Hydrogeochemical prospecting for porphyry copper deposits in the tropical-marine climate of Puerto Rico

A hydrogeochemical survey utilizing waters from streams and springs was conducted in the area of two known porphyry copper deposits in the tropical-marine climate of westcentral Puerto Rico. The most important pathfinder for regional hydrogeochemical surveys is sulfate which reflects the associated pyrite mineralization. Because of increased mobility due to intense chemical weathering and the low pH environment, dissolved copper can also be used as a pathfinder for regional surveys and has the advantage of distinguishing barren pyrite from pyrite associated with copper mineralization. For follow-up surveys, the most important pathfinders are copper, sulfate, pH, zinc, and fluoride. High concentrations of dissolved copper and moderate concentrations of sulfate is a diagnostic indication of nearby sources of copper minerals.An understanding of the geochemical processes taking place in the streambeds and the weathering environment, such as the precipitation of secondary copper minerals, contributes to the interpretation of the geochemical data and the selection of the most favorable areas for further exploration.     

Consequences of change and variability in sea ice on marine ecosystem and biogeochemical processes during the 2007–2008 Canadian International Polar Year program

Change and variability in the timing and magnitude of sea ice geophysical and thermodynamic state have consequences on many aspects of the arctic marine system. The changes in both the geophysical and thermodynamic state, and in particular the timing of the development of these states, have consequences throughout the marine system. In this paper we review the ??consequences?? of change in sea ice state on primary productivity, marine mammal habitats, and sea ice as a medium for storage and transport of contaminants and carbon exchange across the ocean-sea-ice-atmosphere interface based upon results from the International Polar Year. Pertinent results include: 1) conditions along ice edges can bring deep nutrient-rich ??pacific?? waters into nutrient-poor surface waters along the arctic coast, affecting local food webs; 2) both sea ice thermodynamic and dynamic processes ultimately affect ringed seal/polar bear habitats by controlling the timing, location and amount of surface deformation required for ringed seal and polar bear preferred habitat 3) the ice edges bordering open waters of flaw leads are areas of high biological production and are observed to be important beluga habitat. 4) exchange of climate-active gases, including CO₂, is extremely active in sea ice environments, and the overall question of whether the Arctic Ocean is (or will be) a source or sink for CO₂ will be dependent on the balance of competing climate-change feedbacks.     

Centennial-scale climate change from decadally-paced explosive volcanism: a coupled sea ice-ocean mechanism

Northern Hemisphere summer cooling through the Holocene is largely driven by the steady decrease in summer insolation tied to the precession of the equinoxes. However, centennial-scale climate departures, such as the Little Ice Age, must be caused by other forcings, most likely explosive volcanism and changes in solar irradiance. Stratospheric volcanic aerosols have the stronger forcing, but their short residence time likely precludes a lasting climate impact from a single eruption. Decadally paced explosive volcanism may produce a greater climate impact because the long response time of ocean surface waters allows for a cumulative decrease in sea-surface temperatures that exceeds that of any single eruption. Here we use a global climate model to evaluate the potential long-term climate impacts from four decadally paced large tropical eruptions. Direct forcing results in a rapid expansion of Arctic Ocean sea ice that persists throughout the eruption period. The expanded sea ice increases the flux of sea ice exported to the northern North Atlantic long enough that it reduces the convective warming of surface waters in the subpolar North Atlantic. In two of our four simulations the cooler surface waters being advected into the Arctic Ocean reduced the rate of basal sea-ice melt in the Atlantic sector of the Arctic Ocean, allowing sea ice to remain in an expanded state for?>?100 model years after volcanic aerosols were removed from the stratosphere. In these simulations the coupled sea ice-ocean mechanism maintains the strong positive feedbacks of an expanded Arctic Ocean sea ice cover, allowing the initial cooling related to the direct effect of volcanic aerosols to be perpetuated, potentially resulting in a centennial-scale or longer change of state in Arctic climate. The fact that the sea ice-ocean mechanism was not established in two of our four simulations suggests that a long-term sea ice response to volcanic forcing is sensitive to the stability of the seawater column, wind, and ocean currents in the North Atlantic during the eruptions.     

