{VB}_{s}\) with a delay of 3 h, being characterised by \(\mathrm{cc}\gtrsim 0.6\). The Dst derivative \(\mathrm{dDst}/\mathrm{d}t\) is also correlated with \(\mathit{VB}_{s}\), but the correlation is significantly weaker \(\mathrm{cc}\approx 0.4\)?–?0.5, with a delay of 0?–?3 h, depending on the employed sample. Such low values of correlation coefficients indicate that there are other significant effects that influence the relationship between the considered parameters. The correlation of all studied geomagnetic parameters with \(B\) are characterised by considerably lower correlation coefficients, ranging from \(\mathrm{cc}=0.3\) in the case of \(\mathrm{dDst}/\mathrm{d}t\) up to \(\mathrm{cc}=0.56\) in the case of Ap. It is also shown that peak values of geomagnetic indices depend on the duration of the CIR-related structures. The Dst is closely correlated with Ap and AE (\(\mathrm{cc}=0.7\)), Dst being delayed for about 3 h. On the other hand, \(\mathrm{dDst}/\mathrm{d}t\) peaks simultaneously with Ap and AE, with correlation coefficients of 0.48 and 0.56, respectively. The highest correlation (\(\mathrm{cc}=0.81\)) is found for the relationship between Ap and AE.     

The global structural response model for multi-deck ships in concept design phase

This paper is an attempt to contribute to the improvement of an analysis model within overall structural synthesis procedure for the multi-deck ships. The paper is organized in two parts: modeling principles and model validation. Principles of the proposed generic model formulation on the global and sub-structure levels are given in detail while the load model is briefly summarized. The basic building blocks (macro-elements and gross-elements) for the modeling of ordinary stiffened panels, combining numerical and analytical approaches, are presented and discussed w.r.t. requirements for a multi-deck structure. Different surrogates (sets of elements and ordinary macro-elements) used for equivalent modeling of large side openings are evaluated, since the reduced shear stiffness of superstructure sides has large influence on the hull girder stress distributions along the entire cross section height. The generic ship models developed using outlined principles and the basic building blocks are further validated through complex examples of a large cruise ship and a livestock carrier. On the global level, the accuracy of the generic model w.r.t. the longitudinal stress distribution over ships height is compared with a standard full ship FE model. The results confirmed that the suggested structural modeling principles, based on the generic FE model can be applied for the fast investigation of different structural topological/geometrical concepts as well as for the ordinary scantling/material optimization.     

Mesozooplankton spatial distribution and community structure in the South Adriatic Sea during two winters (2015, 2016)

Whereas the data on mesozooplankton in the epipelagic offshore Mediterranean Sea are extensive, less information is available about plankton in the deeper layers. The present study aims to describe the vertical and horizontal structure and distribution of mesozooplankton species and their associations down to 1,200 m in the water of the Southern Adriatic Sea. Zooplankton were sampled using a Nansen net of 200‐μm mesh size during two cruises in the winters of 2015 and 2016, extending from the coast to the open sea. In total, 203 zooplankton taxa were identified. The community was dominated by copepods, representing between 67% and 91% of the total abundance. The highest total densities were recorded in the upper layers where a high proportion (up to 36%) of appendicularians was also observed in the first sampled year. Five groups of samples were determined based on their community structure. In 2015 communities were distinct between the 0 and 50 m layer and the underlying one (50–100 m), whereas in 2016 epipelagic waters were inhabited by a more uniform mesozooplankton community. The mesopelagic and deep‐water fauna, especially copepods, showed a relatively stable composition in both sampling years Overall, our study confirms the oligotrophic character of the Southern Adriatic, with occasional density outbreaks of appendicularians under favourable conditions.