Phase equilibria modelling constraints on P–T conditions during fluid catalysed conversion of granulite to eclogite in the Bergen Arcs,Norway

Exhumed eclogitic crust is rare and exposures that preserve both protoliths and altered domains are limited around the world. Nominally anhydrous Neoproterozoic anorthositic granulites exposed on the island of Holsnøy, in the Bergen Arcs in western Norway, preserve different stages of progressive prograde deformation, together with the corresponding fluid‐assisted metamorphism, which record the conversion to eclogite during the Ordovician–Silurian Caledonian Orogeny. Four stages of deformation can be identified: (1) brittle deformation resulting in the formation of fractures and the generation of pseudotachylites in the granulite; (2) development of mesoscale shear zones associated with increased fluid–rock interaction; (3) the complete large‐scale replacement of granulite by hydrous eclogite with blocks of granulite sitting in an eclogitic “matrix”; and (4) the break‐up of completely eclogitized granulite by continued fluid influx, resulting in the formation of coarse‐grained phengite‐dominated mineral assemblages. P–T constraints derived from phase equilibria forward modelling of mineral assemblages of the early and later stages of the conversion to eclogite document burial and partial exhumation path with peak metamorphic conditions of ~21–22 kbar and 670–690°C. The P–T models, in combination with existing T–t constraints, imply that the Lindås Nappe underwent extremely rapid retrogressive pressure change. Fluid infiltration began on the prograde burial path and continued throughout the recorded P–T evolution, implying a fluid source that underwent progressive dehydration during subduction of the granulites. However, in places limited fluid availability on the prograde path resulted in assemblages largely consuming the available fluid, essentially freezing in snapshots of the prograde evolution. These were carried metastably deeper into the mantle with strain and metamorphic recrystallization partitioned into areas where ongoing fluid infiltration was concentrated.     

An anisotropic cosmological model in Lyra's manifold

A spatially homogeneous and anisotropic cosmological model in Lyra's manifold is obtained when the source of the gravitational field is a perfect fluid with pressure equal to energy density and the metric is of Bianchi type-I. Various physical and geometrical properties of the model have also been discussed.     

A static conformally-flat vacuum model in self-creation cosmology

Vacuum field equations for the conformally-flat spherically-symmetric static space-time are obtained in a self-creation theory of gravitation proposed by Barber. It is shown that the most general conformally-flat spherically-symmetric static vacuum model in this theory represents only purely flat space-time.     

Higher-dimensional vacuum Friedmann models in Dunn's theory of gravitation

The vacuum Friedmann-Robertson-Walker (FRW) models are investigated in Dunn's theory of gravitation with extra dimensions and some properties of the solutions are discussed.     

MHD flow of an elasto-viscous fluid past a porous flat plate

An analytical study is performed to examine the laminar flow of an electrically-conducting elasto-viscous fluid (Walters's liquidB) past an infinite porous flat plate to a step function change in suction velocity in the presence of a transverse magnetic field. The influence of the various parameters, entering in the problem, on the velocity field and shearing stress is extensively discussed.     

r-Centroids and Franck-Condon factors of the CP,SiC, and CO+ molecules

Ther-centroids and Franck-Condon factors for the bands of theA ² –X ²⁺ of CP,C ³ –X ³ of SiC, andB ²⁺ –X ²⁺ of CO⁺ molecules have been determined. The Franck-Condon factors are evaluated by the approximate analytical method of Jarmain and Fraser. The absence of the bands in these systems is explained.     

Analysis of unresolved complex mixtures of hydrocarbons extracted from Late Archean sediments by comprehensive two-dimensional gas chromatography (GC×GC)

Hydrocarbon mixtures too complex to resolve by traditional capillary gas chromatography display gas chromatograms with dramatically rising baselines or “humps” of coeluting compounds that are termed unresolved complex mixtures (UCMs). Because the constituents of UCMs are not ordinarily identified, a large amount of geochemical information is never explored. Gas chromatograms of saturated/unsaturated hydrocarbons extracted from Late Archean argillites and greywackes of the southern Abitibi Province of Ontario, Canada contain UCMs with different appearances or “topologies” relating to the intensity and retention time of the compounds comprising the UCMs. These topologies appear to have some level of stratigraphic organization, such that samples collected at any stratigraphic formation collectively are dominated by UCMs that either elute early- (within a window of C₁₅–C₂₀ n-alkanes), early- to mid- (C₁₅–C₃₀ n-alkanes), or have a broad UCM that extends through the entire retention time of the sample (from C₁₅–C₄₂ n-alkanes). Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC–MS) was used to resolve the constituents forming these various UCMs. Early- to mid-eluting UCMs are dominated by configurational isomers of alkyl-substituted and non-substituted polycyclic compounds that contain up to six rings. Late eluting UCMs are composed of C₃₆–C₄₀ mono-, bi-, and tricyclic archaeal isoprenoid diastereomers. Broad UCMs spanning the retention time of compound elution contain nearly the same compounds observed in the early-, mid-, and late-retention time UCMs. Although the origin of the polycyclic compounds is unclear, the variations in the UCM topology appear to depend on the concentration of initial compound classes that have the potential to become isomerized. Isomerization of these constituents may have resulted from hydrothermal alteration of organic matter.     