Spectral-type simulation of spatially correlated fracture set properties

Fracture set properties such as orientation, spacing, trace length, and waviness tend to be spatially correlated. These properties can be efficiently simulated by spectral analysis procedures that take advantage of the computational speed of the fast Fourier transform. The covariance function of each property to be simulated is obtained from the variogram function estimated from mapped fracture set data and is typically referenced to the mean vector of the set. Simulation procedures for normally and exponentially distributed data involve generating uncorrelated Fourier coefficients that are assigned proper variance according to the spectral density, which is the Fourier transform of the covariance function. These coefficients are then reverse Fourier transformed to produce simulated set properties that have the desired variance and variogram function.     

Abundance and distribution of ichthyoplankton in the upwelling zone off Oregon during anomalous El Niño conditions

The abundance and distribution patterns of nearshore ichthyoplankton were investigated during a year of anomalously high sea temperatures off Oregon. Samples collected from 2 to 18 km offshore from April through September of 1983 showed increased occurrences and higher abundances of taxa usually found at distances offshore of 37 km in other years. The dominant species collected, comprising more than half of the total larval fish abundance, was the northern anchovy (Engraulis mordax). Larval anchovy have rarely been collected inshore in previous studies. Many of the dominant taxa normally found inshore, especially osmerids, were present in reduced numbers in 1983. Changes in the hydrographic conditions associated with onshore surface drift and reduced summer upwelling during the 1983 El Niño could explain the distributional patterns observed. The warm inshore waters apparently provided a substantial spatial and temporal expansion of the spawning habitat for E. mordax.     

Office of Naval Research contributions to neural networks andsignal processing in oceanic engineering

The authors summarize many of the highlights and accomplishments of the Office of Naval Research's neural network basic research programs and share a bit of the historical perspective that serves as a source of pride in the world of Navy science and technology, namely, the long-term support and resulting payoff of Navy-sponsored research in neural networks. The significant problems that must be overcome before neural network applications will become widely available to the Navy community are surveyed     

Basin architecture and thermal maturation in the strike-slip Deer Lake Basin, Carboniferous of Newfoundland

Abstract The Deer Lake Basin is an entirely non-marine basin associated with the Cabot fault zone. Structural and stratigraphic evidence strongly suggest dextral strike-slip movements along the fault zone during Tournaisian-Visean time. Two elongated, end-on structural blocks (probable positive flower structures) contain fold axes and second-order faults oriented obliquely to fault traces bounding the blocks, in a manner implying dextral movements. In one part of the basin, the stratigraphic thickness of a long homoclinal section of later basin-fill sediment (Deer Lake Group) greatly exceeds the suggested depth to basement based on gravity measurements, a situation common to strike-slip basins. Formations representing basin fill can be arranged into megasequences (from oldest to youngest: Anguille Group, Wetstone Point and Wigwam Brook Formations, Deer Lake Group, Howley Formation) corresponding to lateral growth stages of the basin. Gravity, magnetic, and seismic data show that depths to basement on either side of the end-on flower structures are comparable, so that the youngest strata in the basin (Howley Formation) are not underlain by earlier basin fill. These geophysical data, therefore, corroborate the geological conclusion of onlapping stratigraphic relations. The geophysical data suggest participation of basement in Carboniferous gravity faulting and show the location of the subsurface extension of the Taylors Brook Fault in the western part of the Deer Lake Basin. Thermal maturation of the Anguille and Deer Lake Groups, as measured by vitrinite reflectance, clay mineral assemblages, illite crystallinity, and Rock-Eval pyrolysis, indicate a much higher level of maturation for the Anguille than for the Deer Lake Group. Palaeotemperatures for the Anguille and Deer Lake Groups are estimated to be around 200 and 100^oC, respectively, suggesting that Anguille Group rocks are overmature whereas Deer Lake Group strata are within the oil-generating window. Onlapping stratigraphic relations and areally homogeneous time/temperature effects, however, have created a situation in which the Deer Lake Group and Howley Formation have similar maturation levels.     

Simplify or perish

Three suggestions are made for breaking the gridlock which paralyses progress in automating massive symbolic calculations in celestial mechanics: (i) simplifications by canonical transformations, (ii) object oriented programming to endow the algebra of Poisson series with various structures, (iii) massively parallel processing.