Aluminium solubility in rainwater and molten snow

Large variations of aluminium solubilities are found in marine and rural precipitations. The results of seven field experiments are used to produce a model of the solubilization of aluminium independent of the sampling site. Large variations of solubility appear, and the pH seems to be a major factor explaining this solubility changes. Thermodynamic calculations at T=278K suggest that, at higher pHs (>5), equilibrium with gibbsite (Al(OH)₃) or a trivalent alkaline insoluble form acts as a limiting of aluminium solubility and at lower pHs (<5), Al could be in equilibrium with a hydroxysulfate salt Al(OH)_1.5(SO₄)_0.75.Paper submitted to the 7th International Symposium of the Commission for Atmospheric Chemistry and Global Pollution on the Chemistry of the Global Atmosphere held in Chamrousse, France, from 5 to 11 September 1990.     

Typologie et mode de mise en place des roches magmatiques dans les Pyrénées hercyniennes

Résumé L'évolution géodynamique hercynienne des Pyrénées se caractérise par une importante activité magmatique à l'origine de corps plutomques de taille, de composition et de niveaux de mise en place différents. A partir de ces caractéristiques nous avons pu établir une typologie qui nous a permis de distinguer deux types principaux de massifs: 1) les massifs de composition homogène, acides (massifs de type HA) ou basiques (massifs de type HB), localisés dans les grands ensembles métamorphiques régionaux et 2) les massifs de composition hétérogène, formés par l'association de roches basiques et de roches acides dont la répartition spatiale a permis de distinguer les massifs de type CA (roches acides au coeur du massif), les massifs de type CB (roches basiques au coer du massif) et les massifs de type CR (récurrences de lentilles de roches basiques dans un massif zoné de type CA ou CB), mis en place dans le Paléozoïque supérieur généralement loin des grands ensembles métamorphiques. Tous ces massifs se sont mis en place diapiriquement au cours du métamorphisme régional et de la déformation hercynienne majeure.

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One of the main characteristics of the Hercynian geodynamic evolution of the Pyrenees is an intense magmatic activity producing large plutonic bodies. They have different sizes, various compositions and distinct emplacement levels. From these characteristics, a typology for these massifs is defined. Two main types of massifs have been recognized: 1) massifs with an homogenous composition founded in large regional metamorphic areas, and 2) massifs with an heterogenous composition of acid and basic rocks, whose spatial disposition permits the recognition of three sub-types: a) the CA type where acid rocks are at the core of the massif; b) the CB type where basic rocks are at the core of the massif, and c) the CR type where numerous basic xenoliths are scattered within either a CA or a CB type massif. These heterogenous massifs generally occur within Upper Paleozoic rocks and usually far away from regional metamorphic areas. All of these massifs were emplaced diapirically during the regional metamorphism and the main Hercynian deformation.

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Zusammenfassung Ein wichtiges charakteristisches Merkmal der geodynamischen Entwicklung der Pyrenäen während der herzynischen Phase ist eine hohe magmatische Aktivität, auf die Plutone größerer Ausdehnung zurückgeführt werden. Größe, Mineralogie und Erstarrungstiefe der Plutone variieren. Anhand dieser Charakteristika können die Intrusivkörper in zwei Hauptgruppen differenziert werden. Die erste Gruppe (1) sind Plutone homogener Zusammensetzung in regionalmetamorph überprägten Gebieten. Die zweite sind heterogen zusammengesetzte Plutone (2) saurer und basischer Magmatite, deren räumliche Anordnung eine Untergliederung in drei Untergruppen ermöglicht:a) Bei dem CA-Typ befinden sich saure Gesteine im Kern; bei b), dem CB-Typ, liegen basische Gesteine im Kern vor und bei c), einem CR genannten Typ, sind zahlreiche basische Xenolithe entweder in dem CA-oder dem CB-Typ verstreut vorhanden. Diese heterogenen Plutone findet man allein in spätpaläozoischen Gesteinen und in der Regel weit entfernt von Gebieten, die metamorph beeinflußt wurden. Sämtliche Plutone haben eine Diapir-ähnliche Form und intrudierten zeitgleich mit der Regionalmetamorphose und der Hauptphase der herzynischen Deformation.