Chemical characteristics of PM<Subscript>10</Subscript> aerosols and airmass trajectories over Bay of Bengal and Arabian Sea during ICARB

For the first time, chemical characterization of PM₁₀ aerosols was attempted over the Bay of Bengal (BoB) and Arabian Sea (AS) during the ICARB campaign. Dominance of SO ₄ ^2? , NH ₄ ⁺ and NO ₃ ^? was noticed over both the regions which indicated the presence of ammonium sulphate and ammonium nitrate as major water soluble particles playing a very important role in the radiation budget. It was observed that all the chemical constituents had higher concentrations over Bay of Bengal as compared to Arabian Sea. Higher concentrations were observed near the Indian coast showing influence of landmass indicating that gaseous pollutants like SO₂, NH₃ and NO _x are transported over to the sea regions which consequently contribute to higher SO ₄ ^2? , NH ₄ ⁺ and NO ₃ ^? aerosols respectively. The most polluted region over BoB was 13°?19°N and 70°?90°E while it was near 11°N and 75°E over AS. Although the concentrations were higher over Bay of Bengal for all the chemical constituents of PM₁₀ aerosols, per cent non-sea salt (nss) fraction (with respect to Na) was higher over Arabian Sea. Very low Ca2+ concentration was observed at Arabian Sea which led to higher atmospheric acidity as compared to BoB. Nss SO ₄ ^2? alone contributed 48% of total water soluble fraction over BoB as well as AS. Ratios SO ₄ ^2? /NO _? ³ over both the regions (7.8 and 9 over BoB and AS respectively) were very high as compared to reported values at land sites like Allahabad (0.63) and Kanpur (0.66) which may be due to very low NO.3 over sea regions as compared to land sites. Air trajectory analysis showed four classes: (i) airmass passing through Indian land, (ii) from oceanic region, (iii) northern Arabian Sea and Middle East and (iv) African continent. The highest nss SO ₄ ^2? was observed during airmasses coming from the Indian land side while lowest concentrations were observed when the air was coming from oceanic regions. Moderate concentrations of nss SO2. 4 were observed when air was seen moving from the Middle East and African continent. The pH of rainwater was observed to be in the range of 5.9–6.5 which is lower than the values reported over land sites. Similar feature was reported over the Indian Ocean during INDOEX indicating that marine atmosphere had more free acidity than land atmosphere.     

Identification of influencing factors for groundwater quality variation using multivariate analysis

This paper reports the results of multivariate analysis on the major-ions data present in groundwater collected in a hydrogeochemical survey of a hard rock terrain in Andhra Pradesh, India. The use of factor analysis is proposed, as a first step, for identifying the processes influencing the hydrogeochemical variations in groundwater. As a result of the application factor analysis, three factors were obtained, which explained characterization of groundwater quality and identified the sources for the presence of ions and its variations in concentrations and their geochemical processes. The natural dissolution of existing rocks of granites and granitic gneisses is the common influencing source for its hydrogeochemical character in the study area, but at some localized zones, the human-influenced sources of agricultural, industrial and urbanization are the dominating factors. The spatial and seasonal variation of the hydrogeochemical processes associated with the factor variables in the groundwater quality of the study area were analysed and evaluated.     

Collision tectonics of the Central Indian Suture zone as inferred from a deep seismic sounding study

The Central Indian Suture (CIS) is a mega-shear zone extending for hundreds of kilometers across central India. Reprocessing of deep seismic reflection data acquired across the CIS was carried out using workstation-based commercial software. The data distinctly indicate different reflectivity characteristics northwest and southeast of the CIS. Reflections northwest of the CIS predominantly dip southward, while the reflection horizons southeast of the CIS dip northward. We interpret these two adjacent seismic fabric domains, dipping towards each other, to represent a suture between two crustal blocks. The CIS itself is not imaged as a sharp boundary, probably due to the disturbed character of the crust in a 20 to 30-km-wide zone. The time sections also show the presence of strong bands of reflectors covering the entire crustal column in the first 65 km of the northwestern portion of the profile. These reflections predominantly dip northward creating a domal structure with the apex around 30 km northwest of the CIS. There are a very few reflections in the upper 2–2.5 s two-way time (TWT), but the reflectivity is good below 2.5 s TWT. The reflection Moho, taken as the depth to the deepest set of reflections, varies in depth from 41 to 46 km and is imaged sporadically across the profile with the largest amplitude occurring in the northwest. We interpret these data as recording the presence of a mid-Proterozoic collision between two micro-continents, with the Satpura Mobile Belt being thrust over the Bastar craton.