The Maria asteroid family: Genetic relationships and a plausible source of mesosiderites near the 3:1 Kirkwood Gap

We present a mineralogical assessment of 12 Maria family asteroids, using near-infrared spectral data obtained over the years 2000-2009 combined with visible spectral data (when available) to cover the spectral interval of 0.4-2.5 μm. Our analysis indicates the Maria asteroid family, which is located adjacent to the chaotic region of the 3:1 Kirkwood Gap, appears to be a true genetic family composed of assemblages analogous to mesosiderite-type meteorites. Dynamical models by Farinella et al. (Farinella, P., Gunczi, R., Froeschlé, Ch., Froeschlé, C., [1993]. Icarus 101, 174-187) predict this region should supply meteoroids into Earth-crossing orbits. Thus, the Maria family is a plausible source of some or all of the mesosiderites in our meteorite collections. These individual asteroids were most likely once part of a larger parent object that was broken apart and dispersed. One of the Maria dynamical family members investigated, ((695) Bella), was found to be unrelated to the genetic Maria family members. The parameters of (695) Bella indicate an H-chondrite assemblage, and that Bella may be a sister or daughter of Asteroid (6) Hebe.     

Mineralogical characterization of potential targets for the ASTEX mission scenario

In-situ investigation of asteroids is the next logical step in understanding their exact surface mineralogy, petrology, elemental abundances, particle size distribution, internal structure, and collisional evolution. Near-Earth asteroids (NEAs) provide us with ample opportunities for in-situ scientific exploration with lower Δv requirements and subsequently lower costs than their main belt counterparts. The ASTEX mission concept aims at surface characterization of two compositionally diverse NEAs, one with primitive and the other with a strong thermally evolved surface mineralogy. Here we present the first results of our ground-based characterization of potential ASTEX mission targets using the SpeX instrument on the NASA IRTF. Of the four potential targets we characterized, two (1991 JW and 1998 PA) have compositions similar to ordinary chondrite mineralogy. The other two targets (1994 CC and 1999 TA10) are thermally evolved objects with igneous formation histories. While 1994 CC is a triplet system and thus very challenging to orbit the V-type NEA, 1999 TA10 is the most interesting scientific ASTEX target identified so far.     

Biodegradation and environmental behavior of biodiesel mixtures in the sea: An initial study

Biodiesel, a mixture of fatty acid methyl esters (FAMEs) derived from animal fats or vegetable oils, is rapidly moving towards the mainstream as an alternative source of energy. However, the behavior of biodiesel, or blends of biodiesel with fossil diesel, in the marine environment have yet to be fully understood. Hence, we performed a series of initial laboratory experiments and simple calculations to evaluate the microbial and environmental fate of FAMEs. Aerobic seawater microcosms spiked with biodiesel or mixtures of biodiesel and fossil diesel revealed that the FAMEs were degraded at roughly the same rate as n-alkanes, and more rapidly than other hydrocarbon components. The residues extracted from these different microcosms became indistinguishable within weeks. Preliminary results from physical-chemical calculations suggest that FAMEs in biodiesel mixtures will not affect the evaporation rates of spilled petroleum hydrocarbons but may stabilize oil droplets in the water column and thereby facilitate transport.     

Relationship among titanium,rare earth elements,U–Pb ages and deformation microstructures in zircon: Implications for Ti-in-zircon thermometry

A zircon grain in an orthopyroxene–garnet–phlogopite–zircon–rutile-bearing xenolith from Udachnaya, Siberia, preserves a pattern of crystallographic misorientation and subgrain microstructure associated with crystal–plastic deformation. The zircon grain records significant variations in titanium (Ti) from 2.6 to 30 ppm that corresponds to a difference in calculated Ti-in-zircon temperatures of over several hundred degrees Celsius. The highest Ti concentration is measured at subgrain centres (30 ppm), and Ti is variably depleted at low-angle boundaries (down to 2.6 ppm). Variations in cathodoluminescence coincide with the deformation microstructure and indicate localised, differential enrichment of rare earth elements (REE) at low-angle boundaries. Variable enrichment of U and Th and systematic increase of Th/U from 1.61 to 3.52 occurs at low-angle boundaries. Individual SHRIMP-derived U–Pb ages from more deformed zones (mean age of 1799 ± 40, n = 22) are systematically younger than subgrain cores (mean age of 1851 ± 65 Ma, n = 7), and indicate that open system behaviour of Ti–Th–U occurred shortly after zircon growth, prior to the accumulation of significant radiogenic Pb. Modelling of trace-element diffusion distances for geologically reasonable thermal histories indicates that the observed variations are ~ 5 orders of magnitude greater than can be accounted for by volume diffusion. The data are best explained by enhanced diffusion of U, Th and Ti along deformation-related fast-diffusion pathways, such as dislocations and low-angle (< 5°) boundaries. These results indicate chemical exchange between zircon and the surrounding matrix and show that Ti-in-zircon thermometry and U–Pb geochronology from deformed zircon may not yield information relating to the conditions and timing of primary crystallisation.     

Geochemistry of carbonate precipitation from the groundwater in a coastal region

Groundwater samples were collected from a coastal region of Andhra Pradesh to assess the possible conditions of the formation of carbonates. The area experiences a semi-arid climate and is underlain by khondalites, over which the Quaternary sediments occur. The study of the geochemistry of groundwater indicates that groundwater is mostly of fresh, with alkaline nature. The study further suggest that the breakdown of feldspars as kaolinite during rock-water interaction, releases Ca²⁺. Soils/weathered products contribute high CO₂ under the open system. The Ca²⁺ and CO₂ are added to the groundwater through the infiltrating recharge water. They subsequently precipitate as fine-grained carbonates in the weathering profile due to evapotranspiration under a freshwater environment.     

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

Influence of pH on Sporulation,Spore Germination and Germling Survival in Blue-green Algae

An investigation is made on the influence of the pH-value in the range of pH = 4.5 to 11.0 on sporulation, germination and germling development of Anabaena fertilissima and Anabaenopsis arnoldii, isolated from the Sambhar Salt Lake, Rajasthan. Maximum rates of germination were obtained with Anabaena at pH = 7.0… 10.5, with Anabaenopsis at pH = 7.0 to 8.5. With both species, sporulation occurs in the same pH-ranges, Anabaena dying without sporulation in the range of pH = 5.5… 6.5 and above pH = 10.5 and Anabaenopsis surviving without sporulation above pH = 9.5. With Anabaena the germling growth steadily increases from pH = 7 to 10.5, whereas Anabaenopsis shows a maximum at pH = 7 and at any other pH-value growth is considerably lower. Moreover, spore germination is bound to an exchange of the medium. In agreement with these experimental findings concerning the cultures, from July to February Anabaenopsis occurs in the Sambhar Lake as a vegetative form with a partial mass development, and from March to June it survives as a spore. Anabaena, however, has only a short vegetative phase in June, and it survives the remaining part of the year as a spore. Thus, the fast germination and sporulation in the range of higher alkalinity is the ecological strategy for Anabaena to resist the competition offered by Anabaenopsis.