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Evidence for Non-Conservative Behaviour of Chlorine in Humid Tropical Environments

The knowledge of the biogeochemical cycle of chlorine (Cl)is important since this element is used as a tracer of geochemical and hydrological processes in oceanic or continental environments. More specifically, Cl can be used to correct surface water composition from atmospheric contribution in order to calculate precise chemical weathering rates in watersheds. Beyond the problem of potential Cl sources in a given watershed, which is directly related to the lithology, vegetation, and industrial activities, the Cl normalization is based on the assumption that this element behaves conservatively during surface processes (e.g., chemical weathering, adsorption/desorption processes).The purpose of the present study is to forecast the geochemical behavior of Cl in a forested ecosystem located under humid tropical environment.For this reason, we have analyzed the Cl (and also Ca and Na) concentrations ofsurface waters (rainwater, groundwater, river water) over a two-year period in the Nsimi–Zoetele watershed (Cameroon).The Cl mass balance for the watershed appears to be equilibrated over the studied period (1995–1996) but Cl behavior in Mengong River draining the watershed suggests a non-conservative behavior. Indeed, Cl concentrationsin the Mengong River are low during dry seasons and high during wet seasons, which is the reverse tendency to what is usually observed taking into account dilution and evaporation processes. As Cl concentrations in the Mengong River are lower than those measured in all the feeding reservoirs, Cl should be adsorbed onto the soils of the watershed. However, as the Cl mass balance is equilibrated over the whole-year, Cl should be adsorbed and releasedat a seasonal scale. The results we obtained for this small watershed were not generalized for a larger studied basin (i.e., Nyong River basin). Even if these results should be followed by further investigations, this study suggests that Cl normalization should be used with caution to avoid under- or over-estimation of chemical weathering rates.     

Data assimilation for precipitation nowcasting using Bayesian inference

This work introduces a new variational Bayes data assimilation method for the stochastic estimation of precipitation dynamics using radar observations for short term probabilistic forecasting (nowcasting). A previously developed spatial rainfall model based on the decomposition of the observed precipitation field using a basis function expansion captures the precipitation intensity from radar images as a set of ‘rain cells’. The prior distributions for the basis function parameters are carefully chosen to have a conjugate structure for the precipitation field model to allow a novel variational Bayes method to be applied to estimate the posterior distributions in closed form, based on solving an optimisation problem, in a spirit similar to 3D VAR analysis, but seeking approximations to the posterior distribution rather than simply the most probable state. A hierarchical Kalman filter is used to estimate the advection field based on the assimilated precipitation fields at two times. The model is applied to tracking precipitation dynamics in a realistic setting, using UK Met Office radar data from both a summer convective event and a winter frontal event. The performance of the model is assessed both traditionally and using probabilistic measures of fit based on ROC curves. The model is shown to provide very good assimilation characteristics, and promising forecast skill. Improvements to the forecasting scheme are discussed.     

Biological and Temporal Variations of Trace Element Concentrations in the Moss Species Scleropodium purum (Hedw.) Limpr.

Over a period of one year, the moss Scleropodium purum was sampled every two weeks in a French rural area to determine the levels of Li, Na, Al, Si, P, Ca, V, Mn, Fe, Zn, Ba, Hg, and Pb. The element distribution in the moss shoot was studied throughout the year. An apical bioconcentration was discovered for Na, P, Ca, Mn, and Zn, whereas higher levels were found in the basal fraction for Li, Al, Si, V, Fe, Ba, Hg, and Pb. A significant variation of element concentrations was observed during the sampling period. In the apical part Li, Al, Si, V, Fe, Ba, and Hg show maximum levels in the summer and minimum in the autumn. The same pattern was found with Ca and Mn in the whole plant, whereas Na showed opposite fluctuations.     

Transportation of water,particulate and dissolved organic and inorganic matter between a salt marsh and the Ems-Dollard estuary,The Netherlands

Transport processes were studied in a gully between a salt marsh and an estuary. After storm tides, ebb currents in the gully reached high values. It is concluded that particulate matter (both organic and inorganic) are imported into the marsh. Coarse organic debris is exported during storm tides, but this amount is low when compared with the primary production on the marsh. Exports are shown for dissolved organic carbon, ammonia, phosphate and silica, while nitrate and possibly nitrite are imported. Organic matter derived from in situ production and net import is buried and partly mineralized in the marsh.     

Historical mining and smelting in the Vosges Mountains (France) recorded in two ombrotrophic peat bogs

Two peat sequences were sampled in the vicinity of the main mining districts of the Vosges Mountains: Sainte-Marie-aux-Mines and Plancher-les-Mines. Lead isotopic compositions and excess lead fluxes were calculated for each of these radiocarbon-dated sequences. Geochemical records are in very good agreement with the mining history of the area, well known over the last millennium. Except for an anomaly corresponding to the Middle Bronze Age which has not yet been resolved, there is no clear geochemical evidence of local metal production in the Vosges before the 10th century as excess lead deposition archived between 500 BC and 500 AD is attributed to long-range transport of polluted particulate matter. The approach described here can be applied to other mining districts where archaeological evidence is scarce or even lacking, but where past exploitation is suspected.